Bohr magneton
System of units | Value | Unit |
---|---|---|
SITemplate:Physconst | Template:Physconst | J·T−1 |
Gaussian<ref name="O'Handley tati">
Template:Cite book (value updated to correspond to CODATA 2018)</ref> |
Template:Val | erg·G−1 |
eV/T<ref>
Template:Cite web</ref> |
Template:Val | eV·T−1 |
atomic units | Template:Sfrac | Template:Sfrac |
In atomic physics, the Bohr magneton (symbol Template:Math) is a physical constant and the natural unit for expressing the magnetic moment of an electron caused by its orbital or spin angular momentum.<ref> Template:Cite book</ref><ref> Template:Cite book</ref> In SI units, the Bohr magneton is defined as <math display="block">\mu_\mathrm{B} = \frac{e \hbar}{2 m_\mathrm{e}}</math> and in the Gaussian CGS units as <math display="block">\mu_\mathrm{B} = \frac{e \hbar}{2 m_\mathrm{e} c} ,</math> where
- Template:Mvar is the elementary charge,
- Template:Mvar is the reduced Planck constant,
- Template:Math is the electron mass,
- Template:Math is the speed of light.
History
[edit]The idea of elementary magnets is due to Walther Ritz (1907) and Pierre Weiss. Already before the Rutherford model of atomic structure, several theorists commented that the magneton should involve the Planck constant h.<ref name="Keith">Template:Cite book</ref> By postulating that the ratio of electron kinetic energy to orbital frequency should be equal to h, Richard Gans computed a value that was twice as large as the Bohr magneton in September 1911.<ref name="Heilbron">Template:Cite journal</ref> At the First Solvay Conference in November that year, Paul Langevin obtained a value of <math>e\hbar/(2m_\mathrm{e})</math>.<ref> Template:Cite conference</ref> Langevin assumed that the attractive force was inversely proportional to distance to the power <math>n+1,</math> and specifically <math>n=1.</math><ref>Note that the formula <math display="block">I_o=\frac m{Me}\frac h{8\pi}\frac n{n+2}</math> on page 404 should say <math display="block">I_o=\frac {Me}m\frac h{8\pi}\frac n{n+2}.</math></ref>
The Romanian physicist Ștefan Procopiu had obtained the expression for the magnetic moment of the electron in 1913.<ref name = proc1>Template:Cite journal</ref><ref name = proc2>Template:Cite journal</ref> The value is sometimes referred to as the "Bohr–Procopiu magneton" in Romanian scientific literature.<ref>Template:Cite web</ref> The Weiss magneton was experimentally derived in 1911 as a unit of magnetic moment equal to Template:Val joules per tesla, which is about 20% of the Bohr magneton.
In the summer of 1913, the values for the natural units of atomic angular momentum and magnetic moment were obtained by the Danish physicist Niels Bohr as a consequence of his atom model.<ref name="Heilbron"/><ref> Template:Cite book</ref> In 1920, Wolfgang Pauli gave the Bohr magneton its name in an article where he contrasted it with the magneton of the experimentalists which he called the Weiss magneton.<ref name="Keith"/>
Theory
[edit]A magnetic moment of an electron in an atom is composed of two components. First, the orbital motion of an electron around a nucleus generates a magnetic moment by Ampère's circuital law. Second, the inherent rotation, or spin, of the electron has a spin magnetic moment.
In the Bohr model of the atom, for an electron that is in the orbit of lowest energy, its orbital angular momentum has magnitude equal to the reduced Planck constant, denoted ħ. The Bohr magneton is the magnitude of the magnetic dipole moment of an electron orbiting an atom with this angular momentum.<ref>Template:Cite book</ref>
The spin angular momentum of an electron is Template:Sfracħ, but the intrinsic electron magnetic moment caused by its spin is also approximately one Bohr magneton, which results in the electron spin g-factor, a factor relating spin angular momentum to corresponding magnetic moment of a particle, having a value of approximately 2.<ref>Template:Cite book</ref>
See also
[edit]- Anomalous magnetic moment
- Electron magnetic moment
- Bohr radius
- Nuclear magneton
- Parson magneton
- Physical constant
- Zeeman effect