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{{short description|Industry (branch), which is engaged in the manufacturing of chemical products}} [[File:FEMA - 37677 - Aerial of a Louisiana oil refinary repaired since Katrina.jpg|thumb|upright=1.35|Oil refinery in [[Louisiana]] β an example of chemical industry]] The '''chemical industry''' comprises the [[company|companies]] and other organizations that develop and produce industrial, specialty and other [[chemical]]s. Central to the modern [[world economy]], the chemical industry converts [[raw materials]] ([[Petroleum|oil]], [[natural gas]], [[air]], [[water]], [[metal]]s, and [[mineral]]s) into [[commodity chemicals]] for industrial and consumer [[Product (business)|products]]. It includes industries for [[petrochemical industry|petrochemical]]s such as [[polymer]]s for [[Plastics industry|plastic]]s and [[synthetic fiber]]s; [[Inorganic compound|inorganic chemical]]s such as [[acid]]s and [[alkali]]s; [[Agrochemical|agricultural chemicals]] such as [[fertilizer]]s, [[pesticide]]s and [[herbicide]]s; and other categories such as [[industrial gas]]es, [[speciality chemicals]] and [[Pharmaceutical industry|pharmaceuticals]]. Various professionals are involved in the chemical industry including chemical engineers, chemists and lab technicians. ==History== Although chemicals were made and used throughout history, the birth of the heavy chemical industry (production of chemicals in large quantities for a variety of uses) coincided with the beginnings of the [[Industrial Revolution]]. ===Industrial Revolution=== One of the first chemicals to be produced in large amounts through industrial processes was [[sulfuric acid]]. In 1736 pharmacist [[Joshua Ward]] developed a process for its production that involved heating sulfur with saltpeter, allowing the sulfur to oxidize and combine with water. It was the first practical production of sulphuric acid on a large scale. [[John Roebuck]] and [[Samuel Garbett]] were the first to establish a large-scale factory in [[Prestonpans|Prestonpans, Scotland]], in 1749, which used leaden condensing chambers for the manufacture of sulfuric acid.<ref>{{cite book | author = Derry, Thomas Kingston |author2=Williams, Trevor I. | year = 1993 | title = A Short History of Technology: From the Earliest Times to A.D. 1900 | location = New York | publisher = Dover }}</ref><ref>{{cite web | title = Sulfuric Acid: Pumping Up the Volume | author = Kiefer, David M. | year = 2001 | publisher = American Chemical Society | url = http://pubs.acs.org/subscribe/journals/tcaw/10/i09/html/09chemch.html | access-date = 2008-04-21}}</ref> [[File:StRolloxChemical 1831.jpg|thumb|[[Charles Tennant]]'s St. Rollox Chemical Works in 1831, then the biggest chemical enterprise in the world.]] In the early 18th century, cloth was bleached by treating it with stale [[urine]] or [[sour milk]] and exposing it to [[sunlight]] for long periods of time, which created a severe bottleneck in production. Sulfuric acid began to be used as a more efficient agent as well as [[lime (material)|lime]] by the middle of the century, but it was the discovery of [[bleaching powder]] by [[Charles Tennant]] that spurred the creation of the first great chemical industrial enterprise. His powder was made by reacting [[chlorine]] with dry [[slaked lime]] and proved to be a cheap and successful product. He opened the [[St Rollox Chemical Works]], north of [[Glasgow]], and production went from just 52 tons in 1799 to almost 10,000 tons just five years later.<ref>{{cite web | title=The Chemical Industries In The UK|publisher = American Chemical Society|url=http://the-environment.org.uk/bristish_isles/history_chemical_industry_UK.html|access-date = 2013-04-21}}</ref> [[Soda ash]] was used since ancient times in the production of [[glass]], [[textile]], [[soap]], and [[paper]], and the source of the [[potash]] had traditionally been [[wood]] ashes in [[Western Europe]]. By the 18th century, this source was becoming uneconomical due to deforestation, and the [[French Academy of Sciences]] offered a prize of 2400 [[French livre|livres]] for a method to produce alkali from sea salt ([[sodium chloride]]). The [[Leblanc process]] was patented in 1791 by [[Nicolas Leblanc]] who then built a Leblanc plant at [[Saint-Denis, Seine-Saint-Denis|Saint-Denis]].<ref name="Aftalion11">{{Harvnb|Aftalion|1991|pp=11β13}}</ref> He was denied his prize money because of the [[French Revolution]].<ref name='Aftalion14'/> In Britain, the Leblanc process became popular.