Editing Unconventional superconductor (section)

==Previous studies on the symmetry of the HTS order parameter==
The symmetry of the HTS order parameter has been studied in [[nuclear magnetic resonance]] measurements and, more recently, by [[ARPES|angle-resolved photoemission]] and measurements of the microwave penetration depth in a HTS crystal. NMR measurements probe the local magnetic field around an atom and hence reflect the susceptibility of the material. They have been of special interest for the HTS materials because many researchers have wondered whether spin correlations might play a role in the mechanism of the HTS.

NMR measurements of the resonance frequency on [[YBCO]] indicated that electrons in the copper oxide superconductors are paired in [[singlet state|spin-singlet]] states. This indication came from the behavior of the [[Knight shift]], the frequency shift that occurs when the internal field is different from the applied field: In a normal metal, the magnetic moments of the conduction electrons in the neighborhood of the ion being probed align with the applied field and create a larger internal field. As these metals go superconducting, electrons with oppositely directed spins couple to form singlet states. In the anisotropic HTS, perhaps NMR measurements have found that the relaxation rate for copper depends on the direction of the applied static magnetic field, with the rate being higher when the static field is parallel to one of the axes in the copper oxide plane. While this observation by some group supported the d symmetry of the HTS, other groups could not observe it.

Also, by measuring the ''penetration depth'', the symmetry of the HTS order parameter can be studied. The microwave penetration depth is determined by the superfluid density responsible for screening the external field. In the s wave BCS theory, because pairs can be thermally excited across the gap Δ, the change in superfluid density per unit change in temperature goes as exponential behavior, exp(-Δ/''k''<sub>B</sub>''T''). In that case, the penetration depth also varies exponentially with temperature ''T''. If there are nodes in the energy gap as in the ''d'' symmetry HTS, electron pair can more easily be broken, the superfluid density should have a stronger temperature dependence, and the penetration depth is expected to increase as a power of T at low temperatures. If the symmetry is specially ''d''<sub>''x''<sup>2</sup>-''y''<sup>2</sup></sub> then the penetration depth should vary linearly with ''T'' at low temperatures. This technique is increasingly being used to study superconductors and is limited in application largely by the quality of available single crystals.

[[Photoemission spectroscopy]] also could provide information on the HTS symmetry. By scattering photons off electrons in the crystal, one can sample the energy spectra of the electrons. Because the technique is sensitive to the angle of the emitted electrons one can determine the spectrum for different wave vectors on the Fermi surface. However, within the resolution of the [[angle-resolved photoemission spectroscopy]] (ARPES), researchers could not tell whether the gap goes to zero or just gets very small. Also, ARPES are sensitive only to the magnitude and not to the sign of the gap, so it could not tell if the gap goes negative at some point. This means that ARPES cannot determine whether the HTS order parameter has the ''d'' symmetry or not.