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{{short description|None}} In thermodynamics, a physical property is any property that is measurable, and whose value describes a state of a physical system. Thermodynamic properties are defined as characteristic features of a system, capable of specifying the system's state. Some constants, such as the [[ideal gas constant]], {{mvar|R}}, do not describe the state of a system, and so are not properties. On the other hand, some constants, such as {{mvar|K<sub>f</sub>}} (the freezing point depression constant, or [[cryoscopic constant]]), depend on the identity of a substance, and so may be considered to describe the state of a system, and therefore may be considered physical properties. "Specific" properties are expressed on a per mass basis. If the units were changed from per mass to, for example, per mole, the property would remain as it was (i.e., [[Intensive and extensive properties|intensive or extensive]]). ==Regarding work and heat== [[Work (thermodynamics)|Work]] and [[heat]] are not thermodynamic properties, but rather ''[[process function|process quantities]]:'' flows of energy across a system boundary. Systems do not ''contain'' work, but can ''perform'' work, and likewise, in formal thermodynamics, systems do not ''contain'' heat, but can ''transfer'' heat. Informally, however, a difference in the energy of a system that occurs solely because of a difference in its temperature is commonly called ''heat'', and the energy that flows across a boundary as a result of a temperature difference is "heat". Altitude (or elevation) is usually not a thermodynamic property. Altitude can help specify the location of a system, but that does not describe the state of the system. An exception would be if the effect of gravity need to be considered in order to describe a state, in which case altitude could indeed be a thermodynamic property. {| class="wikitable" style="text-align:center" |+[[Thermodynamic]] [[physical property|properties]] and their characteristics !Property!!Symbol!!Units!![[Intensive and extensive properties|Extensive?]]!![[Intensive and extensive properties|Intensive?]]!![[Conjugate variables (thermodynamics)|Conjugate]]!![[Thermodynamic potential|Potential?]] |- |style="text-align:left"|[[activity (chemistry)|Activity]] |{{mvar|a}} |{{spaced ndash}} | |{{aye}} | | |- |style="text-align:left"|[[Chemical potential]] |{{mvar|μ<sub>i</sub>}} |kJ/mol | |{{aye}} |Particle<br /> number {{mvar|N<sub>i</sub>}} | |- |style="text-align:left"|[[Compressibility]] <small>(adiabatic)</small> |{{mvar|β<sub>S</sub>}}, {{mvar|κ}} |Pa<sup>−1</sup> | |{{aye}} | | |- |style="text-align:left"|[[Compressibility]] <small>(isothermal)</small> |{{mvar|β<sub>T</sub>}}, {{mvar|κ}} |Pa<sup>−1</sup> | |{{aye}} | | |- |style="text-align:left"|[[Cryoscopic constant]]<ref>{{Citation | last = Aylward | first = Gordon | author-link = Gordon Aylward | last2 = Findlay | first2 = Tristan | author2-link = Tristan Findlay | title = SI Chemical Data 5th ed. | place = Sweden | publisher = John Wiley & Sons | year = 2002 | edition = 5 | pages = 202 | isbn = 0-470-80044-5}}</ref> |{{mvar|K<sub>f</sub>}} |K·kg/mol | |{{aye}} | | |- |style="text-align:left"|[[Density]] |{{mvar|ρ}} |kg/m<sup>3</sup> | |{{aye}} | | |- |style="text-align:left"|[[Ebullioscopic constant]] |{{mvar|K<sub>b</sub>}} |K·kg/mol | |{{aye}} | | |- |style="text-align:left"|[[Enthalpy]] |{{mvar|H}} |J |{{aye}} | | |{{aye}} |- |style="text-align:left"|{{space|3}} [[Specific enthalpy]] |{{mvar|h}} |J/kg | |{{aye}} | | |- |style="text-align:left"|[[Entropy]] |{{mvar|S}} |J/K |{{aye}} | |Temperature {{mvar|T}} |{{aye}} <small>([[Free