<ref name='Aftalion14'>{{Harvnb|Aftalion|1991|pp=14β16}}</ref> [[William Losh]] built the first soda works in Britain at the [[Losh, Wilson and Bell]] works on the [[River Tyne]] in 1816, but it remained on a small scale due to large [[tariff]]s on salt production until 1824. When these tariffs were repealed, the British soda industry was able to rapidly expand. [[James Muspratt]]'s chemical works in [[Liverpool]] and Charles Tennant's complex near [[Glasgow]] became the largest chemical production centres anywhere. By the 1870s, the British soda output of 200,000 tons annually exceeded that of all other nations in the world combined. [[File:Ernest Solvay.jpg|thumb|left|upright=0.75|[[Ernest Solvay]], patented an improved industrial method for the manufacture of [[soda ash]].]] These huge factories began to produce a greater diversity of chemicals as the [[Industrial Revolution]] matured. Originally, large quantities of alkaline waste were vented into the environment from the production of soda, provoking one of the [[Alkali Act 1863|first pieces of environmental legislation]] to be passed in 1863. This provided for close inspection of the factories and imposed heavy fines on those exceeding the limits on pollution. Methods were devised to make useful byproducts from the alkali. The [[Solvay process]] was developed by the [[Belgium|Belgian]] industrial chemist [[Ernest Solvay]] in 1861. In 1864, Solvay and his brother Alfred constructed a plant in [[Charleroi]] Belgium. In 1874, they expanded into a larger plant in [[Nancy, France|Nancy]], France. The new process proved more economical and less polluting than the Leblanc method, and its use spread. In the same year, [[Ludwig Mond]] visited Solvay to acquire the rights to use his process, and he and [[John Tomlinson Brunner|John Brunner]] formed [[Brunner Mond|Brunner, Mond & Co.]], and built a Solvay plant at [[Winnington]], England. Mond was instrumental in making the Solvay process a commercial success. He made several refinements between 1873 and 1880 that removed byproducts that could inhibit the production of sodium carbonate in the process. The manufacture of chemical products from [[fossil fuels]] began at scale in the early 19th century. The [[coal tar]] and [[ammonia solution|ammoniacal liquor]] residues of [[coal gas]] manufacture for [[gas lighting]] began to be processed in 1822 at the [[Bonnington Chemical Works]] in [[Edinburgh]] to make [[naphtha]], pitch oil (later called [[creosote]]), [[pitch (resin)|pitch]], lampblack ([[carbon black]]) and sal ammoniac ([[ammonium chloride]]).<ref>{{Cite journal|last=Ronalds|first=B.F.|date=2019|title=Bonnington Chemical Works (1822β1878): Pioneer Coal Tar Company|journal=International Journal for the History of Engineering & Technology|volume=89|issue=1β2|pages=73β91|doi=10.1080/17581206.2020.1787807|s2cid=221115202}}</ref> [[Ammonium sulphate]] fertiliser, [[Bitumen|asphalt]] [[road surface|road surfacing]], coke oil and [[coke (fuel)|coke]] were later added to the product line. ===Expansion and maturation=== The late 19th century saw an explosion in both the quantity of production and the variety of chemicals that were manufactured. Large chemical industries arose in Germany and later in the United States. [[File:BASF Werk Ludwigshafen 1866.JPG|thumb|right|The factories of the German firm [[BASF]], in 1866.]] Production of artificial manufactured [[fertilizer]] for [[agriculture]] was pioneered by Sir [[John Lawes]] at his purpose-built [[Rothamsted Research]] facility. In the 1840s he established large works near [[London]] for the manufacture of [[Monocalcium phosphate|superphosphate of lime]]. Processes for the [[vulcanization of rubber]] were patented by [[Charles Goodyear]] in the United States and [[Thomas Hancock (inventor)|Thomas Hancock]] in England in the 1840s. The first synthetic dye was discovered by [[William Henry Perkin]] in [[London]]. He partly transformed [[aniline]] into a crude mixture which, when extracted with alcohol, produced a substance with an intense purple colour. He also developed the first synthetic perfumes. German industry quickly began to dominate the field of synthetic dyes. The three major firms [[BASF]], [[Bayer AG|Bayer]], and [[Hoechst AG|Hoechst]] produced several hundred different dyes. By 1913, German industries produced almost 90% of the world's supply of dyestuffs and sold approximately 80% of their production abroad.<ref>{{Harvnb|Aftalion|1991|p=104}}, {{Harvnb|Chandler|2005|p=475}}</ref> In the United States, [[Herbert Henry Dow]]'s use of electrochemistry to produce chemicals from [[brine]] was a commercial success that helped to promote the country's chemical industry.<ref>{{Cite web|url=https://www.acs.org/content/acs/en/education/whatischemistry/landmarks/bromineproduction.html|title=Electrolytic Production of Bromine β National Historic Chemical Landmark β American Chemical Society|website=American Chemical Society|access-date=2016-10-10}}</ref> The [[petrochemical]] industry can be traced back to the oil works of Scottish chemist [[James Young (Scottish chemist)|James Young]], and Canadian [[Abraham Pineo Gesner]]. The first plastic was invented by [[Alexander Parkes]], an English [[metallurgy|metallurgist]]. In 1856, he patented [[Parkesine]], a [[celluloid]] based on [[nitrocellulose]] treated with a variety of solvents.<ref>{{cite book |title=Patents for inventions |year=1857 |publisher=UK Patent office|page=255 |url=https://books.google.com/books?id=0nCoU-2tAx8C&pg=PA255}}</ref> This material, exhibited at the 1862 London International Exhibition, anticipated many of the modern aesthetic and utility uses of plastics. The industrial production of [[soap]] from vegetable oils was started by [[William Lever]] and his brother [[James Darcy Lever|James]] in 1885 in [[Lancashire]] based on a modern chemical process invented by William Hough Watson that used [[glycerin]] and [[vegetable oil]]s.