Cork (material)
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Cork is an impermeable buoyant material. It is the phellem layer of bark tissue which is harvested for commercial use primarily from Quercus suber (the cork oak), which is native to southwest Europe and northwest Africa. Cork is composed of suberin, a hydrophobic substance. Because of its impermeable, buoyant, elastic, and fire retardant properties, it is used in a variety of products, the most common of which is wine stoppers.
The montado landscape of Portugal produces approximately half of the cork harvested annually worldwide, with Corticeira Amorim being the leading company in the industry.<ref>Template:Cite web</ref> Cork was examined microscopically by Robert Hooke, which led to his discovery and naming of the cell.<ref name="urlRobert Hooke">Template:Cite web</ref>
Cork composition varies depending on geographic origin, climate and soil conditions, genetic origin, tree dimensions, age (virgin or reproduction), and growth conditions. However, in general, cork is made up of suberin (average of about 40%), lignin (22%), polysaccharides (cellulose and hemicellulose) (18%), extractables (15%) and others.<ref name="Duarte 2015">Template:Cite journal File:CC-BY icon.svg Text was copied from this source, which is available under a Creative Commons Attribution 4.0 International License.</ref>
History
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Cork is a natural material used by humans for over 5,000 years. It is a material whose applications have been known since antiquity, especially in floating devices and as stopper for beverages, mainly wine, whose market, from the early twentieth century, had a massive expansion, particularly due to the development of several cork-based agglomerates.<ref name=":1">Template:Cite journal File:CC-BY icon.svg Text was copied from this source, which is available under a Creative Commons Attribution 4.0 International License.</ref>
In China, Egypt, Babylon, and Persia from about 3000 BC, cork was already used for sealing containers, fishing equipment, and domestic applications. In ancient Greece (1600 to 1100 years BC) cork was used in footwear, to manufacture a type of sandals attached to the foot by straps, generally leather and with a sole in cork or leather.<ref name=":0">Template:Cite web</ref><ref>Template:Cite journal</ref>
In the second century AD, a Greek physician, Dioscorides, noted several medical applications of cork, mainly for hair loss treatment.<ref name=":0" /> Nowadays, the majority of people know cork for its use as stoppers in wine bottles. The innovation of using cork as stopper can be traced back to the late 17th century, attributed to Dom Pierre Pérignon.<ref>Template:Cite web</ref> Cork stoppers were adopted in 1729 by Ruinart and in 1973 by Moët et Chandon.<ref name="Duarte 2015"/>
Structure
[edit]Cork presents a characteristic cellular structure in which the cells have usually a pentagonal or hexagonal shape. The cellular wall consists of a thin, lignin-rich middle lamella (internal primary wall), a thick secondary wall made up from alternating suberin and wax lamella, and a thin tertiary wall of polysaccharides. Some studies suggest that the secondary wall is lignified, and therefore, may not consist exclusively of suberin and waxes. The cells of cork are filled with a gas mixture similar to air, making them behave as authentic "pads," which contributes to the capability of cork to recover after compression.<ref name="Duarte 2015"/>
Sources
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There are about 2,200,000 hectares of cork oak (Quercus suber) forest in the Mediterranean basin, the native area of the species. The most extensively managed habitats are in Portugal (34%) and in Spain (27%). Annual production is about 300,000 tons; 49.6% from Portugal, 30.5% from Spain, 5.8% from Morocco, 4.9% from Algeria, 3.5% from Tunisia, 3.1% from Italy, and 2.6% from France.<ref>Template:Cite web</ref> Once the trees are about 25 years old the cork is traditionally stripped from the trunks every nine years, with the first two harvests generally producing lower quality cork (male cork or virgin cork). The trees live for about 300 years.
The cork industry is generally regarded as environmentally friendly.<ref>Template:Cite web</ref> Cork production is generally considered sustainable because the cork tree is not cut down to obtain cork; only the bark is stripped to harvest the cork.<ref>Template:Cite news</ref> The tree continues to live and grow. The sustainability of production and the easy recycling of cork products and by-products are two of its most distinctive aspects. Cork oak forests also prevent desertification and are a particular habitat in the Iberian Peninsula and the refuge of various endangered species.<ref>Template:Cite news</ref>
Carbon footprint studies conducted by Corticeira Amorim, Oeneo Bouchage of France and the Cork Supply Group of Portugal concluded that cork is the most environmentally friendly wine stopper in comparison to other alternatives. The Corticeira Amorim's study, in particular ("Analysis of the life cycle of Cork, Aluminum and Plastic Wine Closures"), was developed by PricewaterhouseCoopers, according to ISO 14040.<ref>Template:Cite web</ref><ref>Template:Cite web</ref> Results concluded that, concerning the emission of greenhouse gases, each plastic stopper released 10 times more CO2, whilst an aluminium screw cap releases 26 times more CO2 than does a cork stopper. For example, to produce 1,000 cork stoppers 1.5 kg Template:CO2 are emitted, but to produce the same amount of plastic stoppers 14 kg of Template:CO2 are emitted and for the same amount of aluminium screw caps 37 kg Template:CO2 are emitted.<ref name=":1" />
The Chinese cork oak is native to East Asia and is cultivated in a limited extent in China; the cork produced is considered inferior to Q. suber and are used to produce agglomerated cork products.<ref>Template:Cite journal</ref>
The so-called "cork trees" (Phellodendron) are unrelated to the cork oak, they have corky bark but not thick enough for cork production.Template:Citation needed
Harvesting
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Cork is extracted only from early May to late August, when the cork can be separated from the tree without causing permanent damage. When the tree reaches 25–30 years of age and about 24 in (60 cm) in circumference, the cork can be removed for the first time. However, this first harvest almost always produces poor quality or virgin cork (Portuguese Template:Lang; Spanish Template:Lang or Template:Lang<ref name="DRAE">Template:Cite web</ref>).
