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===Density=== Most organic solvents have a lower [[density]] than water, which means they are lighter than and will form a layer on top of water. Important exceptions are most of the [[halogen]]ated solvents like [[dichloromethane]] or [[chloroform]] will sink to the bottom of a container, leaving water as the top layer. This is crucial to remember when [[partition coefficient|partitioning]] compounds between solvents and water in a [[separatory funnel]] during chemical syntheses. Often, [[specific gravity]] is cited in place of density. Specific gravity is defined as the density of the solvent divided by the density of water at the same temperature. As such, specific gravity is a unitless value. It readily communicates whether a water-insoluble solvent will float (SG < 1.0) or sink (SG > 1.0) when mixed with water. {| class="wikitable sortable mw-collapsible mw-collapsed" style="margin:1em auto; text-align:center;" ! Solvent ! [[Specific gravity]]<ref>[http://www.xydatasource.com/xy-showdatasetpage.php?datasetcode=831841&dsid=97&searchtext=solvent Selected solvent properties β Specific Gravity] {{webarchive|url=https://web.archive.org/web/20110614130527/http://www.xydatasource.com/xy-showdatasetpage.php?datasetcode=831841&dsid=97&searchtext=solvent |date=14 June 2011 }}. Xydatasource.com. Retrieved on 26 January 2013.</ref> |- | Pentane | 0.626 |- | Petroleum ether | 0.656 |- | Hexane | 0.659 |- | Heptane | 0.684 |- | Diethyl amine | 0.707 |- | Diethyl ether | 0.713 |- | Triethyl amine | 0.728 |- | ''tert''-Butyl methyl ether | 0.741 |- | Cyclohexane | 0.779 |- | ''tert''-Butyl alcohol | 0.781 |- | Isopropanol | 0.785 |- | Acetonitrile | 0.786 |- | Ethanol | 0.789 |- | Acetone | 0.790 |- | Methanol | 0.791 |- | Methyl isobutyl ketone | 0.798 |- | Isobutyl alcohol | 0.802 |- | 1-Propanol | 0.803 |- | Methyl ethyl ketone | 0.805 |- | 2-Butanol | 0.808 |- | Isoamyl alcohol | 0.809 |- | 1-Butanol | 0.810 |- | Diethyl ketone | 0.814 |- | 1-Octanol | 0.826 |- | ''p''-Xylene | 0.861 |- | ''m''-Xylene | 0.864 |- | Toluene | 0.867 |- | Dimethoxyethane | 0.868 |- | Benzene | 0.879 |- | Butyl acetate | 0.882 |- | 1-Chlorobutane | 0.886 |- | Tetrahydrofuran | 0.889 |- | Ethyl acetate | 0.895 |- | ''o''-Xylene | 0.897 |- | Hexamethylphosphorus triamide | 0.898 |- | 2-Ethoxyethyl ether | 0.909 |- | ''N'',''N''-Dimethylacetamide | 0.937 |- | [[Diglyme|Diethylene glycol dimethyl ether]] | 0.943 |- | ''N'',''N''-Dimethylformamide | 0.944 |- | 2-Methoxyethanol | 0.965 |- | Pyridine | 0.982 |- | Propanoic acid | 0.993 |- | Water | 1.000 |- | 2-Methoxyethyl acetate | 1.009 |- | Benzonitrile | 1.01 |- | 1-Methyl-2-pyrrolidinone | 1.028 |-. | Hexamethylphosphoramide | 1.03 |- | 1,4-Dioxane | 1.033 |- | Acetic acid | 1.049 |- | Acetic anhydride | 1.08 |- | Dimethyl sulfoxide | 1.092 |- | Chlorobenzene | 1.1066 |- | Deuterium oxide | 1.107 |- | Ethylene glycol | 1.115 |- | Diethylene glycol | 1.118 |- | Propylene carbonate | 1.21 |- | Formic acid | 1.22 |- | 1,2-Dichloroethane | 1.245 |- | Glycerin | 1.261 |- | Carbon disulfide | 1.263 |- | 1,2-Dichlorobenzene | 1.306 |- | Methylene chloride | 1.325 |- | Nitromethane | 1.382 |- | 2,2,2-Trifluoroethanol | 1.393 |- | Chloroform | 1.498 |- | 1,1,2-Trichlorotrifluoroethane | 1.575 |- | Carbon tetrachloride | 1.594 |- | Tetrachloroethylene | 1.623 |}
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