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===Aliphatic hydrocarbons=== {| class="wikitable sortable sticky-header" ! Formula !! Name !! Ξ<sub>f</sub>''H''<sup>⦡</sup> /(kcal/mol) !! Ξ<sub>f</sub>''H''<sup>⦡</sup> /(kJ/mol) |- | colspan="4"| '''''Straight-chain''''' |- | CH<sub>4</sub> || [[Methane]] || β17.9 || β74.9 |- | C<sub>2</sub>H<sub>6</sub> || [[Ethane]] || β20.0 || β83.7 |- | C<sub>2</sub>H<sub>4</sub> || [[Ethylene]] || 12.5 || 52.5 |- | C<sub>2</sub>H<sub>2</sub> || [[Acetylene]] || 54.2 || 226.8 |- | C<sub>3</sub>H<sub>8</sub> || [[Propane]] || β25.0 || β104.6 |- | C<sub>4</sub>H<sub>10</sub> || ''n''-[[Butane]] || β30.0 || β125.5 |- | C<sub>5</sub>H<sub>12</sub> || ''n''-[[Pentane]] || β35.1 || β146.9 |- | C<sub>6</sub>H<sub>14</sub> || ''n''-[[Hexane]] || β40.0 || β167.4 |- | C<sub>7</sub>H<sub>16</sub> || ''n''-[[Heptane]] || β44.9 || β187.9 |- | C<sub>8</sub>H<sub>18</sub> || ''n''-[[Octane]] || β49.8 || β208.4 |- | C<sub>9</sub>H<sub>20</sub> || ''n''-[[Nonane]] || β54.8 || β229.3 |- | C<sub>10</sub>H<sub>22</sub> || ''n''-[[Decane]] || β59.6 || β249.4 |- | colspan="4"| '''''C<sub>4</sub> Alkane branched isomers''''' |- | C<sub>4</sub>H<sub>10</sub> || [[Isobutane]] (methylpropane) || β32.1 || β134.3 |- | colspan="4"| '''''C<sub>5</sub> Alkane branched isomers''''' |- | C<sub>5</sub>H<sub>12</sub> || [[Neopentane]] (dimethylpropane) || β40.1 || β167.8 |- | C<sub>5</sub>H<sub>12</sub> || [[Isopentane]] (methylbutane) || β36.9 || β154.4 |- | colspan="4"| '''''C<sub>6</sub> Alkane branched isomers''''' |- | C<sub>6</sub>H<sub>14</sub> || [[2,2-Dimethylbutane]] || β44.5 || β186.2 |- | C<sub>6</sub>H<sub>14</sub> || [[2,3-Dimethylbutane]] || β42.5 || β177.8 |- | C<sub>6</sub>H<sub>14</sub> || [[2-Methylpentane]] (isohexane) || β41.8 || β174.9 |- | C<sub>6</sub>H<sub>14</sub> || [[3-Methylpentane]] || β41.1 || β172.0 |- | colspan="4"| '''''C<sub>7</sub> Alkane branched isomers''''' |- | C<sub>7</sub>H<sub>16</sub> || [[2,2-Dimethylpentane]] || β49.2 || β205.9 |- | C<sub>7</sub>H<sub>16</sub> || [[2,2,3-Trimethylbutane]] || β49.0 || β205.0 |- | C<sub>7</sub>H<sub>16</sub> || [[3,3-Dimethylpentane]] || β48.1 || β201.3 |- | C<sub>7</sub>H<sub>16</sub> || [[2,3-Dimethylpentane]] || β47.3 || β197.9 |- | C<sub>7</sub>H<sub>16</sub> || [[2,4-Dimethylpentane]] || β48.2 || β201.7 |- | C<sub>7</sub>H<sub>16</sub> || [[2-Methylhexane]] || β46.5 || β194.6 |- | C<sub>7</sub>H<sub>16</sub> || [[3-Methylhexane]] || β45.7 || β191.2 |- | C<sub>7</sub>H<sub>16</sub> || [[3-Ethylpentane]] || β45.3 || β189.5 |- | colspan="4"| '''''C<sub>8</sub> Alkane branched isomers''''' |- | C<sub>8</sub>H<sub>18</sub> || [[2,3-Dimethylhexane]] || β55.1 || β230.5 |- | C<sub>8</sub>H<sub>18</sub> || [[2,2,3,3-Tetramethylbutane]] || β53.9 || β225.5 |- | C<sub>8</sub>H<sub>18</sub> || [[2,2-Dimethylhexane]] || β53.7 || β224.7 |- | C<sub>8</sub>H<sub>18</sub> || [[2,2,4-Trimethylpentane]] (isooctane) || β53.5 || β223.8 |- | C<sub>8</sub>H<sub>18</sub> || [[2,5-Dimethylhexane]] || β53.2 || β222.6 |- | C<sub>8</sub>H<sub>18</sub> || [[2,2,3-Trimethylpentane]] || β52.6 || β220.1 |- | C<sub>8</sub>H<sub>18</sub> || [[3,3-Dimethylhexane]] || β52.6 || β220.1 |- | C<sub>8</sub>H<sub>18</sub> || [[2,4-Dimethylhexane]] || β52.4 || β219.2 |- | C<sub>8</sub>H<sub>18</sub> || [[2,3,4-Trimethylpentane]] || β51.9 || β217.1 |- | C<sub>8</sub>H<sub>18</sub> || [[2,3,3-Trimethylpentane]] || β51.7 || β216.3 |- | C<sub>8</sub>H<sub>18</sub> || [[2-Methylheptane]] || β51.5 || β215.5 |- | C<sub>8</sub>H<sub>18</sub> || [[3-Ethyl-3-Methylpentane]] || β51.4 || β215.1 |- | C<sub>8</sub>H<sub>18</sub> || [[3,4-Dimethylhexane]] || β50.9 || β213.0 |- | C<sub>8</sub>H<sub>18</sub> || [[3-Ethyl-2-Methylpentane]] || β50.4 || β210.9 |- | C<sub>8</sub>H<sub>18</sub> || [[3-Methylheptane]] || β60.3 || β252.5 |- | C<sub>8</sub>H<sub>18</sub> || [[4-Methylheptane]] || ? || ? |- | C<sub>8</sub>H<sub>18</sub> || [[3-Ethylhexane]] || ? || ? |- | colspan="4"| '''''C<sub>9</sub> Alkane branched isomers (selected)''''' |- | C<sub>9</sub>H<sub>20</sub> || [[2,2,4,4-Tetramethylpentane]] || β57.8|| β241.8 |- | C<sub>9</sub>H<sub>20</sub> || [[2,2,3,3-Tetramethylpentane]] || β56.7 || β237.2 |- | C<sub>9</sub>H<sub>20</sub> || [[2,2,3,4-Tetramethylpentane]] || β56.6 || β236.8 |- | C<sub>9</sub>H<sub>20</sub> || [[2,3,3,4-Tetramethylpentane]] || β56.4 || β236.0 |- | C<sub>9</sub>H<sub>20</sub> || [[3,3-Diethylpentane]] || β55.7 || β233.0 |}
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