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==Definitions== <!--{{atomic radius}}--> Widely used definitions of atomic radius include: * [[Van der Waals radius]]: In the simplest definition, half the minimum distance between the nuclei of two atoms of the element that are not otherwise bound by covalent or metallic interactions.<ref name="Pauling1945"> {{cite book |last1=Pauling | first1=L. |year=1945<!--LoC says 1940, but everywhere else says 1945--> |title=The Nature of the Chemical Bond |edition=2nd |publisher=[[Cornell University Press]] |lccn=42034474 }}</ref> The Van der Waals radius may be defined even for elements (such as metals) in which Van der Waals forces are dominated by other interactions. Because [[Van der Waals force|Van der Waals interactions arise through quantum fluctuations of the atomic polarisation]], the polarisability (which can usually be measured or calculated more easily) may be used to define the Van der Waals radius indirectly.<ref name="Federov2018"> {{cite journal |last1=Federov |first1=Dmitry V. |last2=Sadhukhan |first2=Mainak |last3=StΓΆhr |first3=Martin |last4=Tkatchenko |first4=Alexandre |year=2018 |title=Quantum-Mechanical Relation between Atomic Dipole Polarizability and the van der Waals Radius |url=https://journals.aps.org/prl/abstract/10.1103/PhysRevLett.121.183401 |journal=[[Physical Review Letters]] |volume=121 |issue=18 |pages=183401 |access-date=9 May 2021 |doi=10.1103/PhysRevLett.121.183401 |pmid=30444421 |arxiv=1803.11507 |bibcode=2018PhRvL.121r3401F |s2cid=53564141 }}</ref> * [[Ionic radius]]: the nominal radius of the ions of an element in a specific ionization state, deduced from the spacing of atomic nuclei in crystalline salts that include that ion. In principle, the spacing between two adjacent oppositely charged ions (the [[bond length|length]] of the [[ionic bond]] between them) should equal the sum of their ionic radii.<ref name="Pauling1945"/> * [[Covalent radius]]: the nominal radius of the atoms of an element when [[covalent bond|covalently bound]] to other atoms, as deduced from the separation between the atomic nuclei in molecules. In principle, the distance between two atoms that are bound to each other in a molecule (the length of that covalent bond) should equal the sum of their covalent radii.<ref name="Pauling1945"/> * [[Metallic radius]]: the nominal radius of atoms of an element when joined to other atoms by [[metallic bond]]s.{{citation needed|date=August 2009}} * [[Bohr radius]]: the radius of the lowest-energy electron orbit predicted by [[Bohr model]] of the atom (1913).<ref name="bohrI"> {{cite journal |last=Bohr |first=N. |year=1913 |title=On the Constitution of Atoms and Molecules, Part I. β Binding of Electrons by Positive Nuclei |url=http://web.ihep.su/dbserv/compas/src/bohr13/eng.pdf |archive-url=https://web.archive.org/web/20110902020206/http://web.ihep.su/dbserv/compas/src/bohr13/eng.pdf |archive-date=2011-09-02 |url-status=live |journal=[[Philosophical Magazine]] |series=6 |volume=26 |issue=151 |pages=1β24 |access-date=8 June 2011 |doi=10.1080/14786441308634955 |bibcode=1913PMag...26....1B }}</ref><ref name="bohrII"> {{cite journal |last=Bohr |first=N. |year=1913 |title=On the Constitution of Atoms and Molecules, Part II. β Systems containing only a Single Nucleus |url=http://web.ihep.su/dbserv/compas/src/bohr13b/eng.pdf |archive-url=https://web.archive.org/web/20081209111729/http://web.ihep.su/dbserv/compas/src/bohr13b/eng.pdf |archive-date=2008-12-09 |url-status=live |journal=[[Philosophical Magazine]] |series=6 |volume=26 |issue=153 |pages=476β502 |access-date=8 June 2011 |doi=10.1080/14786441308634993 |bibcode=1913PMag...26..476B }}</ref> It is only applicable to [[hydrogen-like atom|atoms and ions with a single electron]], such as [[hydrogen]], singly ionized [[helium]], and [[positronium]]. Although the model itself is now obsolete, the Bohr radius for the hydrogen atom is still regarded as an important physical constant, because it is equivalent to the quantum-mechanical most probable distance of the electron from the nucleus.
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