entropy|entropic]])</small> |- |style="text-align:left"|{{space|3}} Specific entropy |{{mvar|s}} |J/(kg K) | |{{aye}} | | |- |style="text-align:left"|[[Fugacity]] |{{mvar|f}} |N/m<sup>2</sup> | |{{aye}} | | |- |style="text-align:left"|[[Gibbs free energy]] |{{mvar|G}} |J |{{aye}} | | |{{aye}} |- |style="text-align:left"|{{space|3}} Specific Gibbs free energy |{{mvar|g}} |J/kg | |{{aye}} | | |- |style="text-align:left"|[[Free entropy|Gibbs free entropy]] |{{math|Ξ}} |J/K |{{aye}} | | |{{aye}} <small>([[Free entropy|entropic]])</small> |- |style="text-align:left"|[[Grand potential|Grand / Landau potential]] |{{math|Ω}} |J |{{aye}} | | |{{aye}} |- |style="text-align:left"|[[Heat capacity]] <small>(constant pressure)</small> |{{mvar|C<sub>p</sub>}} |J/K |{{aye}} | | | |- |style="text-align:left"|{{space|3}} [[Specific heat capacity]]<br/>{{space|6}}<small>(constant pressure)</small> |{{mvar|c<sub>p</sub>}} |J/(kg·K) | |{{aye}} | | |- |style="text-align:left"|[[Heat capacity]] <small>(constant volume)</small> |{{mvar|C<sub>v</sub>}} |J/K |{{aye}} | | | |- |style="text-align:left"|{{space|3}} [[Specific heat capacity]]<br/>{{space|6}}<small>(constant volume)</small> |{{mvar|c<sub>v</sub>}} |J/(kg·K) | |{{aye}} | | |- |style="text-align:left"|[[Helmholtz free energy]] |{{mvar|A}}, {{mvar|F}} |J |{{aye}} | | |{{aye}} |- |style="text-align:left"|[[Free entropy|Helmholtz free entropy]] |{{math|Φ}} |J/K |{{aye}} | | |{{aye}} <small>([[Free entropy|entropic]])</small> |- |style="text-align:left"|[[Internal energy]] |{{mvar|U}} |J |{{aye}} | | |{{aye}} |- |style="text-align:left"|{{space|3}} [[Specific internal energy]] |{{mvar|u}} |J/kg | |{{aye}} | | |- |style="text-align:left"|[[Internal pressure]] |{{mvar|π<sub>T</sub>}} |Pa | |{{aye}} | | |- |style="text-align:left"|[[Mass]] |{{mvar|m}} |kg |{{aye}} | | | |- |style="text-align:left"|[[Particle number]] |{{mvar|N<sub>i</sub>}} |{{spaced ndash}} |{{aye}} | |Chemical<br /> potential {{mvar|μ<sub>i</sub>}} | |- |style="text-align:left"|[[Pressure]] |{{mvar|p}} |Pa | |{{aye}} |Volume {{mvar|V}} | |- |style="text-align:left"|[[Thermodynamic temperature|Temperature]] |{{mvar|T}} |K | |{{aye}} |Entropy {{mvar|S}} | |- |style="text-align:left"|[[Thermal conductivity]] |{{mvar|k}} |W/(m·K) | |{{aye}} | | |- |style="text-align:left"|[[Thermal diffusivity]] |{{mvar|α}} |m<sup>2</sup>/s | |{{aye}} | | |- |style="text-align:left"|[[Thermal expansion]] <small>(linear)</small> |{{mvar|α<sub>L</sub>}} |K<sup>−1</sup> | |{{aye}} | | |- |style="text-align:left"|[[Thermal expansion]] <small>(area)</small> |{{mvar|α<sub>A</sub>}} |K<sup>−1</sup> | |{{aye}} | | |- |style="text-align:left"|[[Thermal expansion]] <small>(volumetric)</small> |{{mvar|α<sub>V</sub>}} |K<sup>−1</sup> | |{{aye}} | | |- |style="text-align:left"|[[Vapor quality]]<ref name=boles>{{Cite book | last1 = Cengel | first1 = Yunus A. | last2 = Boles | first2 = Michael A. | title = Thermodynamics: an engineering approach | year = 2002 | publisher = McGraw-Hill | location = Boston | isbn = 0-07-121688-X | pages = 79}}</ref> |{{mvar|χ}} |{{spaced ndash}} | |{{aye}} | | |- |style="text-align:left"|[[Volume (thermodynamics)|Volume]] |{{mvar|V}} |m<sup>3</sup> |{{aye}} | |Pressure {{mvar|P}} | |- |style="text-align:left"|{{spaces|3}} [[Specific volume]] |{{mvar|ν}} |m<sup>3</sup>/kg | |{{aye}} | | |} ==See also== * [[Conjugate variables (thermodynamics)|Conjugate variables]] * [[Dimensionless number]]s * [[Intensive and extensive properties]] * [[Thermodynamic databases for pure substances]] * [[Thermodynamic variable]] ==References== {{reflist}} {{DEFAULTSORT:List Of Thermodynamic Properties}} [[Category:Physics-related lists|Thermodynamic properties]]
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