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===Structure and nomenclature=== Glucose is present in solid form as a [[monohydrate]] with a closed [[pyran]] ring (α-D-glucopyranose monohydrate, sometimes known less precisely by dextrose hydrate). In aqueous solution, on the other hand, a small proportion of glucose can be found in an open-chain configuration while remaining predominantly as α- or β-[[pyranose]], which interconvert. From aqueous solutions, the three known forms can be crystallized: α-glucopyranose, β-glucopyranose and α-glucopyranose monohydrate.<ref name="Ullmann">{{Cite book |doi=10.1002/14356007.a12_457.pub2 |chapter=Glucose and Glucose-Containing Syrups |title=Ullmann's Encyclopedia of Industrial Chemistry |year=2006 |last1=Schenck |first1=Fred W. |publisher=Wiley |isbn=978-3-527-30673-2}}</ref> Glucose is a building block of the disaccharides lactose and sucrose (cane or beet sugar), of [[oligosaccharide]]s such as [[raffinose]] and of [[polysaccharide]]s such as [[starch]], [[amylopectin]], [[glycogen]], and [[cellulose]].<ref name="r2"/><ref name="pf"/> The [[glass transition temperature]] of glucose is {{cvt|31|C}} and the Gordon–Taylor constant (an experimentally determined constant for the prediction of the glass transition temperature for different mass fractions of a mixture of two substances)<ref name="pf">Patrick F. Fox: ''Advanced Dairy Chemistry Volume 3: Lactose, water, salts and vitamins'', Springer, 1992. Volume 3, {{ISBN|9780412630200}}. p. 316.</ref> is 4.5.<ref name="Caballero 1 76">Benjamin Caballero, Paul Finglas, Fidel Toldrá: ''Encyclopedia of Food and Health''. Academic Press (2016). {{ISBN|9780123849533}}, Volume 1, p. 76.</ref> {| class="wikitable centered" |- style="background:#FFDEAD;" ! colspan="3"| Forms and projections of {{sm|d}}-glucose in comparison |- class="background color5" ! [[Natta projection]] ! colspan="2"| [[Haworth projection]] |- class="background color2" | align="center" rowspan="2" | [[File:D-Glucose Keilstrich.svg|100px|class=skin-invert-image]] | align="center" | [[File:Alpha-D-Glucofuranose.svg|120px|class=skin-invert-image]]{{pb}}α-{{sm|d}}-glucofuranose | align="center" | [[File:Beta-D-Glucofuranose.svg|120px|class=skin-invert-image]]{{pb}}β-{{sm|d}}-glucofuranose |- class="background color2" | align="center" | [[File:Alpha-D-Glucopyranose.svg|100px|class=skin-invert-image]]{{pb}}α-{{sm|d}}-glucopyranose | align="center" | [[File:Beta-D-Glucopyranose.svg|100px|class=skin-invert-image]]{{pb}}β-{{sm|d}}-glucopyranose |- class="background color5" ! colspan="3"| α-{{sm|d}}-Glucopyranose in (1) [[Fischer projection|Tollens/Fischer]] (2) Haworth projection (3) chair conformation (4) Mills projection |- class="background color2" | align="center" colspan="3" | [[File:Alpha glucose views.svg|500px|class=skin-invert-image]] |}
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