The workers who specialize in removing the cork are known as extractors. An extractor uses a very sharp axe to make two types of cuts on the tree: one horizontal cut around the plant, called a crown or necklace, at a height of about two to three times the circumference of the tree, and several vertical cuts called rulers or openings. This is the most delicate phase of the work because, even though cutting the cork requires significant force, the extractor must not damage the underlying phellogen or the tree will be harmed.Template:Citation needed
To free the cork from the tree, the extractor pushes the handle of the axe into the rulers. A good extractor needs to use a firm but precise touch in order to free a large amount of cork without damaging the product or tree.Template:Citation needed
These freed portions of the cork are called planks. The planks are usually carried off by hand since cork forests are rarely accessible to vehicles. The cork is stacked in piles in the forest or in yards at a factory and traditionally left to dry, after which it can be loaded onto a truck and shipped to a processor.
Bark from initial harvests can be used to make flooring, shoes, insulation and other industrial products. Subsequent extractions usually occur at intervals of nine years, though it can take up to thirteen for the cork to reach an acceptable size. If the product is of high quality it is known as gentle cork (Portuguese Template:Lang,<ref>Template:Lang comes from and is a synonym of Template:Lang, "beberage or spell to seduce" (Dicionário Houaiss da Língua Portuguesa), from Template:Lang, "to love".</ref> but also Template:Lang only if it is the second time; Spanish Template:Lang, also restricted to the second time<ref name="DRAE"/>), and, ideally, is used to make stoppers for wine and champagne bottles.<ref>Template:Cite web</ref>
Properties and uses
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Cork's elasticity combined with its near-impermeability makes it suitable as a material for bottle stoppers, especially for wine bottles. Cork stoppers represent about 60% of all cork based production. Cork has an almost zero Poisson's ratio, which means the radius of a cork does not change significantly when squeezed or pulled.<ref name="Stavroulakis1">Template:Cite journal</ref>
Cork is an excellent gasket material. Some carburetor float bowl gaskets are made of cork, for example.Template:Citation needed
Cork is also an essential element in the production of badminton shuttlecocks.<ref>Template:Cite web</ref>
Cork's bubble-form structure and natural fire retardancy make it suitable for acoustic and thermal insulation in house walls, floors, ceilings, and facades. The by-product of more lucrative stopper production, corkboard, is gaining popularity as a non-allergenic, easy-to-handle and safe alternative to petrochemical-based insulation products.
Cork is also used to make vinyl record slipmats, due to its ability to not attract dust. They also dampen static and vibrations.<ref>Template:Cite web</ref>
Sheets of cork, also often the by-product of stopper production, are used to make bulletin boards as well as floor and wall tiles.
Cork's low density makes it a suitable material for fishing floats and buoys, as well as handles for fishing rods (as an alternative to neoprene).
