Jump to content
Main menu
Main menu
move to sidebar
hide
Navigation
Main page
Recent changes
Random page
Help about MediaWiki
Special pages
Niidae Wiki
Search
Search
Appearance
Create account
Log in
Personal tools
Create account
Log in
Pages for logged out editors
learn more
Contributions
Talk
Editing
Chemical equilibrium
(section)
Page
Discussion
English
Read
Edit
View history
Tools
Tools
move to sidebar
hide
Actions
Read
Edit
View history
General
What links here
Related changes
Page information
Appearance
move to sidebar
hide
Warning:
You are not logged in. Your IP address will be publicly visible if you make any edits. If you
log in
or
create an account
, your edits will be attributed to your username, along with other benefits.
Anti-spam check. Do
not
fill this in!
==Types of equilibrium== {{Quote box|title=[[Haber–Bosch process]] |quote=<div> # N<sub>2</sub> (g) {{eqm}} N<sub>2</sub> [[Adsorption|(adsorbed)]] # N<sub>2</sub> (adsorbed) {{eqm}} 2 N (adsorbed) # H<sub>2</sub> (g) {{eqm}} H<sub>2</sub> (adsorbed) # H<sub>2</sub> (adsorbed) {{eqm}} 2 H (adsorbed) # N (adsorbed) + 3 H(adsorbed) {{eqm}} NH<sub>3</sub> (adsorbed) # NH<sub>3</sub> (adsorbed) {{eqm}} NH<sub>3</sub> (g) </div> }} Equilibrium can be broadly classified as heterogeneous and homogeneous equilibrium.<ref>{{Cite web|url=https://www.chemguide.co.uk/physical/equilibria/kc.html|title = Equilibrium constants – Kc}}</ref> Homogeneous equilibrium consists of reactants and products belonging in the same phase whereas heterogeneous equilibrium comes into play for reactants and products in different phases. * In the gas phase: [[rocket engine]]s<ref name="nasa">{{cite web|publisher=NASA |series=NASA Reference publication 1311|last1=Gordon|first1=Sanford|last2=McBride|first2=Bonnie J. |date=1994 |url=https://www.grc.nasa.gov/WWW/CEAWeb/RP-1311.pdf |archive-url=https://web.archive.org/web/20060421143635/http://www.grc.nasa.gov/WWW/CEAWeb/RP-1311.pdf |url-status=dead |archive-date=2006-04-21 |title=Computer Program for Calculation of Complex Chemical Equilibrium Compositions and Applications}}</ref> * The industrial synthesis such as [[ammonia]] in the [[Haber–Bosch process]] (depicted right) takes place through a succession of equilibrium steps including [[adsorption]] processes * [[Atmospheric chemistry]] * Seawater and other natural waters: [[chemical oceanography]] * Distribution between two phases ** [[Partition coefficient|log ''D'' distribution coefficient]]: important for pharmaceuticals where lipophilicity is a significant property of a drug ** [[Liquid–liquid extraction]], [[Ion exchange]], [[Chromatography]] ** [[Solubility equilibrium|Solubility product]] ** Uptake and release of oxygen by [[hemoglobin]] in blood * Acid–base equilibria: [[acid dissociation constant]], [[hydrolysis]], [[buffer solution]]s, [[pH indicator|indicators]], [[acid–base homeostasis]] * Metal–ligand complexation: [[Chelation|sequestering agents]], [[chelation therapy]], [[Magnetic resonance imaging|MRI contrast reagents]], [[Schlenk equilibrium]] * Adduct formation: [[host–guest chemistry]], [[supramolecular chemistry]], [[molecular recognition]], [[dinitrogen tetroxide]] * In certain [[oscillating reaction]]s, the approach to equilibrium is not asymptotically but in the form of a damped oscillation .<ref name="CEM"/> * The related [[Nernst equation]] in electrochemistry gives the difference in electrode potential as a function of redox concentrations. * When molecules on each side of the equilibrium are able to further react irreversibly in secondary reactions, the final product ratio is determined according to the [[Curtin–Hammett principle]]. In these applications, terms such as stability constant, formation constant, binding constant, affinity constant, association constant and dissociation constant are used. In biochemistry, it is common to give units for binding constants, which serve to define the concentration units used when the constant's value was determined.
Summary:
Please note that all contributions to Niidae Wiki may be edited, altered, or removed by other contributors. If you do not want your writing to be edited mercilessly, then do not submit it here.
You are also promising us that you wrote this yourself, or copied it from a public domain or similar free resource (see
Encyclopedia:Copyrights
for details).
Do not submit copyrighted work without permission!
Cancel
Editing help
(opens in new window)
Search
Search
Editing
Chemical equilibrium
(section)
Add topic