<ref name="watson">{{cite web |author=Jeannifer Filly Sumayku |url=http://www.thepresidentpost.com/?p=2621 |title=Unilever: Providing Enjoyable and Meaningful Life to Customers |archive-url=https://web.archive.org/web/20131215041539/http://www.thepresidentpost.com/?p=2621 |archive-date=2013-12-15 |url-status=usurped |work=The President Post |date=22 March 2010}}</ref> By the 1920s, chemical firms consolidated into large [[conglomerate (company)|conglomerate]]s; [[IG Farben]] in Germany, [[RhΓ΄ne-Poulenc]] in France and [[Imperial Chemical Industries]] in Britain. [[DuPont|Dupont]] became a major chemicals firm in the early 20th century in America. ==Products== Polymers and plastics such as [[polyethylene]], [[polypropylene]], [[polyvinyl chloride]], [[polyethylene terephthalate]], [[polystyrene]] and [[polycarbonate]] comprise about 80% of the industry's output worldwide.<ref name=Chemistry>{{cite book|title=Chemistry in Daily Life|last=Singh|first=Kirpal|publisher=PHI Learning Private Limited|isbn=978-81-203-4617-8|date=July 2012|page=132|chapter=17.2}}</ref> Chemicals are used in many different consumer goods, and are also used in many different sectors. This includes agriculture manufacturing, construction, and service industries.<ref name=Chemistry /> Major industrial customers include rubber and [[plastic]] products, [[textile]]s, apparel, petroleum refining, [[paper chemicals|pulp and paper]], and primary metals. Chemicals are nearly a $5 trillion global enterprise, and the EU and U.S. chemical companies are the world's largest producers.<ref>{{Cite web |title=Chemicals Market Size, Trends and Global Forecast To 2032 |url=https://www.thebusinessresearchcompany.com/report/chemicals-global-market-report |access-date=2023-08-04 |website=www.thebusinessresearchcompany.com}}</ref> Sales of the chemical business can be divided into a few broad categories, including basic chemicals (about 35% β 37% of dollar output), life sciences (30%), specialty chemicals (20% β 25%) and consumer products (about 10%).<ref name=":0">{{cite web|publisher=Technofunc|title=Sectors of Chemical Industry|url=http://www.technofunc.com/index.php/domain-knowledge/chemicals-industry/item/sectors-of-chemical-industry|access-date=16 September 2013}}</ref> ===Overview=== [[File:Slovnaft - new polypropylene plant PP3.JPG|thumb|upright=1.35|New polypropylene plant PP3 in the [[Slovnaft]] oil refinery ([[Bratislava]], Slovakia)]] Basic chemicals, or "commodity chemicals" are a broad chemical category including polymers, bulk petrochemicals and intermediates, other derivatives and basic industrials, [[inorganic chemistry|inorganic chemicals]], and [[fertilizer]]s. '''Polymers''' are the largest revenue segment and includes all categories of [[plastics industry|plastics]] and human-made fibers. The major markets for plastics are [[packaging]], followed by home construction, containers, appliances, pipe, transportation, toys, and games. * The largest-volume polymer product, [[polyethylene]] (PE), is used mainly in packaging films and other markets such as milk bottles, containers, and pipe. * [[Polyvinyl chloride]] (PVC), another large-volume product, is principally used to make piping for construction markets as well as siding and, to a much smaller extent, transportation and packaging materials. * [[Polypropylene]] (PP), similar in volume to PVC, is used in markets ranging from packaging, appliances, and containers to clothing and carpeting. * [[Polystyrene]] (PS), another large-volume plastic, is used principally for appliances and packaging as well as toys and recreation. * The leading [[synthetic fiber|human-made fibers]] include [[polyester]], [[nylon]], polypropylene, and [[Acrylic fiber|acrylics]], with applications including apparel, home furnishings, and other industrial and consumer use. Principal raw materials for polymers are bulk petrochemicals like ethylene, propylene and benzene. [[Petrochemicals]] and intermediate chemicals are primarily made from [[liquefied petroleum gas]] (LPG), [[natural gas]] and [[crude oil]] fractions. Large volume products include [[ethylene]], [[propylene]], [[benzene]], [[toluene]], [[xylenes]], [[methanol]], [[vinyl chloride monomer]] (VCM), [[styrene]], [[butadiene]], and [[ethylene oxide]]. These basic or commodity chemicals are the starting materials used to manufacture many [[polymer]]s and other more complex organic chemicals particularly those that are made for use in the [[specialty chemicals]] category. '''Other derivatives''' and basic industrials include [[synthetic rubber]], [[surfactant]]s, [[dye]]s and [[pigment]]s, [[turpentine]], [[resin]]s, [[carbon black]], [[explosive]]s, and rubber products and contribute about 20 percent of the basic chemicals' external sales. '''[[inorganic chemistry|Inorganic chemicals]]''' (about 12% of the revenue output) make up the oldest of the chemical categories. Products include [[salt]], [[chlorine]], [[caustic soda]], [[soda ash]], acids (such as [[nitric acid]], [[phosphoric