Granules of cork can also be mixed into concrete. The composites made by mixing cork granules and cement have lower thermal conductivity, lower density, and good energy absorption. Some of the property ranges of the composites are density (400–1500 kg/m3), compressive strength (1–26 MPa), and flexural strength (0.5–4.0 MPa).<ref>Karade SR. 2003. An Investigation of Cork Cement Composites. PhD Thesis. BCUC. Brunel University, UK.</ref>
Use in wine bottling
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As late as the mid-17th century, French vintners did not use cork stoppers, using instead oil-soaked rags stuffed into the necks of bottles.<ref>Prlewe, J. Wine From Grape to Glass. New York: Abbeville Press, 1999, p. 110.</ref>
Wine corks can be made of either a single piece of cork, or composed of particles, as in champagne corks; corks made of granular particles are called "agglomerated corks".<ref>Template:Cite web</ref>
Natural cork closures are used for about 80% of the 20 billion bottles of wine produced each year. After a decline in use as wine-stoppers due to the increase in the use of synthetic alternatives, cork wine-stoppers are making a comeback and currently represent approximately 60% of wine-stoppers in 2016.<ref>Template:Cite web</ref>
Because of the cellular structure of cork, it is easily compressed upon insertion into a bottle and will expand to form a tight seal. The interior diameter of the neck of glass bottles tends to be inconsistent, making this ability to seal through variable contraction and expansion an important attribute. However, unavoidable natural flaws, channels, and cracks in the bark make the cork itself highly inconsistent. In a 2005 closure study, 45% of corks showed gas leakage during pressure testing both from the sides of the cork as well as through the cork body itself.<ref>Template:Cite web</ref>
Since the mid-1990s, a number of wine brands have switched to alternative wine closures such as plastic stoppers, screw caps, or other closures. During 1972 more than half of the Australian bottled wine went bad due to corking. A great deal of anger and suspicion was directed at Portuguese and Spanish cork suppliers who were suspected of deliberately supplying bad cork to non-EEC wine makers to help prevent cheap imports. Cheaper wine makers developed the aluminium "Stelvin" cap with a polypropylene stopper wad. More expensive wines and carbonated varieties continued to use cork, although much closer attention was paid to the quality. Even so, some high premium makers prefer the Stelvin as it is a guarantee that the wine will be good even after many decades of ageing. Some consumers may have conceptions about screw caps being representative of lower quality wines, due to their cheaper price; however, in Australia, for example, much of the non-sparkling wine production now uses these Stelvin caps as a cork alternative, although some have recently switched back to cork citing issues using screw caps.<ref>Template:Cite web</ref>
The alternatives to cork have both advantages and disadvantages. For example, screwtops are generally considered to offer a trichloroanisole (TCA) free seal, but they also reduce the oxygen transfer rate between the bottle and the atmosphere to almost zero, which can lead to a reduction in the quality of the wine.Template:Citation needed TCA is the main documented cause of cork taint in wine. However, some in the wine industry say natural cork stoppers are important because they allow oxygen to interact with wine for proper aging, and are best suited for wines purchased with the intent to age.<ref>Template:Cite web</ref>
Stoppers which resemble natural cork very closely can be made by isolating the suberin component of the cork from the undesirable lignin, mixing it with the same substance used for contact lenses and an adhesive, and molding it into a standardized product, free of TCA or other undesirable substances.<ref>Template:Cite web, The Wine Society</ref> Composite corks with real cork veneers are used in cheaper wines.<ref>Template:Cite news</ref> Celebrated Australian wine writer and critic James Halliday has written that since a cork placed inside the neck of a wine bottle is 350-year-old technology, it is logical to explore other more modern and precise methods of keeping wine safe.<ref>Template:Cite web</ref>
The study "Analysis of the life cycle of Cork, Aluminum and Plastic Wine Closures," conducted by PricewaterhouseCoopers and commissioned by a major cork manufacturer, Amorim, concluded that cork is the most environmentally responsible stopper, in a one-year life cycle analysis comparison with plastic stoppers and aluminum screw caps.<ref>Template:Cite web</ref><ref>Template:Cite web</ref>
Other uses
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- On 28 November 2007, the Portuguese national postal service CTT issued the world's first postage stamp made of cork.<ref>Template:Cite web</ref><ref>Template:Cite web</ref>
- In musical instruments, particularly woodwind instruments, where it is used to fasten together segments of the instrument, making the seams airtight. Low quality conducting baton handles are also often made out of cork.
- In shoes, especially those using welt construction to improve climate control and comfort.
- Because it is impermeable and moisture-resistant, cork is often used as an alternative to leather in handbags, wallets, and other fashion items.
- To make bricks for the outer walls of houses, as in Portugal's pavilion at Expo 2000.
- As the core of both baseballs and cricket balls. A corked bat is made by replacing the interior of a baseball bat with cork – a practice known as "corking". It was historically a method of cheating at baseball; the efficacy of the practice is now discredited.
- In various forms, in spacecraft heat shields<ref>Template:Cite web</ref> and fairings.
- In the paper pick-up mechanisms in inkjet and laser printers.
- To make later-model pith helmets.<ref>Template:Cite web</ref>
- Hung from hats to keep insects away. (See cork hat)
- As a core material in sandwich composite construction.
- As the friction lining material of an automatic transmission clutch, as designed in certain mopeds.
- Alternative of wood or aluminium in automotive interiors.<ref>Template:Cite web</ref>
- Cork slabs are sometimes used by orchid growers as a natural mounting material.
- Cork paddles are used by glass blowers to manipulate and shape hot molten glass.
- Many racing bicycles have their handlebars wrapped in cork-based tape manufactured in a variety of colors.
- To make architectural models.
See also
[edit]Notes
[edit]References
[edit]- Margarida Pi i Contallé. 2006. Laboratory head in Manuel Serra Hongos y micotoxinas en tapones de corcho. Propuesta de límites micológicos aceptables
- Cork production corkfacts.com
- Instituto de Promoción del Corcho, Extremadura iprocor.org Template:In lang
- Analysis of the life cycle of Cork, Aluminium and Plastic Wine Closures
- Henley, Paul, BBC.com (18 September 2008). "Urging vintners to put a cork in it".
- PricewaterhouseCoopers/ECOBILAN (October 2008). Analysis of the life cycle of Cork, Aluminium and Plastic Wine Closures
- Cork - Forest in a Bottle. 2008.
External links
[edit]- Cork Quality Council
- Book review: To cork or not to cork
- Material Properties Data: Cork
- Cork Recycling Initiative. 2017.
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