Jump to content
Main menu
Main menu
move to sidebar
hide
Navigation
Main page
Recent changes
Random page
Help about MediaWiki
Special pages
Niidae Wiki
Search
Search
Appearance
Create account
Log in
Personal tools
Create account
Log in
Pages for logged out editors
learn more
Contributions
Talk
Editing
Metalloid
(section)
Page
Discussion
English
Read
Edit
View history
Tools
Tools
move to sidebar
hide
Actions
Read
Edit
View history
General
What links here
Related changes
Page information
Appearance
move to sidebar
hide
Warning:
You are not logged in. Your IP address will be publicly visible if you make any edits. If you
log in
or
create an account
, your edits will be attributed to your username, along with other benefits.
Anti-spam check. Do
not
fill this in!
===Judgment-based=== A metalloid is an element that possesses a preponderance of properties in between, or that are a mixture of, those of [[metal]]s and [[nonmetal]]s, and which is therefore hard to classify as either a [[metal]] or a [[nonmetal]]. This is a generic definition that draws on metalloid attributes consistently cited in the literature.{{refn|1=Definitions and extracts by different authors, illustrating aspects of the generic definition, follow: *"In chemistry a metalloid is an element with properties intermediate between those of [[metal]]s and [[nonmetal]]s."<ref>[[#Cusack1987|Cusack 1987, p. 360]]</ref> *"Between the [[metal]]s and [[nonmetal]]s in the periodic table we find elements ... [that] share some of the characteristic properties of both the [[metal]]s and [[Nonmetal|nonmetals]], making it difficult to place them in either of these two main categories"<ref>[[#Kelter2009|Kelter, Mosher & Scott 2009, p. 268]]</ref> *"Chemists sometimes use the name metalloid ... for these elements which are difficult to classify one way or the other."<ref name="Hill 2000, p. 41">[[#Hill2000|Hill & Holman 2000, p. 41]]</ref> *"Because the traits distinguishing [[metal]]s and [[nonmetal]]s are qualitative in nature, some elements do not fall unambiguously in either category. These elements ... are called metalloids ..."<ref>[[#King1979|King 1979, p. 13]]</ref> More broadly, metalloids have been referred to as: *"elements that ... are somewhat of a cross between [[metal]]s and [[nonmetal]]s";<ref>[[#Moore2011|Moore 2011, p. 81]]</ref> or *"weird in-between elements".<ref>[[#Gray2010|Gray 2010]]</ref>|group=n}} Difficulty of categorisation is a key attribute. Most elements have a mixture of metallic and nonmetallic properties,<ref name=Hopkins>[[#Hopkins1956|Hopkins & Bailar 1956, p. 458]]</ref> and can be classified according to which set of properties is more pronounced.<ref>[[#Glinka1965|Glinka 1965, p. 77]]</ref>{{refn|1=[[Gold]], for example, has mixed properties but is still recognised as "king of [[metal]]s". Besides metallic behaviour (such as high electrical conductivity, and [[cation]] formation), gold shows nonmetallic behaviour: *It has the [[table of standard electrode potentials|highest]] [http://www.chemguide.co.uk/physical/redoxeqia/introduction.html electrode potential] *It has the third-highest [[ionization energy]] among the [[metal]]s (after [[zinc]] and [[mercury (element)|mercury]]) *It has the highest [[electron affinity]] *Its [[electronegativity]] of 2.54 is highest among the [[metal]]s and exceeds that of some [[nonmetal]]s ([[hydrogen]] 2.2; [[phosphorus]] 2.19; and [[radon]] 2.2) *It forms the Au<sup>β</sup> auride [[anion]], acting in this way like a [[halogen]] *It sometimes has a tendency, known as "[[aurophilicity]]", to bond to itself.<ref>[[#Wiberg2001|Wiberg 2001, p. 1279]]</ref> On halogen character, see also Belpassi et al.,<ref>[[#Belpassi2006|Belpassi et al. 2006, pp. 4543β44]]</ref> who conclude that in the aurides MAu (M = [[alkali metal|LiβCs]]) gold "behaves as a halogen, intermediate between [[bromine|Br]] and [[iodine|I]]"; on aurophilicity, see also Schmidbaur and Schier.