acid]], and [[sulfuric acid]]), [[titanium dioxide]], and [[hydrogen peroxide]]. '''[[Fertilizers]]''' are the smallest category (about 6 percent) and include [[phosphate]]s, [[ammonia]], and [[potash]] chemicals. ===Life sciences=== Life sciences (about 30% of the dollar output of the chemistry business) include differentiated chemical and biological substances, [[pharmaceutical]]s, diagnostics, [[veterinary medicine|animal health products]], [[vitamin]]s, and [[pesticides]]. While much smaller in volume than other chemical sectors, their products tend to have high prices β over ten dollars per pound β growth rates of 1.5 to 6 times [[GDP]], and research and development spending at 15 to 25% of sales. Life science products are usually produced with high specifications and are closely scrutinized by government agencies such as the Food and Drug Administration. Pesticides, also called "crop protection chemicals", are about 10% of this category and include [[herbicides]], [[insecticide]]s, and [[fungicide]]s.<ref name=":0" /> ===Specialty chemicals=== [[Specialty chemicals]] are a category of relatively high-valued, rapidly growing chemicals with diverse end product markets. Typical growth rates are one to three times GDP with prices over a dollar per pound. They are generally characterized by their innovative aspects. Products are sold for what they can do rather than for what chemicals they contain. Products include electronic chemicals, [[industrial gas]]es, adhesives and sealants as well as coatings, industrial and institutional cleaning chemicals, and catalysts. In 2012, excluding fine chemicals, the $546 billion global specialty chemical market was 33% Paints, Coating and Surface Treatments, 27% Advanced Polymer, 14% Adhesives and Sealants, 13% additives, and 13% pigments and inks.<ref name="2012e">{{cite report|publisher=Marketline|title="Global Specialty Chemicals" |via=2012e.igem.org |url=http://2012e.igem.org/wiki/images/f/fb/Global_Specialty_Chemicals_Profile.pdf|date=May 2012|access-date=16 September 2012|archive-url=https://web.archive.org/web/20121115071331/http://2012e.igem.org/wiki/images/f/fb/Global_Specialty_Chemicals_Profile.pdf|archive-date=15 November 2012|df=dmy-all}}</ref> [[Speciality chemicals]] are sold as effect or performance chemicals. Sometimes they are mixtures of formulations, unlike "[[fine chemicals]]", which are almost always single-molecule products. ===Consumer products=== Consumer products include direct product sales of chemicals such as [[soap]]s, [[detergent]]s, and [[cosmetics]]. Typical growth rates are 0.8 to 1.0 times GDP.{{Citation needed|date=June 2023}} Consumers rarely come into contact with basic chemicals. Polymers and specialty chemicals are materials that they encounter everywhere daily. Examples are plastics, cleaning materials, cosmetics, paints and coatings, electronics, automobiles and the materials used in home construction.<ref name="2012e"/> These specialty products are marketed by chemical companies to the downstream manufacturing industries as [[pesticides]], [[Polymers|specialty polymers]], electronic chemicals, [[surfactants]], construction chemicals, industrial cleaners, [[Flavoring|flavours]] and [[fragrances]], specialty coatings, printing inks, water-soluble polymers, [[food additives]], [[paper chemicals]], oil field chemicals, plastic adhesives, [[adhesives]] and [[sealants]], [[Cosmetic ingredients|cosmetic chemicals]], [[Water treatment|water management chemicals]], [[catalysts]], and textile chemicals. Chemical companies rarely supply these products directly to the consumer. Annually the [[American Chemistry Council]] tabulates the US production volume of the top 100 chemicals. In 2000, the aggregate production volume of the top 100 chemicals totaled 502 million tons, up from 397 million tons in 1990. Inorganic chemicals tend to be the largest volume but much smaller in dollar revenue due to their low prices. The top 11 of the 100 chemicals in 2000 were [[sulfuric acid]] (44 million tons), [[nitrogen]] (34), [[ethylene]] (28), [[oxygen]] (27), [[Lime (material)|lime]] (22), [[ammonia]] (17), [[propylene]] (16), [[polyethylene]] (15), [[chlorine]] (13), [[phosphoric acid]] (13) and [[diammonium phosphate]]s (12).{{citation needed|date=January 2019}} ==Companies== {{main|List of largest chemical producers}} The largest chemical producers today are global companies with international operations and plants in numerous countries. Below is a list of the top 25 chemical companies by chemical sales in 2015. (Note: Chemical sales represent only a portion of total sales for some companies.) Top chemical companies by chemical sales in 2015.