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===Other generally encountered ligands (alphabetical)=== In this table other common ligands are listed in alphabetical order. {| class="wikitable sortable" ! Ligand !! Formula (bonding atom(s) in bold) !! Charge !! Most common denticity !! Remark(s) |- | [[Acetylacetone|Acetylacetonate]] (acac)|| CH<sub>3</sub>βC'''O'''βCH<sub>2</sub>βC'''O'''βCH<sub>3</sub> || monoanionic || bidentate || In general bidentate, bound through both oxygens, but sometimes bound through the central carbon only,<br/> see also analogous ketimine analogues |- | [[Alkene]]s || R<sub>2</sub>'''C=C'''R<sub>2</sub> || neutral || || compounds with a CβC double bond |- | [[Aminopolycarboxylic acid]]s (APCAs) || || || || |- | [[BAPTA]] (1,2-bis(o-aminophenoxy)ethane-N,N,N',N'-tetraacetic acid) || || || || |- | [[Benzene]] || '''C<sub>6</sub>'''H<sub>6</sub> || neutral || || and other arenes |- | [[1,2-Bis(diphenylphosphino)ethane]] (dppe) || (C<sub>6</sub>H<sub>5</sub>)<sub>2</sub>'''P'''βC<sub>2</sub>H<sub>4</sub>β'''P'''(C<sub>6</sub>H<sub>5</sub>)<sub>2</sub> || neutral || bidentate || |- | [[1,1-Bis(diphenylphosphino)methane]] (dppm) || (C<sub>6</sub>H<sub>5</sub>)<sub>2</sub>'''P'''βCH<sub>2</sub>β'''P'''(C<sub>6</sub>H<sub>5</sub>)<sub>2</sub> || neutral || || Can bond to two metal atoms at once, forming dimers |- | [[Corrole]]s || || || tetradentate || |- | [[Crown ether]]s || || neutral || || primarily for alkali and alkaline earth metal cations |- | [[Cryptand|2,2,2-cryptand]] || || || hexadentate || primarily for alkali and alkaline earth metal cations |- | [[Cryptate]]s || || neutral || || |- | [[Cyclopentadienyl complex|Cyclopentadienyl]] (Cp) || {{chem|'''C'''|'''5'''|H|5|β}} || monoanionic || || Although monoanionic, by the nature of its occupied molecular orbitals, it is capable of acting as a tridentate ligand. |- | [[Diethylenetriamine]] (dien) || C<sub>4</sub>H<sub>13</sub>'''N<sub>3</sub>''' || neutral || tridentate || related to TACN, but not constrained to facial complexation |- | [[Dimethylglyoxime|Dimethylglyoximate]] (dmgH<sup>β</sup>) || || monoanionic || || |- | [[DOTA (chelator)|1,4,7,10-tetraazacyclododecane-1,4,7,10-tetraacetic acid]] (DOTA) || || || || |- | Diethylenetriaminepentaacetic acid (DTPA) ([[pentetic acid]]) || || || || |- | [[Ethylenediaminetetraacetic acid]] (EDTA) (edta<sup>4β</sup>) || (<sup>β</sup>O'''O'''CβCH<sub>2</sub>)<sub>2</sub>'''N'''βC<sub>2</sub>H<sub>4</sub>β'''N'''(CH<sub>2</sub>-C'''O'''O<sup>β</sup>)<sub>2</sub> || tetraanionic || hexadentate || |- | Ethylenediaminetriacetate || <sup>β</sup>O'''O'''CβCH<sub>2</sub>'''N'''HβC<sub>2</sub>H<sub>4</sub>β'''N'''(CH<sub>2</sub>-C'''O'''O<sup>β</sup>)<sub>2</sub> || trianionic || pentadentate || |- | [[EGTA (chemical)|Ethyleneglycolbis(oxyethylenenitrilo)tetraacetate]] (egta<sup>4β</sup>) || (<sup>β</sup>O'''O'''CβCH<sub>2</sub>)<sub>2</sub>'''N'''βC<sub>2</sub>H<sub>4</sub>β'''O'''βC<sub>2</sub>H<sub>4</sub>β'''O'''βC<sub>2</sub>H<sub>4</sub>β'''N'''(CH<sub>2</sub>βC'''O'''O<sup>β</sup>)<sub>2</sub> || tetraanionic || octodentate || |- | [[Fura-2]] || || || || |- | [[Glycine|Glycinate]] (glycinato) || '''N'''H<sub>2</sub>CH<sub>2</sub>C'''O'''O<sup>β</sup> || monoanionic || bidentate || other Ξ±-amino acid anions are comparable (but chiral) |- | [[Heme]] || || dianionic || tetradentate || macrocyclic ligand |- | [[Iminodiacetic acid]] (IDA) || || || tridentate || Used extensively to make [[radioactive tracer|radiotracers]] for [[scintigraphy]] by complexing the metastable radionuclide [[technetium-99m]]. For example, in [[cholescintigraphy]], HIDA, BrIDA, PIPIDA, and DISIDA are used |- | [[Nicotianamine]] || || || || Ubiquitous in higher [[plant]]s |- | [[Nitrosyl]] || '''N'''O<sup>+</sup> || cationic || || bent (1e<sup>β</sup>) and linear (3e<sup>β</sup>) bonding mode |- | [[Nitrilotriacetic acid]] (NTA) || || || || |- | [[Oxo (ligand)|Oxo]] || '''O'''<sup>2β</sup> || dianion || monodentate || sometimes bridging |- | [[Pyrazine]] || '''N'''<sub>2</sub>C<sub>4</sub>H<sub>4</sub> || neutral || ditopic || sometimes bridging |- | [[Scorpionate ligand]] || || || tridentate || |- | [[Sulfite]] || '''O'''β{{chem|SO|2|2β}}<br/>'''S'''β{{chem|O|3|2β}} || monoanionic || monodentate || ambidentate |- | [[Terpyridine|2,2';6',2β³-Terpyridine]] (terpy) || '''N'''C<sub>5</sub>H<sub>4</sub>βC<sub>5</sub>H<sub>3</sub>'''N'''βC<sub>5</sub>H<sub>4</sub>'''N''' || neutral || tridentate || meridional bonding only |- | [[Triazacyclononane]] (tacn) || (C<sub>2</sub>H<sub>4</sub>)<sub>3</sub>('''N'''R)<sub>3</sub> || neutral || tridentate || macrocyclic ligand<br/> see also the ''N'',''N''β²,''N''β³-trimethylated analogue |- | [[Tricyclohexylphosphine]] || '''P'''(C<sub>6</sub>H<sub>11</sub>)<sub>3</sub> or '''P'''Cy<sub>3</sub> || neutral || monodentate || |- | [[Triethylenetetramine]] (trien) || C<sub>6</sub>H<sub>18</sub>'''N<sub>4</sub>''' || neutral || tetradentate || |- | [[Trimethylphosphine]] || '''P'''(CH<sub>3</sub>)<sub>3</sub> || neutral || monodentate || |- | [[Tris(o-tolyl)phosphine]] || '''P'''(''o''-tolyl)<sub>3</sub> || neutral || monodentate || |- | [[Tris(2-aminoethyl)amine]] (tren) || ('''N'''H<sub>2</sub>CH<sub>2</sub>CH<sub>2</sub>)<sub>3</sub>'''N''' || neutral || tetradentate || |- | Tris(2-diphenylphosphineethyl)amine (np<sub>3</sub>) || || neutral || tetradentate || |- |[[Tropylium]] || {{chem|'''C'''|'''7'''|H|7|+}} || cationic || || |- |[[Carbon dioxide]] || β'''C'''O<sub>2</sub>, others || neutral || || see [[metal carbon dioxide complex]] |- |[[Phosphorus trifluoride]] (trifluorophosphorus) || β'''P'''F<sub>3</sub> || neutral || || |}
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