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===Construction=== The main use of calcium carbonate is in the construction industry, either as a building material, or limestone [[Construction aggregate|aggregate]] for road building, as an ingredient of [[cement]], or as the starting material for the preparation of [[slaked lime|builders' lime]] by burning in a [[kiln]]. However, because of weathering mainly caused by [[acid rain]],<ref>{{cite web|title = Effects of Acid Rain|publisher = US Environmental Protection Agency|access-date = 14 March 2015|url = http://www.epa.gov/acidrain/effects/materials.html|archive-date = 2 March 2015|archive-url = https://web.archive.org/web/20150302173739/http://www.epa.gov/acidrain/effects/materials.html|url-status = live}}</ref> calcium carbonate (in limestone form) is no longer used for building purposes on its own, but only as a raw primary substance for building materials. Calcium carbonate is also used in the purification of [[iron]] from [[iron ore]] in a [[blast furnace]]. The carbonate is [[Calcination|calcined]] ''in situ'' to give [[calcium oxide]], which forms a [[slag]] with various impurities present, and separates from the purified iron.<ref>{{cite web|title = Blast Furnace|publisher = Science Aid|access-date = 30 December 2007|url = http://www.scienceaid.co.uk/chemistry/industrial/blastfurnace.html|archive-url = https://web.archive.org/web/20071217143213/http://www.scienceaid.co.uk/chemistry/industrial/blastfurnace.html|archive-date = 17 December 2007}}</ref> In the [[oil industry]], calcium carbonate is added to [[drilling fluid]]s as a formation-bridging and filtercake-sealing agent; it is also a weighting material which increases the density of drilling fluids to control the downhole pressure. Calcium carbonate is added to [[swimming pool]]s, as a [[pH]] corrector for maintaining [[alkalinity]] and offsetting the acidic properties of the [[disinfectant]] agent.<ref>{{Cite book|url=https://books.google.com/books?id=8jF-AwAAQBAJ&q=Calcium+carbonate+is+also+mixed+with+putty+in+setting+stained+glass+windows,+and+as+a+resist+to+prevent+glass+from+sticking+to+kiln+shelves+when+firing+glazes+and+paints+at+high+temperature&pg=PT1601|title=Health & Drugs: Disease, Prescription & Medication|last=Sfetcu|first=Nicolae|date=2014-05-02|publisher=Nicolae Sfetcu|language=en}}</ref> It is also used as a raw material in the [[Sugar refining|refining of sugar]] from [[sugar beet]]; it is calcined in a kiln with [[anthracite]] to produce calcium oxide and carbon dioxide. This burnt lime is then slaked in fresh water to produce a calcium hydroxide [[Suspension (chemistry)|suspension]] for the precipitation of impurities in raw juice during [[carbonatation]].<ref>{{cite book|last1=McGinnis|first1=R. A.|title=Beet-Sugar Technology|publisher=Beet Sugar Development Foundation|page=178|edition=2nd}}</ref> Calcium carbonate in the form of [[chalk]] has traditionally been a major component of [[blackboard]] chalk. However, modern manufactured chalk is mostly [[gypsum]], hydrated [[calcium sulfate]] {{chem2|CaSO4*2H2O}}. Calcium carbonate is a main source for growing [[biorock]]. Precipitated calcium carbonate (PCC), pre-dispersed in [[slurry]] form, is a common filler material for [[latex gloves]] with the aim of achieving maximum saving in material and production costs.