<ref>[[#Schmidbaur2008|Schmidbaur & Schier 2008, pp. 1931β51]]</ref>|group=n}} Only the elements at or near the margins, lacking a sufficiently clear preponderance of either metallic or nonmetallic properties, are classified as metalloids.<ref>[[#TM1987|Tyler Miller 1987, p. 59]]</ref> [[Boron]], [[silicon]], [[germanium]], [[arsenic]], [[antimony]], and [[tellurium]] are commonly recognised as metalloids.<ref>[[#Goldsmith1982|Goldsmith 1982, p. 526]]; [[#Kotz2009|Kotz, Treichel & Weaver 2009, p. 62]]; [[#Bettelheim|Bettelheim et al. 2010, p. 46]]</ref>{{refn|1=Mann et al.<ref name=Mann/> refer to these elements as "the recognized metalloids".|group=n}} Depending on the author, one or more from [[selenium]], [[polonium]], or [[astatine]] are sometimes added to the list.<ref>[[#Hawkes2001|Hawkes 2001, p. 1686]]; [[#Segal1989|Segal 1989, p. 965]]; [[#McMurray2009|McMurray & Fay 2009, p. 767]]</ref> [[Boron]] sometimes is excluded, by itself, or with [[silicon]].<ref>[[#Bucat1983|Bucat 1983, p. 26]]; [[#Brown2007|Brown c. 2007]]</ref> Sometimes [[tellurium]] is not regarded as a metalloid.<ref name="Swift1962,100">[[#Swift1962|Swift & Schaefer 1962, p. 100]]</ref> The inclusion of [[antimony]], [[polonium]], and [[astatine]] as metalloids has been questioned.<ref>[[#Hawkes2001|Hawkes 2001, p. 1686]]; [[#Hawkes2010|Hawkes 2010]]; [[#Holt2007|Holt, Rinehart & Wilson c. 2007]]</ref> Other elements are occasionally classified as metalloids. These elements include<ref>[[#Dunstan1968|Dunstan 1968, pp. 310, 409]]. Dunstan lists Be, Al, Ge (maybe), As, Se (maybe), Sn, Sb, Te, Pb, Bi, and Po as metalloids (pp. 310, 323, 409, 419).</ref> [[hydrogen]],<ref>[[#Tilden1876|Tilden 1876, pp. 172, 198β201]]; [[#Smith1994|Smith 1994, p. 252]]; [[#Bodner1993|Bodner & Pardue 1993, p. 354]]</ref> [[beryllium]],<ref>[[#Bassett1966|Bassett et al. 1966, p. 127]]</ref> [[nitrogen]],<ref name=rausch>[[#Rausch1960|Rausch 1960]]</ref> [[phosphorus]],<ref>[[#Thayer1977|Thayer 1977, p. 604]]; [[#Warren1981|Warren & Geballe 1981]]; [[#M&E|Masters & Ela 2008, p. 190]]</ref> [[sulfur]],<ref>[[#Warren1981|Warren & Geballe 1981]]; [[#Chalmers1959|Chalmers 1959, p. 72]]; [[#United1965|US Bureau of Naval Personnel 1965, p. 26]]</ref> [[zinc]],<ref>[[#Siebring1967|Siebring 1967, p. 513]]</ref> [[gallium]],<ref>[[#Wiberg2001|Wiberg 2001, p. 282]]</ref> [[tin]], [[iodine]],<ref>[[#Rausch1960|Rausch 1960]]; [[#Friend1953|Friend 1953, p. 68]]</ref> [[lead]],<ref>[[#Murray1928|Murray 1928, p. 1295]]</ref> [[bismuth]],<ref name="Swift1962,100"/> and [[radon]].<ref>[[#Hampel&H1966|Hampel & Hawley 1966, p. 950]]; [[#Stein1985|Stein 1985]]; [[#Stein1987|Stein 1987, pp. 240, 247β48]]</ref> The term metalloid has also been used for elements that exhibit metallic [[Lustre (mineralogy)|lustre]] and [[Electrical resistivity and conductivity|electrical conductivity]], and that are [[amphoterism|amphoteric]], such as [[arsenic]], [[antimony]], [[vanadium]], [[chromium]], [[molybdenum]], [[tungsten]], [[tin]], [[lead]], and [[aluminium]].<ref>[[#Hatcher1949|Hatcher 1949, p. 223]]; [[#Secrist|Secrist & Powers 1966, p. 459]]</ref> The [[Post-transition metal#p-block metals|p-block metals]],<ref>[[#Taylor1960|Taylor 1960, p. 614]]</ref> and nonmetals (such as carbon or nitrogen) that can form [[alloy]]s with metals<ref>[[#Considine1984|Considine & Considine 1984, p. 568]]; [[#Cegielski1998|Cegielski 1998, p. 147]]; [[#TheAmerican2005|''The American heritage science dictionary 2005'', p. 397]]</ref> or modify their properties<ref>[[#Woodward1948|Woodward 1948, p. 1]]</ref> have also occasionally been considered as metalloids.
Summary:
Please note that all contributions to Niidae Wiki may be edited, altered, or removed by other contributors. If you do not want your writing to be edited mercilessly, then do not submit it here.
You are also promising us that you wrote this yourself, or copied it from a public domain or similar free resource (see
Encyclopedia:Copyrights
for details).
Do not submit copyrighted work without permission!
Cancel
Editing help
(opens in new window)
Search
Search
Editing
Metalloid
(section)
Add topic