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==Precautions== {{Chembox | container_only = yes |Section7={{Chembox Hazards | ExternalSDS = | GHSPictograms = {{GHS corrosion}} | GHSSignalWord = Danger | HPhrases = {{H-phrases|290|318}} | PPhrases = {{P-phrases|280|305|351|338|310}}<ref>{{cite web |url=https://www.sigmaaldrich.com/catalog/product/aldrich/203319?lang=en®ion=US |title=Gallium 203319|publisher=Sigma Aldrich}}</ref> | NFPA-H = 1 | NFPA-F = 0 | NFPA-R = 0 | NFPA-S = | NFPA_ref = <ref>{{cite web |url=https://www.sigmaaldrich.com/MSDS/MSDS/DisplayMSDSPage.do?country=US&language=en&productNumber=203319&brand=ALDRICH&PageToGoToURL=https%3A%2F%2Fwww.sigmaaldrich.com%2Fcatalog%2Fproduct%2Faldrich%2F203319%3Flang%3Den |title=MSDS β 203319|publisher=Sigma Aldrich}}</ref> }} }} Metallic gallium is not toxic. However, several gallium compounds are toxic. Gallium halide complexes can be toxic.<ref>{{cite journal |last1=Ivanoff |first1=C. S. |last2=Ivanoff |first2=A. E. |last3=Hottel |first3=T. L. |date=February 2012 |title=Gallium poisoning: a rare case report. |journal=Food Chem. Toxicol. |volume=50 |issue=2 |pages=212β5 |doi=10.1016/j.fct.2011.10.041 |pmid=22024274}}</ref> The Ga<sup>3+</sup> ion of soluble gallium salts tends to form the insoluble hydroxide when injected in large doses; precipitation of this hydroxide resulted in [[nephrotoxicity]] in animals. In lower doses, soluble gallium is tolerated well and does not accumulate as a poison, instead being excreted mostly through urine. Excretion of gallium occurs in two phases: the first phase has a [[biological half-life]] of 1 hour, while the second has a biological half-life of 25 hours.<ref name="Nordberg">{{cite book |first1=Gunnar F. |last1=Nordberg |first2=Bruce A. |last2=Fowler |first3=Monica |last3=Nordberg |title=Handbook on the Toxicology of Metals |publisher=Academic Press |pages=788β90 |edition=4th |date=7 August 2014 |isbn=978-0-12-397339-9}}</ref> Inhaled Ga<sub>2</sub>O<sub>3</sub> particles are probably toxic.<ref>{{cite book |doi=10.1016/b978-0-444-52272-6.00474-8 |chapter=Gallium: Environmental Pollution and Health Effects |title=Encyclopedia of Environmental Health |date=2011 |last1=Yu |first1=H.-S. |last2=Liao |first2=W.-T. |pages=829β833 |isbn=978-0-444-52272-6 }}</ref> {{clear}}
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