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===Occurrence=== [[Image:Molybdenit 1.jpg|thumb|left|Molybdenite]] Rhenium is one of the rarest elements in [[Earth's crust]] with an average concentration of 1 ppb;<ref name="G&W" /> other sources quote the number of 0.5 ppb making it the 77th most abundant element in Earth's crust.<ref name="Emsley2001p358">{{cite book|title=Nature's Building Blocks: An A-Z Guide to the Elements|last=Emsley|first=John|publisher=Oxford University Press|date=2001|location=Oxford, England, UK|isbn=978-0-19-850340-8|chapter=Rhenium|pages=[https://archive.org/details/naturesbuildingb0000emsl/page/358 358–360]|chapter-url=https://books.google.com/books?id=j-Xu07p3cKwC|url=https://archive.org/details/naturesbuildingb0000emsl/page/358}}</ref> Rhenium is probably not found free in nature (its possible natural occurrence is uncertain), but occurs in amounts up to 0.2%<ref name="G&W" /> in the mineral [[molybdenite]] (which is primarily [[molybdenum disulfide]]), the major commercial source, although single molybdenite samples with up to 1.88% have been found.<ref name="Rousch" /> [[Chile]] has the world's largest rhenium reserves, part of the copper ore deposits, and was the leading producer as of 2005.<ref>{{cite web|url=http://minerals.usgs.gov/minerals/pubs/country/2005/cimyb05.pdf |first=Steve T.|last=Anderson| publisher=[[United States Geological Survey]]|title=2005 Minerals Yearbook: Chile|access-date=2008-10-26}}</ref> It was only recently (in 1994) that the first rhenium [[mineral]] was found and described, a rhenium [[sulfide mineral]] (ReS<sub>2</sub>) condensing from a [[fumarole]] on [[Kudriavy]] volcano, [[Iturup]] island, in the [[Kuril Islands]].<ref>{{cite journal|last=Korzhinsky|first=M. A.|author2=Tkachenko, S. I. |author3=Shmulovich, K. I. |author4=Taran Y. A. |author5= Steinberg, G. S. | date=2004-05-05|title=Discovery of a pure rhenium mineral at Kudriavy volcano|journal=[[Nature (journal)|Nature]]|volume=369|pages=51–52|doi=10.1038/369051a0|issue=6475|bibcode = 1994Natur.369...51K |s2cid=4344624}}</ref> Kudriavy discharges up to 20–60 kg rhenium per year mostly in the form of rhenium disulfide.<ref>{{cite journal| last1 = Kremenetsky| first1 = A. A.| last2 = Chaplygin| first2 = I. V.| title = Concentration of rhenium and other rare metals in gases of the Kudryavy Volcano (Iturup Island, Kurile Islands)| journal = Doklady Earth Sciences| volume = 430| issue = 1| page = 114| date = 2010| doi = 10.1134/S1028334X10010253|bibcode = 2010DokES.430..114K | s2cid = 140632604}}</ref><ref>{{cite journal | last1 = Tessalina | first1 = S. | last2 = Yudovskaya | first2 = M. | last3 = Chaplygin | first3 = I. | last4 = Birck | first4 = J. | last5 = Capmas | first5 = F. | title = Sources of unique rhenium enrichment in fumaroles and sulphides at Kudryavy volcano | journal = Geochimica et Cosmochimica Acta | volume = 72 | page = 889 | date = 2008 | doi = 10.1016/j.gca.2007.11.015 | bibcode=2008GeCoA..72..889T | issue = 3}}</ref> Named [[rheniite]], this rare mineral commands high prices among collectors.<ref>{{cite web|url=http://www.galleries.com/minerals/sulfides/rheniite/rheniite.htm|publisher=Amethyst Galleries|title=The Mineral Rheniite}}</ref> <!--Dr. Kremenetsky from [[Russian Academy of Sciences|RAS]] Mineralogy Institute argues that this source could be commercially exploited,<ref>[http://www.nkj.ru/archive/articles/5340/ Завод на вулкане] // Наука и жизнь, № 11, 2000, in Russian.</ref> but currently there is no active attempts to extract it.--> {{Clear}}
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