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====Thermal stability==== The air stability of graphene shows a clear thickness dependence: monolayer graphene is reactive to oxygen at 250 °C, strongly doped at 300 °C, and etched at 450 °C; in contrast, bulk graphite is not oxidized until 800 °C.<ref name="LiSantos2014"/> Atomically thin boron nitride has much better oxidation resistance than graphene. Monolayer boron nitride is not oxidized till 700 °C and can sustain up to 850 °C in air; bilayer and trilayer boron nitride nanosheets have slightly higher oxidation starting temperatures.<ref name="LiCervenka2014">{{cite journal|last1=Li|first1=Lu Hua|last2=Cervenka|first2=Jiri|last3=Watanabe|first3=Kenji|last4=Taniguchi|first4=Takashi|last5=Chen|first5=Ying|title=Strong Oxidation Resistance of Atomically Thin Boron Nitride Nanosheets|journal=ACS Nano|volume=8|issue=2|year=2014|pages=1457–1462|doi=10.1021/nn500059s|pmid=24400990|arxiv=1403.1002|bibcode=2014arXiv1403.1002L|s2cid=5372545}}</ref> The excellent thermal stability, high impermeability to gas and liquid, and electrical insulation make atomically thin boron nitride potential coating materials for preventing surface oxidation and corrosion of metals<ref name="LiXing2014">{{cite journal|last1=Li|first1=Lu Hua|last2=Xing|first2=Tan|last3=Chen|first3=Ying|last4=Jones|first4=Rob|title=Nanosheets: Boron Nitride Nanosheets for Metal Protection (Adv. Mater. Interfaces 8/2014)|journal=Advanced Materials Interfaces|volume=1|issue=8|year=2014|pages=n/a|doi=10.1002/admi.201470047|doi-access=free}}</ref><ref>{{Cite journal|last1=Liu|first1=Zheng|last2=Gong|first2=Yongji|last3=Zhou|first3=Wu|last4=Ma|first4=Lulu|last5=Yu|first5=Jingjiang|last6=Idrobo|first6=Juan Carlos|last7=Jung|first7=Jeil|last8=MacDonald|first8=Allan H.|last9=Vajtai|first9=Robert|date=2013-10-04|title=Ultrathin high-temperature oxidation-resistant coatings of hexagonal boron nitride|journal=Nature Communications|volume=4|issue=1|pages=2541|doi=10.1038/ncomms3541|pmid=24092019|bibcode=2013NatCo...4.2541L|doi-access=free}}</ref> and other two-dimensional (2D) materials, such as [[black phosphorus]].<ref>{{Cite journal|last1=Chen|first1=Xiaolong|last2=Wu|first2=Yingying|last3=Wu|first3=Zefei|last4=Han|first4=Yu|last5=Xu|first5=Shuigang|last6=Wang|first6=Lin|last7=Ye|first7=Weiguang|last8=Han|first8=Tianyi|last9=He|first9=Yuheng|date=2015-06-23|title=High-quality sandwiched black phosphorus heterostructure and its quantum oscillations|journal=Nature Communications|volume=6|issue=1|pages=7315|doi=10.1038/ncomms8315|pmid=26099721|pmc=4557360|arxiv=1412.1357|bibcode=2015NatCo...6.7315C}}</ref>
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