<ref name=precaco3>{{cite web|title=Precipitated Calcium Carbonate uses |url=http://www.aristocratholding.com/calris-5.html |archive-url=https://web.archive.org/web/20140725032803/http://www.aristocratholding.com/calris-5.html |archive-date=25 July 2014}}</ref> Fine ground calcium carbonate (GCC) is an essential ingredient in the microporous film used in [[diapers]] and some building films, as the pores are nucleated around the calcium carbonate particles during the manufacture of the film by biaxial stretching. GCC and PCC are used as a filler in [[paper]] because they are cheaper than [[wood fiber]]. Printing and writing paper can contain 10β20% calcium carbonate. In North America, calcium carbonate has begun to replace [[Kaolinite|kaolin]] in the production of [[glossy paper]]. Europe has been practicing this as alkaline [[papermaking]] or acid-free papermaking for some decades. PCC used for paper filling and paper coatings is precipitated and prepared in a variety of shapes and sizes having characteristic narrow particle size distributions and equivalent spherical diameters of 0.4 to 3 micrometers.{{citation needed|date=June 2015}} Calcium carbonate is widely used as an [[Extender (ink)|extender]] in [[paint]]s,<ref name = reade>{{cite web|title = Calcium Carbonate Powder|publisher = Reade Advanced Materials|date = 4 February 2006|access-date = 30 December 2007|url = http://www.reade.com/Products/Minerals_and_Ores/calcium_carbonate.html|archive-url = https://web.archive.org/web/20080222003757/http://www.reade.com/Products/Minerals_and_Ores/calcium_carbonate.html|archive-date = 22 February 2008}}</ref> in particular [[Gloss and matte paint|matte]] [[emulsion paint]] where typically 30% by weight of the paint is either chalk or marble. It is also a popular filler in plastics.<ref name = reade/> Some typical examples include around 15β20% loading of chalk in [[Polyvinyl chloride|unplasticized polyvinyl chloride]] (uPVC) [[Rain gutter|drainpipes]], 5β15% loading of [[stearic acid|stearate]]-coated chalk or marble in uPVC window profile. [[Polyvinyl chloride|PVC]] cables can use calcium carbonate at loadings of up to 70 phr (parts per hundred parts of resin) to improve mechanical properties (tensile strength and elongation) and electrical properties (volume resistivity).{{citation needed|date=June 2015}} [[Polypropylene]] compounds are often filled with calcium carbonate to increase rigidity, a requirement that becomes important at high usage temperatures.<ref name= Imerys>{{cite web |url=http://www.imerys-perfmins.com/calcium-carbonate/eu/calcium-carbonate-plastic.htm |title=Calcium carbonate in plastic applications |access-date=1 August 2008 |publisher=Imerys Performance Minerals |archive-url=https://web.archive.org/web/20080804020529/http://www.imerys-perfmins.com/calcium-carbonate/eu/calcium-carbonate-plastic.htm |archive-date=4 August 2008}}</ref> Here the percentage is often 20β40%. It also routinely used as a filler in [[Thermosetting plastic|thermosetting resins]] (sheet and bulk molding compounds)<ref name = Imerys/> and has also been mixed with [[acrylonitrile butadiene styrene|ABS]], and other ingredients, to form some types of compression molded "clay" [[poker chip]]s.<ref>{{Cite web|url=http://www.xintuchemical.com/why-do-calcium-carbonate-play-an-important-part-in-industrial-a-59.html|title=Why do calcium carbonate play an important part in Industrial|website=www.xintuchemical.com|language=en|access-date=2018-10-07|archive-date=7 October 2018|archive-url=https://web.archive.org/web/20181007183653/http://www.xintuchemical.com/why-do-calcium-carbonate-play-an-important-part-in-industrial-a-59.html|url-status=live}}</ref> Precipitated calcium carbonate, made by dropping [[calcium oxide]] into water, is used by itself or with additives as a white paint, known as [[whitewash]]ing.