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===Aqueous chemistry=== Strong acids dissolve gallium, forming gallium(III) salts such as [[gallium(III) nitrate|{{chem|Ga(NO|3|)|3}}]] (gallium nitrate). [[Aqueous]] solutions of gallium(III) salts contain the hydrated gallium ion, {{chem|[Ga(H|2|O)|6|]|3+}}.<ref name="wiberg_holleman">{{cite book |title= Inorganic chemistry |author1= Wiberg, Egon |author2= Wiberg, Nils |author3= Holleman, Arnold Frederick |publisher= Academic Press |date= 2001 |isbn= 978-0-12-352651-9}}</ref>{{rp|1033}} [[Gallium(III) hydroxide]], {{chem|Ga(OH)|3}}, may be precipitated from gallium(III) solutions by adding [[ammonia]]. Dehydrating {{chem|Ga(OH)|3}} at 100 °C produces gallium oxide hydroxide, GaO(OH).<ref name="downs">{{cite book |title= Chemistry of aluminium, gallium, indium, and thallium |author= Downs, Anthony John |publisher= Springer |date= 1993 |isbn= 978-0-7514-0103-5}}</ref>{{rp|140–141}} Alkaline [[hydroxide]] solutions dissolve gallium, forming ''gallate'' salts (not to be confused with identically named [[gallic acid]] salts) containing the {{chem|Ga(OH)|4|-}} anion.<ref name="eagleson" /><ref name="wiberg_holleman" />{{rp|1033}}<ref name="sipos" /> Gallium hydroxide, which is [[amphoteric]], also dissolves in alkali to form gallate salts.<ref name="downs" />{{rp|141}} Although earlier work suggested {{chem|Ga(OH)|6|3-}} as another possible gallate anion,<ref>{{cite book |title= Electrochemistry—Volume 3: Specialist periodical report |author= Hampson, N. A. |editor= Harold Reginald Thirsk |publisher= Royal Society of Chemistry |location= Great Britain |date= 1971 |isbn= 978-0-85186-027-5 |page= 71 |url= https://books.google.com/books?id=vN0Y7KMGqNcC}}</ref> it was not found in later work.<ref name="sipos">{{cite journal |last1= Sipos |first1= P. L. |last2= Megyes |first2= T. N. |last3= Berkesi |year= 2008 |first3= O. |title= The Structure of Gallium in Strongly Alkaline, Highly Concentrated Gallate Solutions—a Raman and {{SimpleNuclide|Ga|71}}-NMR Spectroscopic Study |journal= J Solution Chem |volume= 37 |issue= 10 |pages= 1411–1418 |doi= 10.1007/s10953-008-9314-y |s2cid= 95723025 }}</ref>
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