<ref>{{Cite periodical |url=http://cen.acs.org/articles/94/i30/CENs-Global-Top-50.html|title=C&EN's Global Top 50 chemical companies of 2015 |date= July 25, 2016 |volume= 94 |issue=30 |periodical= Chemical & Engineering News|last=Tullo|first=Alexander H. |access-date=2016-10-10}}</ref> {| class="wikitable" |- !Rank ! Company!!2015 Chemical Sales ([[United States dollar|USD]] in billions)!!Headquarters |- | 1 | [[BASF]] | $63.7 | style="text-align:center;" |{{flagicon|GER}}[[Ludwigshafen]], Germany |- | 2 | [[Dow Chemical Company]] | $48.8 | style="text-align:center;" |{{flagicon|United States}}[[Midland, Michigan]], United States |- |3 |[[China Petrochemical Corporation]] |$43.8 | style="text-align:center;" |{{flagicon|CHN}} [[Beijing]], China |- | 4 | [[SABIC]] | $34.3 | style="text-align:center;" |{{flagicon|SAU}}[[Riyadh]], Saudi Arabia |- | 5 | [[Formosa Plastics]] | $29.2 | style="text-align:center;" |{{flagicon|Taiwan}}[[Kaohsiung|Kaohsiung City]], Taiwan |- | 6 |[[Ineos]] | $28.5 | style="text-align:center;" |{{flagicon|UK}} [[London]], United Kingdom |- |7 |[[ExxonMobil]] |$28.1 | style="text-align:center;" |{{flagicon|United States}}[[Irving, Texas]], United States |- | 8 | [[LyondellBasell]] | $26.7 | style="text-align:center;" |{{flagicon|United States}}[[Houston]], [[Texas]], United States, and {{flagicon|UK}}[[London]], United Kingdom |- | 9 | [[Mitsubishi Chemical]] | $24.3 | style="text-align:center;" |{{flagicon|JPN}}[[Tokyo]], Japan |- | 10 | [[DuPont]] | $20.7 | style="text-align:center;" |{{flagicon|United States}}[[Wilmington, Delaware]], United States |- |11 |[[LG Chem]] |$18.2 | style="text-align:center;" |{{flagicon|KOR}} [[Seoul]], South Korea |- | 12 | [[Air Liquide]] | $17.3 | style="text-align:center;" |{{flagicon|FRA}}[[Paris]], France |- |13 |[[Linde Group]] |$16.8 | style="text-align:center;" |{{flagicon|GER}}[[Munich]], Germany and {{flagicon|United States}} [[New Jersey]], United States |- | 14 | [[AkzoNobel]] | $16.5 | style="text-align:center;" |{{flagicon|NED}}[[Amsterdam]], Netherlands |- | 15 | [[PTT Global Chemical]] | $16.2 | style="text-align:center;" |{{flagicon|THA}}[[Bangkok]], Thailand |- | 16 | [[Toray Industries]] | $15.5 | style="text-align:center;" |{{flagicon|JPN}}[[Tokyo]], Japan |- | 17 | [[Evonik Industries]] | $15.0 | style="text-align:center;" |{{flagicon|GER}}[[Essen]], Germany |- | 18 | [[PPG Industries]] | $14.2 | style="text-align:center;" |{{flagicon|United States}}[[Pittsburgh]], [[Pennsylvania]], United States |- |19 |[[Braskem]] |$14.2 | style="text-align:center;" |{{flagicon|BRA}} [[SΓ£o Paulo]], Brazil |- |20 |[[Yara International]] |$13.9 | style="text-align:center;" |{{flagicon|NOR}} [[Oslo]], Norway |- |21 |[[Covestro]] |$13.4 | style="text-align:center;" |{{flagicon|GER}}[[Leverkusen]], Germany |- |22 |[[Sumitomo Chemical]] |$13.3 | style="text-align:center;" |{{flagicon|JPN}}[[Tokyo]], Japan |- |23 |[[Reliance Industries]] |$12.9 | style="text-align:center;" |{{flagicon|IND}} [[Mumbai]], India |- |24 |[[Solvay S.A.|Solvay]] |$12.3 | style="text-align:center;" |{{flagicon|BEL}} [[Brussels]], Belgium |- | 25 | [[Bayer]] | $11.5 | style="text-align:center;" |{{flagicon|GER}}[[Leverkusen]], Germany |- |} == Technology == [[File:Turbine generator systems1.png|thumb|upright=1.35|This is a process diagram of a turbine generator. Engineers working to produce a sustainable process for use in the chemical industry need to know how to design a sustainable process in which the system can withstand or manipulate process-halting conditions such as heat, friction, pressure, emissions, and contaminants.]] From the perspective of chemical engineers, the chemical industry involves the use of [[chemical process]]es such as [[chemical reaction]]s and [[refining]] methods to produce a wide variety of solid, liquid, and gaseous materials. Most of these products serve to [[Manufacturing|manufacture]] other items, although a smaller number go directly to consumers. [[Solvent]]s, [[pesticide]]s, [[lye]], [[sodium carbonate|washing soda]], and [[portland cement]] provide a few examples of products used by consumers. The industry includes manufacturers of [[inorganic]]- and [[Organic chemistry|organic]]-industrial chemicals, ceramic products, petrochemicals, agrochemicals, polymers and rubber (elastomers), oleochemicals (oils, fats, and waxes), explosives, fragrances and flavors. Examples of these products are shown in the Table below. {| class="wikitable" |- !Product Type!!Examples |- | [[inorganic]] industrial | [[ammonia]], [[chlorine]], [[sodium hydroxide]], [[sulfuric acid]], [[nitric acid]] |- | [[Organic chemistry|organic]] industrial | [[acrylonitrile]], [[phenol]], [[ethylene oxide]], [[urea]] |- | [[ceramic]] products | [[silica]] brick, frit |- | [[petrochemical]]s | [[ethylene]], [[propylene]], [[benzene]], [[styrene]] |- | [[agrochemical]]s | [[fertilizers]], [[insecticides]], [[herbicides]] |- | [[polymer]]s | [[polyethylene]], [[Bakelite]], [[polyester]] |- | [[elastomer]]s | [[polyisoprene]], [[neoprene]], [[polyurethane]] |- | [[oleochemical]]s | [[lard]], [[soybean oil]], [[stearic acid]] |- | [[explosives]] | [[nitroglycerin]], [[ammonium nitrate]], [[nitrocellulose]] |- | [[fragrance]]s and [[Flavoring|flavor]]s | [[benzyl benzoate]], [[coumarin]], [[vanillin]] |- | [[industrial gas]]es | [[nitrogen]], [[oxygen]], [[acetylene]], [[nitrous oxide]] |} Related industries include [[petroleum]], [[glass]], [[paint]], [[ink]], [[sealant]], [[adhesive]], [[pharmaceutical]]s and [[food processing]]. Chemical processes such as chemical reactions operate in [[chemical plant]]s to form new substances in various