Jump to content
Main menu
Main menu
move to sidebar
hide
Navigation
Main page
Recent changes
Random page
Help about MediaWiki
Special pages
Niidae Wiki
Search
Search
Appearance
Create account
Log in
Personal tools
Create account
Log in
Pages for logged out editors
learn more
Contributions
Talk
Editing
Passivation (chemistry)
(section)
Page
Discussion
English
Read
Edit
View history
Tools
Tools
move to sidebar
hide
Actions
Read
Edit
View history
General
What links here
Related changes
Page information
Appearance
move to sidebar
hide
Warning:
You are not logged in. Your IP address will be publicly visible if you make any edits. If you
log in
or
create an account
, your edits will be attributed to your username, along with other benefits.
Anti-spam check. Do
not
fill this in!
===Discovery and etymology=== The fact that iron doesn't react with concentrated [[nitric acid]] was discovered by [[Mikhail Lomonosov]] in 1738 and rediscovered by [[James Keir]] in 1790, who also noted that such pre-immersed Fe doesn't reduce [[silver]] from [[Silver nitrate|nitrate]] anymore.<ref name=":0">{{Cite book |last=Lu |first=Xinying |url=https://books.google.com/books?id=FXitEAAAQBAJ&pg=PA2 |title=Passivation and Corrosion of Black Rebar with Mill Scale |date=2023-02-10 |publisher=Springer Nature |isbn=978-981-19-8102-9 |language=en}}</ref> In the 1830s, [[Michael Faraday]] and [[Christian Friedrich Schönbein]] studied that issue systematically and demonstrated that when a piece of [[iron]] is placed in dilute [[nitric acid]], it will dissolve and produce [[hydrogen]], but if the iron is placed in concentrated nitric acid and then returned to the dilute nitric acid, little or no reaction will take place. In 1836, Schönbein named the first state the active condition and the second the passive condition while Faraday proposed the modern explanation of the oxide film described above (Schönbein disagreed with it), which was experimentally proven by [[Ulick Richardson Evans]] only in 1927.<ref name=":0" /> Between 1955 and 1957, [[Carl Frosch]] and [[Lincoln Derrick]] discovered surface passivation of silicon wafers by silicon dioxide, using passivation to build the first silicon dioxide field effect transistors.<ref>{{Cite patent|number=US2802760A|title=Oxidation of semiconductive surfaces for controlled diffusion|gdate=1957-08-13|invent1=Lincoln|invent2=Frosch|inventor1-first=Derick|inventor2-first=Carl J.|url=https://patents.google.com/patent/US2802760A}}</ref><ref>{{Cite journal |last1=Frosch |first1=C. J. |last2=Derick |first2=L. |date=1957-09-01 |title=Surface Protection and Selective Masking during Diffusion in Silicon |url=https://iopscience.iop.org/article/10.1149/1.2428650 |journal=Journal of the Electrochemical Society |language=en |volume=104 |issue=9 |pages=547 |doi=10.1149/1.2428650 |issn=1945-7111}}</ref><ref>{{Cite journal |last1=Huff |first1=Howard |last2=Riordan |first2=Michael |date=2007-09-01 |title=Frosch and Derick: Fifty Years Later (Foreword) |url=https://iopscience.iop.org/article/10.1149/2.F02073IF |journal=The Electrochemical Society Interface |volume=16 |issue=3 |pages=29 |doi=10.1149/2.F02073IF |issn=1064-8208}}</ref>
Summary:
Please note that all contributions to Niidae Wiki may be edited, altered, or removed by other contributors. If you do not want your writing to be edited mercilessly, then do not submit it here.
You are also promising us that you wrote this yourself, or copied it from a public domain or similar free resource (see
Encyclopedia:Copyrights
for details).
Do not submit copyrighted work without permission!
Cancel
Editing help
(opens in new window)
Search
Search
Editing
Passivation (chemistry)
(section)
Add topic