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===Solubility=== Chalcedony is more [[soluble]] than quartz under low-temperature conditions, despite the two minerals being chemically identical. Possible reasons include the existence of the moganite component, defects caused by [[Crystal twinning|Brazil twinning]], and small crystal size.<ref name="Gislason_1993">{{cite journal |last1=Gislason |first1= S. R. |last2=Heaney |first2= P. J. |last3= Veblen |first3= D. R. |last4= Livi |first4= K. J. T. |journal=Chemical Geology |date=March 1993 |title=The difference between the solubility of quartz and chalcedony: the cause? |volume= 107 |issue= 3–4 |url= https://www.academia.edu/13667025 |pages=363–366 |doi=10.1016/0009-2541(93)90210-A |bibcode= 1993ChGeo.107..363G |access-date=2024-04-12}}</ref><ref name="heany_1992" /> ====Solubility of quartz and chalcedony in pure water==== This table gives equilibrium concentrations of total dissolved silicon as calculated by ''PHREEQC'' (PH REdox EQuilibrium (in C language, USGS)) using the llnl.dat database.{{Citation needed|date=December 2009}} {{table alignment}} {| class="wikitable col2right col3right" |+Comparative solubility (mg/L) ! Temperature ! Quartz ! Chalcedony |- ! 0.01 °C | 0.68 | 1.34 |- ! 25.0 °C | 2.64 | 4.92 |- ! 50.0 °C | 6.95 | 12.35 |- ! 75.0 °C | 14.21 | 24.23 |- ! 100.0 °C | 24.59 | 40.44 |}
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