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==Manufacture== {{main|Hydrogen cyanide#Production and synthesis}} The principal process used to manufacture cyanides is the [[Andrussow process]] in which gaseous [[hydrogen cyanide]] is produced from [[methane]] and [[ammonia]] in the presence of [[oxygen]] and a [[platinum]] [[catalyst]].<ref>{{cite journal |title=Über die schnell verlaufenden katalytischen Prozesse in strömenden Gasen und die Ammoniak-Oxydation (V) |trans-title=About the quicka catalytic processes in flowing gases and the ammonia oxidation (V) |language=de |author-link1=Leonid Andrussow |first1=Leonid |last1=Andrussow |journal=Berichte der Deutschen Chemischen Gesellschaft |volume=60 |issue=8 |pages=2005–2018 |year=1927 |doi=10.1002/cber.19270600857}}</ref><ref>{{cite journal |title=Über die katalytische Oxydation von Ammoniak-Methan-Gemischen zu Blausäure |trans-title=About the catalytic oxidation of ammonia-methane mixtures to cyanide |language=de |first1=L. |last1=Andrussow |journal=[[Angewandte Chemie]] |volume=48 |issue=37 |pages=593–595 |year=1935 |doi=10.1002/ange.19350483702 |bibcode=1935AngCh..48..593A}}</ref> :{{chem2|2 CH4 + 2 NH3 + 3 O2 → 2 HCN + 6 H2O}} Sodium cyanide, the precursor to most cyanides, is produced by treating [[hydrogen cyanide]] with [[sodium hydroxide]]:<ref name=Ullmann /> :{{chem2|HCN + NaOH → NaCN + H2O}}
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