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===Reaction overview=== {| class="wikitable sortable" style="background-color:white;float: center; border-collapse: collapse; margin: 0em 1em;" border="1" cellpadding="2" cellspacing="0" ! width=200px|Reaction name !! Product !! class="unsortable" | Comment |- |valign=top | [[Hydrogenation]] |valign=top| alkanes | addition of hydrogen |- | [[Hydroalkenylation]] | alkenes | hydrometalation / insertion / beta-elimination by metal catalyst |- |valign=top | [[Halogen addition reaction]] |valign=top| 1,2-dihalide | electrophilic addition of halogens |- |valign=top | [[Hydrohalogenation]] ([[Markovnikov's rule|Markovnikov]]) |valign=top| haloalkanes | addition of hydrohalic acids |- |valign=top | Anti-Markovnikov [[hydrohalogenation]] |valign=top| haloalkanes | free radicals mediated addition of hydrohalic acids |- |valign=top | [[Hydroamination]] |valign=top| amines | addition of {{chem2|N\sH}} bond across {{chem2|C\sC}} double bond |- |valign=top | [[Hydroformylation]] |valign=top| aldehydes | industrial process, addition of CO and {{chem2|H2}} |- |valign=top | [[Hydrocarboxylation]] and [[Koch reaction]] |valign=top| carboxylic acid | industrial process, addition of CO and {{chem2|H2O}}. |- |valign=top | [[Carboalkoxylation]] |valign=top| ester | industrial process, addition of CO and alcohol. |- |valign=top| [[alkylation]] |valign=top| ester |industrial process: alkene alkylating carboxylic acid with [[silicotungstic acid]] the catalyst. |- |valign=top | [[Sharpless bishydroxylation]] |valign=top| diols | oxidation, reagent: osmium tetroxide, chiral ligand |- |valign=top| [[Woodward cis-hydroxylation|Woodward ''cis''-hydroxylation]] |valign=top|diols |oxidation, reagents: iodine, silver acetate |- |valign=top| [[Ozonolysis]] |valign=top| aldehydes or ketones |reagent: ozone |- | [[Olefin metathesis]] | alkenes | two alkenes rearrange to form two new alkenes |- | [[Diels–Alder reaction]] | cyclohexenes | cycloaddition with a diene |- | [[Pauson–Khand reaction]] | cyclopentenones | cycloaddition with an alkyne and CO |- | [[Hydroboration–oxidation]] | alcohols | reagents: borane, then a peroxide |- | [[Oxymercuration-reduction]] | alcohols | electrophilic addition of mercuric acetate, then reduction |- | [[Prins reaction]] | 1,3-diols | electrophilic addition with aldehyde or ketone |- | [[Paterno–Büchi reaction]] | oxetanes | photochemical reaction with aldehyde or ketone |- | [[Epoxidation]] | epoxide | electrophilic addition of a peroxide |- | [[Cyclopropanation]] | cyclopropanes | addition of carbenes or carbenoids |- | [[Hydroacylation]] | ketones | oxidative addition / reductive elimination by metal catalyst |- | [[Hydrophosphination]] | phosphines | |- |}
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