types of reaction vessels. In many cases, the reactions take place in special corrosion-resistant equipment at elevated temperatures and pressures with the use of [[catalyst]]s. The products of these reactions are separated using a variety of techniques including [[distillation]] especially [[fractional distillation]], [[Precipitation (chemistry)|precipitation]], [[crystallization]], [[adsorption]], [[filtration]], [[Sublimation (chemistry)|sublimation]], and [[drying]]. The processes and products or products are usually tested during and after manufacture by dedicated instruments and on-site [[quality control]] [[Laboratory|laboratories]] to ensure safe operation and to assure that the product will meet required [[specification]]s. More organizations within the industry are implementing chemical compliance software to maintain quality products and [[manufacturing]] standards.<ref>{{cite web|title=Chemical and Agrochemical Enterprise Quality Management Software|url=http://www.spartasystems.com/industries/other-industries/chemical-and-agrochemical/|publisher=Sparta Systems, Inc.|access-date=20 March 2015|archive-date=7 October 2015|archive-url=https://web.archive.org/web/20151007070625/http://www.spartasystems.com/industries/other-industries/chemical-and-agrochemical/}}</ref> The products are packaged and delivered by many methods, including pipelines, tank-cars, and tank-trucks (for both solids and liquids), cylinders, drums, bottles, and boxes. Chemical companies often have a [[research-and-development]] laboratory for developing and testing products and processes. These facilities may include pilot plants and such research facilities may be located at a site separate from the production plant(s). == World chemical production == [[File:Colonne distillazione.jpg|thumb|right|Distillation columns]] The scale of chemical manufacturing tends to be organized from largest in volume ([[petrochemical]]s and [[commodity chemicals]]), to [[specialty chemicals]], and the smallest, [[fine chemicals]]. The petrochemical and commodity chemical manufacturing units are on the whole single product continuous processing plants. Not all petrochemical or commodity chemical materials are made in one single location, but groups of related materials often are to induce industrial symbiosis as well as material, energy and utility efficiency and other [[economies of scale]]. Those chemicals made on the largest of scales are made in a few manufacturing locations around the world, for example in [[Texas]] and [[Louisiana]] along the [[Gulf Coast of the United States]], on [[Teesside]] ([[United Kingdom]]), and in [[Rotterdam]] in the [[Netherlands]]. The large-scale manufacturing locations often have clusters of manufacturing units that share utilities and large-scale infrastructure such as [[power stations]], [[Port|port facilities]], and road and rail terminals. To demonstrate the clustering and integration mentioned above, some 50% of the United Kingdom's petrochemical and commodity chemicals are produced by the [[Northeast of England Process Industry Cluster]] on [[Teesside]]. Specialty chemical and fine chemical manufacturing are mostly made in discrete batch processes. These manufacturers are often found in similar locations but in many cases, they are to be found in multi-sector business parks. ===Continents and countries=== [[File:Kemira factory in Oulu Jun2011 001.jpg|thumb|[[Kemira]]'s chemical plant in [[Oulu]], Finland]] In the U.S. there are 170 major chemical companies.<ref>{{Cite book|url=https://books.google.com/books?id=6trCF6poRSQC&q=In+the+U.S.+there+are+170+major+chemical+companies.&pg=PA132|title=CHEMISTRY IN DAILY LIFE |last=SINGH |first=KIRPAL |date=2012-07-07|publisher=PHI Learning Pvt. Ltd.|isbn=978-81-203-4617-8|language=en}}</ref> They operate internationally with more than 2,800 facilities outside the U.S. and 1,700 foreign subsidiaries or affiliates operating. The U.S. chemical output is $750 billion a year. The U.S. industry records large trade surpluses and employs more than a million people in the United States alone. The chemical industry is also the second largest consumer of energy in manufacturing and spends over $5 billion annually on pollution abatement. In Europe, the chemical, plastics, and rubber sectors are among the largest industrial sectors.<ref>{{cite web |title=Our contribution to EU27 industry |url=https://cefic.org/a-pillar-of-the-european-economy/facts-and-figures-of-the-european-chemical-industry/our-contribution-to-eu-industry/ |website=cefic.org |access-date=28 October 2022}}</ref> Together they generate about 3.2 million jobs in more than 60,000 companies. Since 2000 the chemical sector alone has represented 2/3 of the entire manufacturing trade surplus of the EU. In 2012, the chemical sector accounted for 12% of the EU manufacturing industry's added value. Europe remains the world's biggest chemical trading region with 43% of the world's exports and 37% of the world's imports, although the latest data shows that Asia is catching up with 34% of the exports and 37% of imports.