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===Comparison with analogues=== Hydrogen peroxide has several structural analogues with {{chem2|H_{''m''}X\sXH_{''n''}|}} bonding arrangements (water also shown for comparison). It has the highest (theoretical) boiling point of this series (X = O, S, N, P). Its melting point is also fairly high, being comparable to that of [[hydrazine]] and water, with only [[hydroxylamine]] crystallising significantly more readily, indicative of particularly strong hydrogen bonding. [[Diphosphane]] and [[hydrogen disulfide]] exhibit only weak hydrogen bonding and have little chemical similarity to hydrogen peroxide. Structurally, the analogues all adopt similar skewed structures, due to repulsion between adjacent [[lone pair]]s. {| class="wikitable sortable" |+ Properties of {{chem2|H2O2}} and its analogues<br/>Values marked * are extrapolated |- ! Name !! Formula !! [[Molar mass]]<br>(g/mol) !! Melting<br>point (Β°C) !! Boiling<br>point (Β°C) |- | [[Properties of water|Water]] || HOH || 18.02 || 0.00 || 99.98 |- | Hydrogen peroxide || HOOH || 34.01 || β0.43 || 150.2* |- | [[Hydrogen disulfide]] || HSSH || 66.15 || β89.6 || 70.7 |- | [[Hydrazine]] || H<sub>2</sub>NNH<sub>2</sub> || 32.05 || 2 || 114 |- | [[Hydroxylamine]] || NH<sub>2</sub>OH || 33.03 || 33 || 58* |- | [[Diphosphane]] || H<sub>2</sub>PPH<sub>2</sub> || 65.98 || β99 || 63.5* |}
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