<ref>{{Cite web|url=https://www.dgci.be/18122-11/precipitated_calcium_carbonate_commodity_price|title=precipitated calcium carbonate commodity price|website=www.dgci.be|access-date=2018-10-07|archive-url=https://web.archive.org/web/20181007223232/https://www.dgci.be/18122-11/precipitated_calcium_carbonate_commodity_price|archive-date=7 October 2018}}</ref><ref name="JimohEtAl2017">{{cite journal | url=http://www.scielo.org.za/pdf/sajc/v70/01.pdf | title=Understanding the Precipitated Calcium Carbonate (PCC) Production Mechanism and Its Characteristics in the LiquidβGas System Using Milk of Lime (MOL) Suspension | author=Jimoh, O.A. | display-authors=et al | journal=South African Journal of Chemistry | year=2017 | volume=70 | pages=1β7 | doi=10.17159/0379-4350/2017/v70a1 | doi-access=free | access-date=7 October 2018 | archive-date=21 September 2018 | archive-url=https://web.archive.org/web/20180921161721/http://www.scielo.org.za/pdf/sajc/v70/01.pdf | url-status=live}}</ref> Calcium carbonate is added to a wide range of trade and [[do it yourself]] adhesives, sealants, and decorating fillers.<ref name = reade/> Ceramic tile adhesives typically contain 70% to 80% limestone. Decorating crack fillers contain similar levels of marble or dolomite. It is also mixed with putty in setting [[stained glass]] windows, and as a resist to prevent glass from sticking to kiln shelves when firing glazes and paints at high temperature.<ref>{{Cite web|url=https://www.chemicalprocessing.com/experts/environmental-protection/show/533|access-date=2021-02-03|website=www.chemicalprocessing.com | title = Topic: Re: Can our calcium carbonate "waste" be utilized in other industries so we can divert it from landfills? | date = 4 March 2010 | url-status = live|archive-url=https://web.archive.org/web/20170323143544/http://www.chemicalprocessing.com:80/experts/environmental-protection/show/533/ |archive-date=23 March 2017}}</ref><ref>{{Cite web|title=Why do calcium carbonate play an important part in Industry?|url=http://www.xintuchemical.com/why-do-calcium-carbonate-play-an-important-part-in-industrial-a-59.html|access-date=2021-02-03|website=www.xintuchemical.com|archive-date=7 October 2018|archive-url=https://web.archive.org/web/20181007183653/http://www.xintuchemical.com/why-do-calcium-carbonate-play-an-important-part-in-industrial-a-59.html|url-status=live}}</ref><ref>{{Cite web|title=Calcium Carbonates / Calcite/ Limestone. CaCO3 {{!}} Rajasthan Minerals & Chemicals|url=http://www.rmcl.co.in/calcium-carbonates_calcite.html|access-date=2021-02-03|website=www.rmcl.co.in|archive-date=15 April 2021|archive-url=https://web.archive.org/web/20210415090019/http://www.rmcl.co.in/calcium-carbonates_calcite.html}}</ref><ref>{{Cite web|url=http://kamceramics.com/portfolio/calcium-carbonate/|title=Calcium Carbonate|access-date=2021-02-03|website=kamceramics.com|archive-date=15 April 2021|archive-url=https://web.archive.org/web/20210415064720/http://kamceramics.com/portfolio/calcium-carbonate/|url-status=live}}</ref> In [[ceramic glaze]] applications, calcium carbonate is known as ''whiting'',<ref name = reade/> and is a common ingredient for many glazes in its white powdered form. When a glaze containing this material is fired in a kiln, the whiting acts as a [[Ceramic flux|flux]] material in the glaze. Ground calcium carbonate is an [[abrasive]] (both as scouring powder and as an ingredient of household scouring creams), in particular in its calcite form, which has the relatively low hardness level of 3 on the [[Mohs scale of mineral hardness|Mohs scale]], and will therefore not scratch [[glass]] and most other [[ceramic]]s, [[Vitreous enamel|enamel]], [[bronze]], [[iron]], and [[steel]], and have a moderate effect on softer metals like [[aluminium]] and [[copper]]. A paste made from calcium carbonate and [[deionized water]] can be used to clean [[tarnish]] on [[silver]].<ref name="Make it Shine">{{cite web|title = Ohio Historical Society Blog: Make It Shine|publisher = Ohio Historical Society|url = http://ohiohistory.wordpress.com/2011/06/02/making-it-shine/|access-date = 2 June 2011|archive-url = https://web.archive.org/web/20120323201653/http://ohiohistory.wordpress.com/2011/06/02/making-it-shine/|archive-date = 23 March 2012}}</ref>
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