Editing Phosphor (section)

====Color television CRTs====
{{missing information|section|time period of each phosphor composition|date=October 2020}}
The phosphors in color CRTs need higher contrast and resolution than the black-and-white ones. The energy density of the electron beam is about 100 times greater than in black-and-white CRTs; the electron spot is focused to about 0.2&nbsp;mm diameter instead of about 0.6&nbsp;mm diameter of the black-and-white CRTs. Effects related to electron irradiation degradation are therefore more pronounced.

Color CRTs require three different phosphors, emitting in red, green and blue, patterned on the screen. Three separate electron guns are used for color production (except for displays that use [[beam-index tube]] technology, which is rare). The red phosphor has always been a problem, being the dimmest of the three necessitating the brighter green and blue electron beam currents be adjusted down to make them equal the red phosphor's lower brightness. This made early color TVs only usable indoors as bright light made it impossible to see the dim picture, while portable black-and-white TVs viewable in outdoor sunlight were already common.

The composition of the phosphors changed over time, as better phosphors were developed and as environmental concerns led to lowering the content of cadmium and later abandoning it entirely. The {{chem2|(Zn,Cd)S:Ag,Cl}} was replaced with {{chem2|(Zn,Cd)S:Cu,Al}} with lower cadmium/zinc ratio, and then with cadmium-free {{chem2|ZnS:Cu,Al}}.

The blue phosphor stayed generally unchanged, a silver-doped zinc sulfide. The green phosphor initially used manganese-doped zinc silicate, then evolved through silver-activated cadmium-zinc sulfide, to lower-cadmium copper-aluminium activated formula, and then to cadmium-free version of the same. The red phosphor saw the most changes; it was originally manganese-activated zinc phosphate, then a silver-activated cadmium-zinc sulfide, then the europium(III) activated phosphors appeared; first in an [[yttrium vanadate]] matrix, then in [[yttrium oxide]] and currently in [[yttrium oxysulfide]]. The evolution of the phosphors was therefore (ordered by B-G-R):
* {{chem2|ZnS:Ag}}&nbsp;&ndash;&nbsp;{{chem2|Zn2SiO4:Mn}}&nbsp;&ndash;&nbsp;{{chem2|Zn3(PO4)2:Mn}}
* {{chem2|ZnS:Ag}}&nbsp;&ndash;&nbsp;{{chem2|(Zn,Cd)S:Ag}}&nbsp;&ndash;&nbsp;{{chem2|(Zn,Cd)S:Ag}}
* {{chem2|ZnS:Ag}}&nbsp;&ndash;&nbsp;{{chem2|(Zn,Cd)S:Ag}}&nbsp;&ndash;&nbsp;{{chem2|YVO4:Eu(3+)}} (1964&ndash;?)
* {{chem2|ZnS:Ag}}&nbsp;&ndash;&nbsp;{{chem2|(Zn,Cd)S:Cu,Al}}&nbsp;&ndash;&nbsp;{{chem2|Y2O2S:Eu(3+)}} or {{chem2|Y2O3:Eu(3+)}}
* {{chem2|ZnS:Ag}}&nbsp;&ndash;&nbsp;{{chem2|ZnS:Cu,Al}} or {{chem2|ZnS:Au,Cu,Al}}&nbsp;&ndash;&nbsp;{{chem2|Y2O2S:Eu(3+)}}<ref name="lumdisp"/>