<ref>{{cite web|publisher=CEFIC|title=Facts and Figures 2012:The European chemicals industry in a worldwide perspective|url=http://www.cefic.org/Documents/FactsAndFigures/2012/Facts-and-Figures-2012-The-Brochure.pdf|access-date=5 August 2013|archive-date=4 March 2016|archive-url=https://web.archive.org/web/20160304070157/http://www.cefic.org/Documents/FactsAndFigures/2012/Facts-and-Figures-2012-The-Brochure.pdf|url-status=dead}}</ref> Even so, Europe still has a trading surplus with all regions of the world except Japan and China where in 2011 there was a chemical trade balance. Europe's trade surplus with the rest of the world today amounts to 41.7 billion Euros.<ref>{{cite news|first=Stan|last=Higgins|publisher=Chemical News|title=European Chemicals Industry: A review|url=http://www.nepic.co.uk/WebformFolder/IndiaChemicalNews_Issue3.pdf|date=April 2013|pages=18β20|access-date=2013-08-05|archive-url=https://web.archive.org/web/20150723230317/http://www.nepic.co.uk/WebformFolder/IndiaChemicalNews_Issue3.pdf|archive-date=2015-07-23}}</ref> Over the 20 years between 1991 and 2011, the European Chemical industry saw its sales increase from 295 billion Euros to 539 billion Euros, a picture of constant growth. Despite this, the European industry's share of the world chemical market has fallen from 36% to 20%. This has resulted from the huge increase in production and sales in emerging markets like India and China.<ref>{{cite web|publisher=CEFIC|title=Facts and Figures 2012:The European chemicals industry in a worldwide perspective|url=http://www.cefic.org/Documents/FactsAndFigures/2012/Facts-and-Figures-2012-The-Brochure.pdf|access-date=5 August 2013|page=6|archive-date=4 March 2016|archive-url=https://web.archive.org/web/20160304070157/http://www.cefic.org/Documents/FactsAndFigures/2012/Facts-and-Figures-2012-The-Brochure.pdf|url-status=dead}}</ref> The data suggest that 95% of this impact is from China alone. In 2012 the data from the European Chemical Industry Council shows that five European countries account for 71% of the EU's chemicals sales. These are Germany, France, the United Kingdom, Italy and the Netherlands.<ref>{{cite web|publisher=CEFIC|title=Facts and Figures 2012:The European chemicals industry in a worldwide perspective|url=http://www.cefic.org/Documents/FactsAndFigures/2012/Facts-and-Figures-2012-The-Brochure.pdf|access-date=5 August 2013|page=7|archive-date=4 March 2016|archive-url=https://web.archive.org/web/20160304070157/http://www.cefic.org/Documents/FactsAndFigures/2012/Facts-and-Figures-2012-The-Brochure.pdf|url-status=dead}}</ref> The chemical industry has seen growth in China, India, Korea, the Middle East, South East Asia, Nigeria and Brazil. The growth is driven by changes in feedstock availability and price, labor and energy costs, differential rates of economic growth and environmental pressures. Just as companies emerge as the main producers of the chemical industry, we can also look on a more global scale at how industrialized countries rank, with regard to the billions of dollars worth of production a country or region could export. Though the business of chemistry is worldwide in scope, the bulk of the world's $3.7 trillion chemical output is accounted for by only a handful of industrialized nations. The United States alone produced $689 billion, 18.6 percent of the total world chemical output in 2008.<ref name="r1">{{cite web|url=http://www.americanchemistry.com/s_acc/sec_directory.asp?CID=292&DID=747|title=Global Business of Chemistry|access-date=26 February 2016|archive-url=https://web.archive.org/web/20101019103305/http://americanchemistry.com/s_acc/sec_directory.asp?CID=292&DID=747|archive-date=2010-10-19}}</ref> {| class="wikitable" |- ! '''Global Chemical Shipments by Country/Region (billions of dollars)'''<ref name="r1" /> !! 1998 !! 1999 !! 2000 !! 2001 !! 2002 !! 2003 !! 2004 !! 2005 !! 2006 !! 2008 || 2009 |- | United States of America || 416.7 || 420.3 || 449.2 || 438.4 || 462.5 || 487.7 || 540.9 || 610.9 || 657.7 || 664.1 || 689.3 |- | Canada || 21.1 || 21.8 || 25.0 || 24.8 || 25.8 || 30.5 || 36.2 || 40.2 || 43.7 || 45.4 || 47.4 |- | Mexico || 19.1 || 21.0 || 23.8 || 24.4 || 24.3 || 23.5 || 25.6 || 29.2 || 32.0 || 33.4 || 37.8 |- |'''North America''' || '''456.9''' || '''463.1''' || '''498.0''' || '''487.6''' || '''512.6''' || '''541.7''' || '''602.7''' || '''680.3''' || '''733.4''' || '''742.8''' || '''774.6''' |- | |- | Brazil || 46.5 || 40.0 || 45.7 || 41.5 || 39.6 || 47.4 || 60.2 || 71.1 || 82.8 || 96.4 || 126.7 |- | Other || 59.2 || 58.1 || 60.8 || 63.4 || 58.6 || 62.9 || 69.9 || 77.2 || 84.6 || 89.5 || 102.1 |- | '''Latin America''' || '''105.7''' || '''98.1''' || '''106.5''' || '''104.9''' || '''98.2''' || '''110.3''' || '''130.0''' || '''148.3''' || '''167.4''' || '''185.9''' || '''228.8''' |- | |- | | Germany || 124.9 || 123.2 || 118.9 || 116.1 || 120.1 || 148.1 || 168.6 || 178.6 || 192.5 || 229.5 || 263.2 |- | France || 79.1 || 78.5 || 76.5 || 76.8 || 80.5 || 99.6 || 111.1 || 117.5 || 121.3 || 138.4 || 158.9 |- | United Kingdom || 70.3 || 70.1 || 66.8 || 66.4 || 69.9 || 77.3 || 91.3 || 95.2 || 107.8 || 118.2 || 123.4 |- | Italy || 63.9 || 64.6 || 59.5 || 58.6 || 64.5 || 75.8 || 86.6 || 89.8 || 95.3 || 105.9 || 