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===Synthetic [[polymer]] glues=== ====Thermoplastic polymers==== {{main|thermoplastic polymer|Hot-melt adhesive}} Thermoplastic glues including hot-melt adhesives cure reversibly as they cool, like the gelatin and keratin glues listed above. They frequently don't emit volatiles unless overheated. {| class="wikitable sortable plainrowheaders" |- ! scope="col" width="20" | Type ! scope="col" width="20" | Subtypes ! scope="col" width="50" | Source(s) !Manufacture ! scope="col" width="250" | Chemistry ! scope="col" width="200" | Volatiles ! scope="col" align="center" width="100" | Safety ! scope="col" width="80" | Properties !Shelf life !Setting !Strength !Solvents ! scope="col" width="30" | Uses ! scope="col" width="30" | Date |- ! [[Ethylene-vinyl acetate]] ! |synthetic |[[polyethylene]] mixed with about 11% [[vinyl acetate]] | | | | | | | | | | |- ![[Polyolefins]] !(polyethylene, polypropylene, etc.) |synthetic | | | | | | |[[thermosetting]] | | | | |- ! [[Polyamide]]s ! |synthetic | | | | | | | | | | | |- ! [[Polyester]]s ! |synthetic | | | | | | | | | | | |- ! [[Polyurethane]]s ! |synthetic | | | | | | | | | | | |- ! [[Polycaprolactone]] ! |synthetic | |biodegradable | | | | |very low melting temperature, {{cvt|40|-|60|C|F}} and heat conductivity means it can be moulded by hand. Can be used to mould itself. | | | |} * Styrene acrylic copolymer β e.g. "No More Nails" ====Thermosetting polymers==== {{main|thermosetting polymer}} Thermosetting glues or thermosets cure irreversibly by polymerization. The polymerization can be triggered by heat or other radiation, or high pressure or a [[catalyst]]/hardener may be added. {| class="wikitable sortable plainrowheaders" |- ! scope="col" width="20" | Type ! scope="col" width="20" | Subtypes ! scope="col" width="50" | Source(s) !Manufacture ! scope="col" width="250" | Chemistry ! scope="col" width="200" | Volatiles ! scope="col" align="center" width="100" | Safety ! scope="col" width="80" | Properties !Shelf life !Working time !Setting !Strength !Solvents ! scope="col" width="30" | Uses ! scope="col" width="30" | Date |- ! [[Phenol formaldehyde resin]]s (PF), also called phenolic resins ! [[Resorcinol glue]], [[Para tertiary butylphenol formaldehyde resin]] |synthetic |[[resorcinol]] or similar is mixed with [[phenol]] to make a resin; cured by adding [[formaldehyde]] | |offgasses phenol and formeldehyde |phenol and formeldehyde are toxic, PTBPF causes contact allergies |Temperature-, UV-, and microbe-resistant. No gap-filling; joint must fit tightly. Brown in colour, sands off.<ref name=":0">{{Cite web |last=Boat |first=Classic |date=2011-03-11 |title=Adhesives for Wooden Boats: Structural Glues |url=https://www.classicboat.co.uk/practical-advice/adhesives-for-wooden-boats-structural-glues/ |access-date=2022-11-11 |website=Classic Boat Magazine |language=en-US}}</ref> |A few years, unmixed. |Temperature-dependent. Will not cure at temperatures below {{convert|10|C|F}}.<ref name=":0" /> |Needs to be clamped |Structural |Water-soluble until set, waterproof after.<ref name=":0" /> |laminating plywood, especially for exterior use; woodworking | |- ![[Urea-formaldehyde]] glue ! |synthetic |[[urea]] and [[formaldehyde]] | |offgasses urea and formeldehyde |formeldehyde is toxic, urea is an irritant | | | | |[[thermosetting]] | | | |- ![[Polysulfide]]s ! |synthetic | | | | |Will melt acrylic, polycarbonate, ABS and PVC plastic. Can be used to glue nylon, epoxy, and polyoxymethylene.<ref>{{Cite web |title=Marine Caulking & Adhesives |url=https://www.westmarine.com/marine-caulking-adhesives/ |access-date=2022-11-11 |website=West Marine |language=en-US}}</ref> | | | | | | |} * [[Epoxy]] resins ** [[Epoxy putty]] * Polyvinyls ** [[Polyvinyl acetate]] (PVA) Includes white glue (e.g. [[Elmer's Glue]]) and yellow [[Wood glue|carpenter's glue]] (Aliphatic resin) (Brands include Titebond and Lepage) ** [[Polyvinyl alcohol]] ** [[Polyvinyl chloride]] (PVC) ** Polyvinyl chloride emulsion (PVCE) β a water-miscible emulsion that polymerizes as it cures ** [[Polyvinylpyrrolidone]] (component of [[glue stick]]s) * [[Silicone resin]]s * [[Silyl modified polymers]]
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