Jump to content
Main menu
Main menu
move to sidebar
hide
Navigation
Main page
Recent changes
Random page
Help about MediaWiki
Special pages
Niidae Wiki
Search
Search
Appearance
Create account
Log in
Personal tools
Create account
Log in
Pages for logged out editors
learn more
Contributions
Talk
Editing
Alkene
(section)
Page
Discussion
English
Read
Edit
View history
Tools
Tools
move to sidebar
hide
Actions
Read
Edit
View history
General
What links here
Related changes
Page information
Appearance
move to sidebar
hide
Warning:
You are not logged in. Your IP address will be publicly visible if you make any edits. If you
log in
or
create an account
, your edits will be attributed to your username, along with other benefits.
Anti-spam check. Do
not
fill this in!
=== NMR spectroscopy === In <sup>1</sup>H [[NMR]] spectroscopy, the [[hydrogen]] bonded to the carbon adjacent to double bonds will give a [[chemical shift|Ξ΄<sub>H</sub>]] of 4.5β6.5 [[parts per million|ppm]]. The double bond will also [[Electromagnetic shielding|deshield]] the hydrogen attached to the carbons adjacent to sp<sup>2</sup> carbons, and this generates Ξ΄<sub>H</sub>=1.6β2. ppm peaks.<ref>{{cite web|url=http://www2.ups.edu/faculty/hanson/Spectroscopy/NMR/HNMRshift.htm|title=Overview of Chemical Shifts in H-NMR|last=Hanson|first=John|website=ups.edu|access-date=May 5, 2019}}</ref> Cis/trans isomers are distinguishable due to different [[J-coupling]] effect. Cis [[Vicinal (chemistry)|vicinal]] hydrogens will have coupling constants in the range of 6β14 [[Hz]], whereas the trans will have coupling constants of 11β18 Hz.<ref name="NMR of Alkenes">{{cite web|url=https://chem.libretexts.org/Bookshelves/Organic_Chemistry/Supplemental_Modules_(Organic_Chemistry)/Alkenes/Properties_of_Alkenes/Nuclear_Magnetic_Resonance_(NMR)_of_Alkenes|author=<!--Not stated-->|title=Nuclear Magnetic Resonance (NMR) of Alkenes|website=Chemistry LibreTexts|date=April 23, 2019|access-date=May 5, 2019}}</ref> In their <sup>13</sup>C NMR spectra of alkenes, double bonds also deshield the carbons, making them have low field shift. C=C double bonds usually have chemical shift of about 100β170 ppm.<ref name="NMR of Alkenes" />
Summary:
Please note that all contributions to Niidae Wiki may be edited, altered, or removed by other contributors. If you do not want your writing to be edited mercilessly, then do not submit it here.
You are also promising us that you wrote this yourself, or copied it from a public domain or similar free resource (see
Encyclopedia:Copyrights
for details).
Do not submit copyrighted work without permission!
Cancel
Editing help
(opens in new window)
Search
Search
Editing
Alkene
(section)
Add topic