122.9 |- | Spain || 31.0 || 30.8 || 30.8 || 31.9 || 33.4 || 42.0 || 48.9 || 52.7 || 56.7 || 63.7 || 74.8 |- | Netherlands || 29.7 || 29.4 || 31.3 || 30.6 || 32.2 || 40.1 || 49.0 || 52.7 || 59.2 || 67.9 || 81.7 |- | Belgium || 27.1 || 27.0 || 27.5 || 27.1 || 28.7 || 36.1 || 41.8 || 43.5 || 46.9 || 51.6 || 62.6 |- | Switzerland || 22.1 || 22.2 || 19.4 || 21.1 || 25.5 || 30.3 || 33.8 || 35.4 || 37.8 || 42.7 || 53.1 |- | Ireland || 16.9 || 20.1 || 22.6 || 22.9 || 29.1 || 32.3 || 33.9 || 34.9 || 37.5 || 46.0 || 54.8 |- | Sweden || 11.1 || 11.4 || 11.2 || 11.0 || 12.5 || 15.9 || 18.2 || 19.3 || 21.2 || 21.2 || 22.6 |- | Other || 27.1 || 26.8 || 25.9 || 26.4 || 27.9 || 33.5 || 38.6 || 42.9 || 46.2 || 50.3 || 58.9 |- |'''Western Europe''' || '''503.1''' || '''504.0''' || '''490.4''' || '''488.8''' || '''524.4''' || '''630.9''' || '''721.9''' || '''762.7''' || '''822.4''' || '''935.4''' || '''1,076.8''' |- | |- | Russia || 23.8 || 24.6 || 27.4 || 29.1 || 30.3 || 33.4 || 37.5 || 40.9 || 53.1 || 63.0 || 77.6 |- | Other || 22.3 || 20.3 || 21.9 || 23.4 || 25.3 || 31.4 || 39.6 || 46.2 || 55.0 || 68.4 || 87.5 |- | '''Central/Eastern Europe''' || '''46.1''' || '''44.9''' || '''49.3''' || '''52.5''' || '''55.6''' || '''64.8''' ||''' 77.1''' || '''87.1''' || '''108.0''' || '''131.3''' || '''165.1''' |- | |- | '''Africa and Middle East''' || '''52.7''' || '''53.2''' || '''59.2''' || '''57.4''' || '''60.4''' || '''73.0''' || '''86.4''' || '''99.3''' || '''109.6''' || '''124.2''' || '''160.4''' |- | |- | Japan || 193.8 || 220.4 || 239.7 || 208.3 || 197.2 || 218.8 || 243.6 || 251.3 || 248.5 || 245.4 || 298.0 |- | Asia-Pacific excluding Japan || 215.2 || 241.9 || 276.1 || 271.5 || 300.5 || 369.1 || 463.9 || 567.5 || 668.8 || 795.5 || 993.2 |- | China || 80.9 || 87.8 || 103.6 || 111.0 || 126.5 || 159.9 || 205.0 || 269.0 || 331.4 || 406.4 || 549.4 |- | India || 30.7 || 35.3 || 35.3 || 32.5 || 33.5 || 40.8 || 53.3 || 63.6 || 72.5 || 91.1 || 98.2 |- | Australia || 11.3 || 12.1 || 11.2 || 10.8 || 11.3 || 14.9 || 17.0 || 18.7 || 19.1 || 22.8 || 27.1 |- | Korea || 39.3 || 45.5 || 56.3 || 50.4 || 54.9 || 64.4 || 78.7 || 91.9 || 103.4 || 116.7 || 133.2 |- | Singapore || 6.3 || 8.5 || 9.5 || 9.4 || 12.5 || 16.1 || 20.0 || 22.0 || 25.8 || 28.9 || 31.6 |- | Taiwan || 21.9 || 23.7 || 29.2 || 26.8 || 28.4 || 34.3 || 44.5 || 49.5 || 53.8 || 57.4 || 62.9 |- | Other Asia/Pacific || 24.8 || 29.1 || 30.9 || 30.8 || 33.3 || 38.8 || 45.5 || 52.9 || 62.9 || 72.2 || 90.8 |- |'''Asia/Pacific''' || '''409.0''' || '''462.3''' || '''515.7''' || '''479.7''' || '''497.7''' || '''587.8''' || '''707.5''' || '''818.8''' || '''917.3''' || '''1041.0''' || '''1291.2''' |- | |- | '''Total world shipments''' || '''1573.5''' || '''1625.5''' || '''1719.0''' || '''1670.9''' || '''1748.8''' || '''2008.5''' || '''2325.6''' || '''2596.4''' || '''2858.1''' || '''3160.7''' || '''3696.8''' |} ==See also== *[[Chemical engineering]] *[[Chemical leasing]] *[[Pharmaceutical industry]] *[[Industrial gas]] *[[Prices of chemical elements]] *[[Responsible Care]] *[[Northeast of England Process Industry Cluster]] (NEPIC) ==References== {{reflist}} * {{cite book |first=Fred |last=Aftalion |title=A History of the International Chemical Industry |publisher=University of Pennsylvania Press |year=1991 |isbn=978-0-8122-1297-6}}. [https://www.questia.com/PM.qst?a=o&d=10894619 online version] {{Webarchive|url=https://web.archive.org/web/20110604143338/http://www.questia.com/PM.qst?a=o&d=10894619 |date=2011-06-04 }} * {{cite book |first=E. N. |last=Brandt |title=Growth Company: Dow Chemical's First Century |year=1997 |publisher=Michigan State University Press |isbn=0-87013-426-4}}. [https://web.archive.org/web/20050429054605/http://www.eh.net/bookreviews/library/0207.shtml online review] * {{cite book |first=Alfred D. |last=Chandler |title=Shaping the Industrial Century: The Remarkable Story of the Evolution of the Modern Chemical and Pharmaceutical Industries |publisher=Harvard University Press|year=2005 |isbn=0-674-01720-X}}. chapters 3-6 deal with DuPont, Dow Chemicals, Monsanto, American Cyanamid, Union Carbide, and Allied in US; and European chemical producers, Bayer, Farben, and ICI. * {{cite journal |first=Micheal |last=McCoy |display-authors=etal |title=Facts & Figures of the Chemical Industry |journal=Chemical & Engineering News |volume=84|number=28 |date=July 10, 2006 |pages=35β72}} * {{cite book |last1=Shreve|first1=R. Norris |first2=Joseph A. Jr. |last2=Brink |title=The Chemical Process Industries |edition=4th |location=New York |publisher=McGraw Hill |year=1977}} * {{cite book |last1=Woytinsky |first1=W. S. |first2=E. S. |last2=Woytinsky |title=World Population and Production Trends and Outlooks |year=1953 |pages=1176β1205}} Contains many tables and maps on the worldwide chemical industry in 1950. ==External links== * Chemical refinery resources: [https://web.archive.org/web/20150204034435/http://www.ccc-group.com/chemicals/solutions/industrial-1 ''ccc-group.com''] {{Industries}} {{Authority control}} [[Category:Chemical industry| ]] [[Category:Industrial processes]] [[Category:Industries (economics)]]
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