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{{Infobox mineral | name = Greenockite | category = [[Sulfide mineral]] | image = Greenockite-259580.jpg | imagesize = 260px | caption = Greenockite crystals from Tsumeb Mine, Namibia (Picture width 1 mm) | formula = CdS | IMAsymbol = Gnk<ref>{{Cite journal|last=Warr|first=L.N.|date=2021|title=IMAβCNMNC approved mineral symbols|journal=Mineralogical Magazine|volume=85|issue=3|pages=291β320|doi=10.1180/mgm.2021.43|bibcode=2021MinM...85..291W|s2cid=235729616|doi-access=free}}</ref> | molweight = 144.48 | strunz = 2.CB.45 | system = [[Hexagonal crystal system|Hexagonal]] | class = Dihexagonal pyramidal (6mm) <br/><small>(same [[H-M symbol]])</small> | symmetry = ''P6''<sub>3</sub>mc | unit cell = a = 4.136 <br/>c = 6.713 [Γ ]; Z = 2 | color = Honey yellow, citron yellow, orange yellow | habit = Colloform β forming from a gel or colloidal mass; encrustations β forms crust-like aggregates on matrix; radial β crystals radiate from a center without producing stellar forms (e.g. stibnite) | twinning = Rare on {11{{overline|2}}2} forming trillings | cleavage = Distinct on {11{{overline|2}}2}, imperfect on {0001} | fracture = Conchoidal | tenacity = Brittle | mohs = 3.0β3.5 | luster = Adamantine to resinous | refractive = n<sub>Ο</sub> = 2.529 n<sub>Ξ΅</sub> = 2.506 | opticalprop = Uniaxial (β) | birefringence = Ξ΄ = 0.023 | pleochroism = Weak | streak = Yellow orange to brick red | gravity = 4.8β4.9 | melt = | fusibility = | diagnostic = | solubility = | diaphaneity = Nearly opaque to translucent | fluorescence = yellow-orange fluorescence under UV when rich in zinc{{citation needed|date=May 2014}} | other = Toxic | references = <ref name=HBM>[http://rruff.geo.arizona.edu/doclib/hom/greenockite.pdf Handbook of Mineralogy]</ref><ref name=Mindat>[http://www.mindat.org/min-1746.html Mindat]</ref><ref name=Webmin>[http://webmineral.com/data/Greenockite.shtml Webmineral]</ref> | SMILES = [CdH2-2]1[S+2]47[CdH-2]2[S+2][CdH-2]3[S+2]8([CdH2-2][SH+2]([CdH2-2]4)[CdH2-2]6)[CdH-2]4[S+2][CdH-2]5[S+2]6([CdH2-2]6)[Cd-2]78[S+2]78[CdH-2]([SH+2]69)[SH+2]5[CdH2-2][SH+2]4[CdH-2]7[SH+2]3[CdH2-2][SH+2]2[CdH-2]8[SH+2]1[CdH2-2]9 | Jmol = [CdH2-2]1[SH+2]([CdH2-2]6)[CdH2-2][SH+2]7[CdH-2]2[S+2][Cd-2]3([S+2][CdH-2]9[S+2]5)[S+2]18[Cd-2]45[S+2][CdH-2]5[SH+2]6[Cd-2]78[S+2]78[CdH2-2][SH+2]5[CdH2-2][S+2]4([CdH2-2][SH+2]9[CdH2-2]4)[CdH-2]7[S+2]34[CdH2-2][SH+2]2[CdH2-2]8 }} '''Greenockite''', also ''cadmium blende'' or ''cadmium ochre'' (obsolete) is a rare [[cadmium]] bearing metal [[sulfide mineral]] consisting of [[cadmium sulfide]] (CdS) in crystalline form. Greenockite crystallizes in the [[Hexagonal crystal system|hexagonal]] system. It occurs as massive encrustations and as hemimorphic six-sided pyramidal crystals which vary in color from a honey yellow through shades of red to brown. The [[Mohs hardness]] is 3 to 3.5 and the [[specific gravity]] is 4.8 to 4.9. Greenockite belongs to the [[wurtzite]] group and is isostructural with it at high temperatures. It is also isostructural with [[sphalerite]] at low temperatures. It occurs with other sulfide minerals such as sphalerite and [[galena]], and is the only ''ore mineral'' of cadmium. Most cadmium is recovered as a byproduct of copper, zinc, and lead mining. It is also known from the lead-zinc districts of the central [[United States]]. It was first recognized in 1840 in [[Bishopton, Renfrewshire|Bishopton]], [[Scotland]], during the cutting of a tunnel for the [[Glasgow, Paisley and Greenock Railway]]. The mineral was named after the land owner [[Charles Cathcart, 2nd Earl Cathcart|Lord Greenock]] (1783β1859).<ref name=Mindat/><ref>{{Cite web |url=http://www.hmag.gla.ac.uk/John/huntmin/greenock.htm |title=Glasgow museum site |access-date=2005-08-02 |archive-url=https://web.archive.org/web/20120716222609/http://www.hmag.gla.ac.uk/John/huntmin/greenock.htm |archive-date=2012-07-16 |url-status=dead }}</ref> ==Use== Greenockite, also known as "cadmium ochre", was used as a yellow pigment prior to cadmium being recognized as a [[toxic]] element. The extracted cadmium has various industrial use, such as electrical nickel-cadmium (NiCd) [[rechargeable batteries]], [[electroplating]], high temp alloys, plating steel and other metals that corrode easily, and use in control rods for some nuclear reactors. ==References== {{Reflist}} *[https://web.archive.org/web/20051106000206/http://mineral.galleries.com/minerals/sulfides/greenock/greenock.htm Mineral galleries] ==External links== *{{Commons category-inline}} [[File:Greenockite-3D-balls.png|thumb|left|[[Crystal structure]] of greenockite]] [[Category:Cadmium minerals]] [[Category:Sulfide minerals]] [[Category:Renfrewshire]] [[Category:Hexagonal minerals]] [[Category:Minerals in space group 186]] [[Category:Blendes]] {{-}} {{sulfide-mineral-stub}}
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