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== Chemical composition == [[File:Elbaite with albite - São José da Safira, Minas Gerais, Brazil.jpg|thumb|upright|Elbaite]] The tourmaline mineral group is chemically one of the most complicated groups of [[silicate minerals]]. Its composition varies widely because of [[Multiple isomorphous replacement|isomorphous replacement]] (solid solution), and its general formula can be written as {{chem2|XY3Z6(T6O18)(BO3)3V3W}}, where:<ref>Hawthorne, F.C. & Henry, D.J. (1999). [http://eurjmin.geoscienceworld.org/cgi/content/abstract/11/2/201 "Classification of the minerals of the tourmaline group"] {{webarchive|url=https://web.archive.org/web/20071016064718/http://eurjmin.geoscienceworld.org/cgi/content/abstract/11/2/201 |date=2007-10-16 }}. ''European Journal of Mineralogy'', 11, pp. 201–215.</ref> * X = [[calcium|Ca]], [[sodium|Na]], [[potassium|K]], [[vacancy defect|▢ = vacancy]] * Y = [[lithium|Li]], [[magnesium|Mg]], [[iron|Fe]]<sup>2+</sup>, [[manganese|Mn]]<sup>2+</sup>, [[zinc|Zn]], [[aluminium|Al]], [[chromium|Cr]]<sup>3+</sup>, [[vanadium|V]]<sup>3+</sup>, [[iron|Fe]]<sup>3+</sup>, [[titanium|Ti]]<sup>4+</sup>, [[vacancy defect|▢ = vacancy]] * Z = Mg, Al, Fe<sup>3+</sup>, Cr<sup>3+</sup>, V<sup>3+</sup> * T = [[silicon|Si]], Al, [[boron|B]] * B = B, [[vacancy defect|▢ = vacancy]] * V = [[oxygen|O]][[hydrogen|H]], O * W = OH, [[fluorine|F]], O {| class="wikitable" |+ The 41 minerals in the group (endmember formulas) recognized by the [[International Mineralogical Association]] |- ! Species Name ! Ideal Endmember Formula ! IMA Number ! Symbol |- | [[Adachiite]] | CaFe<sup>2+</sup><sub>3</sub>Al<sub>6</sub>(Si<sub>5</sub>AlO<sub>18</sub>)(BO<sub>3</sub>)<sub>3</sub>(OH)<sub>3</sub>OH | 2012-101 | Adc |- | [[Alumino-oxy-rossmanite]] | ▢Al<sub>3</sub>Al<sub>6</sub>(Si<sub>5</sub>AlO<sub>18</sub>)(BO<sub>3</sub>)<sub>3</sub>(OH)<sub>3</sub>O | 2020-008 | Aorsm |- | [[Bosiite]] | NaFe<sup>3+</sup><sub>3</sub>(Al<sub>4</sub>Mg<sub>2</sub>)Si<sub>6</sub>O<sub>18</sub>(BO<sub>3</sub>)<sub>3</sub>(OH)<sub>3</sub>O | 2014-094 | Bos |- | [[Celleriite]] | ▢(Mn<sup>2+</sup><sub>2</sub>Al)Al<sub>6</sub>(Si<sub>6</sub>O<sub>18</sub>)(BO<sub>3</sub>)<sub>3</sub>(OH)<sub>3</sub>(OH) | 2019-089 | Cll |- | [[Chromium-dravite]] | NaMg<sub>3</sub>Cr<sub>6</sub>Si<sub>6</sub>O<sub>18</sub>(BO<sub>3</sub>)<sub>3</sub>(OH)<sub>3</sub>OH | 1982-055 | Cdrv |- | [[Chromo-alumino-povondraite]] | NaCr<sub>3</sub>(Al<sub>4</sub>Mg<sub>2</sub>)Si<sub>6</sub>O<sub>18</sub>(BO<sub>3</sub>)<sub>3</sub>(OH)<sub>3</sub>O | 2013-089 | Capov |- | [[Darrellhenryite]] | NaLiAl<sub>2</sub>Al<sub>6</sub>Si<sub>6</sub>O<sub>18</sub>(BO<sub>3</sub>)<sub>3</sub>(OH)<sub>3</sub>O | 2012-026 | Dhry |- | [[#Chemical composition|Dravite]] | NaMg<sub>3</sub>Al<sub>6</sub>Si<sub>6</sub>O<sub>18</sub>(BO<sub>3</sub>)<sub>3</sub>(OH)<sub>3</sub>OH | - 1884 - | Drv |- | [[Dutrowite]] | Na(Fe<sub>2.5</sub>Ti<sub>0.5</sub>)Al<sub>6</sub>Si<sub>6</sub>O<sub>18</sub>(BO<sub>3</sub>)<sub>3</sub>(OH)<sub>3</sub>O | 2019-082 | Dtw |- | [[Elbaite]] |Na(Li<sub>1.5</sub>,Al<sub>1.5</sub>)Al<sub>6</sub>Si<sub>6</sub>O<sub>18</sub>(BO<sub>3</sub>)<sub>3</sub>(OH)<sub>3</sub>OH | - 1913 - | Elb |- | [[Ertlite]] |NaAl<sub>3</sub>Al<sub>6</sub>(Si<sub>4</sub>B<sub>2</sub>O<sub>18</sub>)(BO<sub>3</sub>)<sub>3</sub>(OH)<sub>3</sub>O | 2023-086 | Etl |- | [[Ferro-bosiite]] | NaFe<sup>3+</sup><sub>3</sub>(Al<sub>4</sub>Fe<sup>2+</sup><sub>2</sub>)Si<sub>6</sub>O<sub>18</sub>(BO<sub>3</sub>)<sub>3</sub>(OH)<sub>3</sub>O | 2022-069 | Fbos |- | [[Feruvite]] | CaFe<sup>2+</sup><sub>3</sub>(MgAl<sub>5</sub>)Si<sub>6</sub>O<sub>18</sub>(BO<sub>3</sub>)<sub>3</sub>(OH)<sub>3</sub>OH | 1987-057 | Fer |- | [[Fluor-buergerite]] | NaFe<sup>3+</sup><sub>3</sub>Al<sub>6</sub>Si<sub>6</sub>O<sub>18</sub>(BO<sub>3</sub>)<sub>3</sub>O<sub>3</sub>F | 1965-005 | Fbu |- | [[Fluor-dravite]] | NaMg<sub>3</sub>Al<sub>6</sub>Si<sub>6</sub>O<sub>18</sub>(BO<sub>3</sub>)<sub>3</sub>(OH)<sub>3</sub>F | 2009-089 | Fdrv |- | [[Fluor-elbaite]] | Na(Li<sub>1.5</sub>,Al<sub>1.5</sub>)Al<sub>6</sub>Si<sub>6</sub>O<sub>18</sub>(BO<sub>3</sub>)<sub>3</sub>(OH)<sub>3</sub>F | 2011-071 | Felb |- | [[Fluor-liddicoatite]] | Ca(Li<sub>2</sub>,Al)Al<sub>6</sub>Si<sub>6</sub>O<sub>18</sub>(BO<sub>3</sub>)<sub>3</sub>(OH)<sub>3</sub>F | 1976-041{{efn|Named 'liddicoatite' in 1976; renamed to fluor-liddicoatite by the IMA in 2011}} | Fld |- | [[Fluor-rossmanite]] | ▢(LiAl<sub>2</sub>)Al<sub>6</sub>Si<sub>6</sub>O<sub>18</sub>(BO<sub>3</sub>)<sub>3</sub>(OH)<sub>3</sub>F | 2023-111 | Frsm |- | [[Fluor-schorl]] | NaFe<sup>2+</sup><sub>3</sub>Al<sub>6</sub>Si<sub>6</sub>O<sub>18</sub>(BO<sub>3</sub>)<sub>3</sub>(OH)<sub>3</sub>F | 2010-067 | Fsrl |- | [[Fluor-tsilaisite]] | NaMn<sup>2+</sup><sub>3</sub>Al<sub>6</sub>Si<sub>6</sub>O<sub>18</sub>(BO<sub>3</sub>)<sub>3</sub>(OH)<sub>3</sub>F | 2012-044 | Ftl |- | [[Fluor-uvite]] | CaMg<sub>3</sub>(Al<sub>5</sub>Mg)Si<sub>6</sub>O<sub>18</sub>(BO<sub>3</sub>)<sub>3</sub>(OH)<sub>3</sub>F | - 1930 - | Fluvt |- | [[Foitite]] | ▢(Fe<sup>2+</sup><sub>2</sub>Al)Al<sub>6</sub>Si<sub>6</sub>O<sub>18</sub>(BO<sub>3</sub>)<sub>3</sub>(OH)<sub>3</sub>OH | 1992-034 | Foi |- | [[Lucchesiite]] | Ca(Fe<sup>2+</sup>)<sub>3</sub>Al<sub>6</sub>Si<sub>6</sub>O<sub>18</sub>(BO<sub>3</sub>)<sub>3</sub>(OH)<sub>3</sub>O | 2015-043 | Lcc |- | [[Magnesio-dutrowite]] | Na(Mg<sub>2.5</sub>Ti<sub>0.5</sub>)Al<sub>6</sub>Si<sub>6</sub>O<sub>18</sub>(BO<sub>3</sub>)<sub>3</sub>(OH)<sub>3</sub>O | 2023-015 | Mdtw |- | [[Magnesio-foitite]] | ▢(Mg<sub>2</sub>Al)Al<sub>6</sub>Si<sub>6</sub>O<sub>18</sub>(BO<sub>3</sub>)<sub>3</sub>(OH)<sub>3</sub>OH | 1998-037 | Mfoi |- | [[Magnesio-lucchesite]] | Ca(Mg<sub>3</sub>Al<sub>6</sub>Si<sub>6</sub>O<sub>18</sub>(BO<sub>3</sub>)<sub>3</sub>(OH)<sub>3</sub>O | 2019-025 | Mlcc |- | [[Maruyamaite]] | K(MgAl<sub>2</sub>)(Al<sub>5</sub>Mg)Si<sub>6</sub>O<sub>18</sub>(BO<sub>3</sub>)<sub>3</sub>(OH)<sub>3</sub>O | 2013-123 | Mry |- | [[#Chemical composition|Olenite]] | NaAl<sub>3</sub>Al<sub>6</sub>Si<sub>6</sub>O<sub>18</sub>(BO<sub>3</sub>)<sub>3</sub>O<sub>3</sub>OH | 1985-006 | Ole |- | [[Oxy-chromium-dravite]] | NaCr<sub>3</sub>(Mg<sub>2</sub>Cr<sub>4</sub>)Si<sub>6</sub>O<sub>18</sub>(BO<sub>3</sub>)<sub>3</sub>(OH)<sub>3</sub>O | 2011-097 | Ocdrv |- | [[Oxy-dravite]] | Na(Al<sub>2</sub>Mg)(Al<sub>5</sub>Mg)Si<sub>6</sub>O<sub>18</sub>(BO<sub>3</sub>)<sub>3</sub>(OH)<sub>3</sub>O | 2012-004 | Odrv |- | [[Oxy-foitite]] | ▢(Fe<sup>2+</sup>Al<sub>2</sub>)Al<sub>6</sub>Si<sub>6</sub>O<sub>18</sub>(BO<sub>3</sub>)<sub>3</sub>(OH)<sub>3</sub>O | 2016-069 | Ofoi |- | [[Oxy-schorl]] | Na(Fe<sup>2+</sup><sub>2</sub>Al)Al<sub>6</sub>Si<sub>6</sub>O<sub>18</sub>(BO<sub>3</sub>)<sub>3</sub>(OH)<sub>3</sub>O | 2011-011 | Osrl |- | [[Oxy-vanadium-dravite]] | NaV<sub>3</sub>(V<sub>4</sub>Mg<sub>2</sub>)Si<sub>6</sub>O<sub>18</sub>(BO<sub>3</sub>)<sub>3</sub>(OH)<sub>3</sub>O | 1999-050 | Ovdrv |- | [[Povondraite]] | NaFe<sup>3+</sup><sub>3</sub>(Fe<sup>3+</sup><sub>4</sub>Mg<sub>2</sub>)Si<sub>6</sub>O<sub>18</sub>(BO<sub>3</sub>)<sub>3</sub>(OH)<sub>3</sub>O | 1979{{efn|Named 'ferridravite' in 1979; renamed to povondraite by the IMA in 1990}} | Pov |- | [[Princivalleite]] | Na(Mn<sub>2</sub>Al)Al<sub>6</sub>Si<sub>6</sub>O<sub>18</sub>(BO<sub>3</sub>)<sub>3</sub>(OH)<sub>3</sub>O | 2020-056 | Pva |- | [[Rossmanite]] | ▢(LiAl<sub>2</sub>)Al<sub>6</sub>Si<sub>6</sub>O<sub>18</sub>(BO<sub>3</sub>)<sub>3</sub>(OH)<sub>3</sub>OH | 1996-018 | Rsm |- | [[Schorl]] | NaFe<sup>2+</sup><sub>3</sub>Al<sub>6</sub>Si<sub>6</sub>O<sub>18</sub>(BO<sub>3</sub>)<sub>3</sub>(OH)<sub>3</sub>OH | - 1505 - | Srl |- | [[Tsilaisite]] | NaMn<sup>2+</sup><sub>3</sub>Al<sub>6</sub>Si<sub>6</sub>O<sub>18</sub>(BO<sub>3</sub>)<sub>3</sub>(OH)<sub>3</sub>OH | 2011-047 | Tsl |- | [[Uvite]] | CaMg<sub>3</sub>(Al<sub>5</sub>Mg)Si<sub>6</sub>O<sub>18</sub>(BO<sub>3</sub>)<sub>3</sub>(OH)<sub>3</sub>OH | 2000-030 | Uvt |- | [[Vanadio-oxy-chromium-dravite]] | NaV<sub>3</sub>(Cr<sub>4</sub>Mg<sub>2</sub>)Si<sub>6</sub>O<sub>18</sub>(BO<sub>3</sub>)<sub>3</sub>(OH)<sub>3</sub>O | 2012-034 | Vocdrv |- | [[Vanadio-oxy-dravite]] | NaV<sub>3</sub>(Al<sub>4</sub>Mg<sub>2</sub>)Si<sub>6</sub>O<sub>18</sub>(BO<sub>3</sub>)<sub>3</sub>(OH)<sub>3</sub>O | 2012-074 | Vodrv |} {{notelist}} Mineral species that were named before the IMA was founded in 1958 do not have an IMA number. The IMA commission on new mineral names published a list of approved symbols for each mineral species in 2021.<ref>Warr, L.N. "IMA–CNMNC approved mineral symbols." ''Mineralogical Magazine'', 2021, v. 85, p. 291–320. doi:10.1180/mgm.2021.43.</ref> A revised nomenclature for the tourmaline group was published in 2011.<ref>{{Cite journal |journal=American Mineralogist |volume=96 |pages=895–913 |year=2011 |title=Nomenclature of the tourmaline-supergroup minerals |author=Darrell J. Henry, Milan Novák, [[Frank C. Hawthorne]], Andreas Ertl, Barbara L. Dutrow, Pavel Uher, and Federico Pezzotta |issue=5–6 |doi=10.2138/am.2011.3636 |bibcode=2011AmMin..96..895H |s2cid=38696645 |url=http://pubsites.uws.edu.au/ima-cnmnc/henry%20et%20al%202011%20tourmaline%20tomenclature.pdf |url-status=live |archive-url=https://web.archive.org/web/20120326093327/http://pubsites.uws.edu.au/ima-cnmnc/henry%20et%20al%202011%20tourmaline%20tomenclature.pdf |archive-date=2012-03-26 }}</ref><ref>Erratum: American Mineralogist (2013), Volume 98, page 524.</ref><ref>Frank C. Hawthorne and Dona M. Dirlam. "Tourmaline: Tourmaline the Indicator Mineral: From Atomic Arrangement to Viking Navigation." ''Elements'', October 2011, v. 7, p. (5): 307–312, doi:10.2113/gselements.7.5.307.</ref>
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