Jump to content
Main menu
Main menu
move to sidebar
hide
Navigation
Main page
Recent changes
Random page
Help about MediaWiki
Special pages
Niidae Wiki
Search
Search
Appearance
Create account
Log in
Personal tools
Create account
Log in
Pages for logged out editors
learn more
Contributions
Talk
Editing
Carbon monoxide
(section)
Page
Discussion
English
Read
Edit
View history
Tools
Tools
move to sidebar
hide
Actions
Read
Edit
View history
General
What links here
Related changes
Page information
Appearance
move to sidebar
hide
Warning:
You are not logged in. Your IP address will be publicly visible if you make any edits. If you
log in
or
create an account
, your edits will be attributed to your username, along with other benefits.
Anti-spam check. Do
not
fill this in!
==Use== ===Chemical industry=== Carbon monoxide is an [[industrial gas]] that has many applications in bulk chemicals manufacturing.<ref>{{cite book|last1=Elschenbroich|first1=C.|title=Organometallics: A Concise Introduction|last2=Salzer|first2=A.|publisher=Wiley-VCH|year=2006|isbn=978-3-527-28165-7|edition=2nd|location=Weinheim}}</ref> Large quantities of aldehydes are produced by the [[hydroformylation]] reaction of [[alkene]]s, carbon monoxide, and {{chem2|H2}}. Hydroformylation is coupled to the [[Shell higher olefin process]] to give precursors to [[detergent]]s. [[Phosgene]], useful for preparing isocyanates, polycarbonates, and polyurethanes, is produced by passing purified carbon monoxide and [[chlorine]] gas through a bed of porous [[activated carbon]], which serves as a [[catalyst]]. World production of this compound was estimated to be 2.74 million tonnes in 1989.<ref name="Ullmann">{{Ullmann's|author1=Wolfgang Schneider|author2=Werner Diller|title=Phosgene|doi=10.1002/14356007.a19_411}}</ref> :{{chem2|CO + Cl2 -> COCl2}} [[Methanol]] is produced by the [[hydrogenation]] of carbon monoxide. In a related reaction, the hydrogenation of carbon monoxide is coupled to C−C bond formation, as in the [[Fischer–Tropsch process]] where carbon monoxide is hydrogenated to liquid hydrocarbon fuels. This technology allows [[coal]] or biomass to be converted to diesel. In the [[Cativa process]], carbon monoxide and methanol react in the presence of a homogeneous [[iridium]] [[catalyst]] and [[hydroiodic acid]] to give [[acetic acid]]. This process is responsible for most of the industrial production of acetic acid. ===Metallurgy=== {{Main|Metallurgy}} Carbon monoxide is a strong reductive agent and has been used in [[pyrometallurgy]] to reduce [[metal]]s from [[ore]]s since ancient times. Carbon monoxide strips oxygen off metal oxides, reducing them to pure metal in high temperatures, forming [[carbon dioxide]] in the process. Carbon monoxide is not usually supplied as is, in the gaseous phase, in the reactor, but rather it is formed in high temperature in presence of oxygen-carrying ore, or a carboniferous agent such as coke, and high temperature. The [[blast furnace]] process is a typical example of a process of reduction of metal from ore with carbon monoxide. Likewise, [[blast furnace gas]] collected at the top of blast furnace, still contains some 10% to 30% of carbon monoxide, and is used as fuel on [[Cowper stove]]s and on Siemens-Martin furnaces on [[open hearth furnace|open hearth steelmaking]]. ===Proposed use as a rocket fuel === Carbon monoxide has been proposed for use as a fuel on Mars by NASA researcher [[Geoffrey Landis]]. [[Carbon monoxide/oxygen engine]]s have been suggested for early surface transportation use as both carbon monoxide and oxygen can be straightforwardly produced from the carbon dioxide [[atmosphere of Mars]] by [[zirconia]] [[electrolysis]], without using any [[Water on Mars|Martian water resources]] to obtain hydrogen, which would be needed to make methane or any hydrogen-based fuel.<ref name="landis2001">{{cite journal|last=Landis|date=2001|title=Mars Rocket Vehicle Using In Situ Propellants|journal=Journal of Spacecraft and Rockets|volume=38|issue=5|pages=730–735|bibcode=2001JSpRo..38..730L|doi=10.2514/2.3739}}</ref> Landis also proposed manufacturing the fuel from the similar carbon dioxide atmosphere of Venus for a sample return mission, in combination with solar-powered UAVs and rocket balloon ascent.<ref name="o253">{{cite web |date=2024-01-04 |title=Sample Return from the Surface of Venus |url=https://www.nasa.gov/general/sample-return-from-the-surface-of-venus/ |access-date=2024-05-29 |website=NASA}}</ref>
Summary:
Please note that all contributions to Niidae Wiki may be edited, altered, or removed by other contributors. If you do not want your writing to be edited mercilessly, then do not submit it here.
You are also promising us that you wrote this yourself, or copied it from a public domain or similar free resource (see
Encyclopedia:Copyrights
for details).
Do not submit copyrighted work without permission!
Cancel
Editing help
(opens in new window)
Search
Search
Editing
Carbon monoxide
(section)
Add topic