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===Alum found at archaeological sites=== The western desert of Egypt was a major source of alum substitutes in antiquity. These [[evaporite]]s were mainly {{chem|Fe|Al|2|(SO|4|)|4|路22鈥疕|2|O}}, {{chem|Mg|Al|2|(SO|4|)|4|路22鈥疕|2|O}}, {{chem|NaAl(SO|4|)|2|路6鈥疕|2|O}}, {{chem|Mg|SO|4|路7H|2|O}} and {{chem|Al|2|(SO|4|)|3|路17鈥疕|2|O}}.{{refn|name=Picon-etal-2005-lAlun| {{cite conference |author1=Picon, M. |author-link=Maurice Picon |display-authors=etal |date=2005 |title=L'alun des oasis occidentales d'Egypte: Researches sur terrain et recherches en laboratoire}} }} <ref name="Borgard-Brun-Picon-2005-06-07-alunMedit" /> The [[Ancient Greece|Ancient Greek]] [[Herodotus]] mentions Egyptian alum as a valuable commodity in ''The Histories''.<ref name=Herodotus-c430蕶岽勧磭-Hists/> The production of potassium alum from [[alunite]] is archaeologically attested on the island [[Lesbos]].{{refn|name=Archontidou-2005-alunMedit| {{cite conference |last=Archontidou |first=A. |date=2005 |title=Un atelier de preparation de l'alun a partir de l'alunite dans l'isle de Lesbos |language=fr,grc }} <ref name="Borgard-Brun-Picon-2005-06-07-alunMedit" /> }} The site was abandoned during the 7th century CE, but dates back at least to the 2nd century CE. Native ''alumen'' from the island of [[Melos]] appears to have been a mixture mainly of alunogen ({{chem|Al|2|(SO|4|)|3|路17鈥疕|2|O}}) with potassium alum and other minor sulfates.{{refn|name=Hall-Jones-2005-alunMedit| {{cite conference |first1=A. J. |last1=Hall |first2=E. |last2=Photos-Jones |date=2005 |title=The nature of Melian alumen and its potential for exploitation in Antiquity }} <ref name="Borgard-Brun-Picon-2005-06-07-alunMedit" /> }}
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