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==Systems== Several thermodynamic definitions are very useful in thermochemistry. A system is the specific portion of the universe that is being studied. Everything outside the system is considered the surroundings or environment. A system may be: * a (completely) [[isolated system]] which can exchange neither energy nor matter with the surroundings, such as an insulated [[bomb calorimeter]] * a [[thermally isolated system]] which can exchange mechanical work but not heat or matter, such as an insulated closed [[piston]] or [[balloon]] * a [[mechanically isolated system]] which can exchange heat but not mechanical work or matter, such as an '''un'''insulated [[bomb calorimeter]] * a [[closed system]] which can exchange energy but not matter, such as an '''un'''insulated closed piston or balloon * an [[Thermodynamic system#Open system|open system]] which it can exchange both matter and energy with the surroundings, such as a pot of boiling water
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