Editing Guar gum (section)

=== Crosslinking guar ===

Guar molecules have a tendency to aggregate during the hydraulic fracturing process, mainly due to intermolecular hydrogen bonding. These aggregates are detrimental to oil recovery because they clog the fractures, restricting the flow of oil. Cross-linking guar polymer chains prevents aggregation by forming metal–hydroxyl complexes. The first crosslinked guar gels were developed in the late 1960s. Several metal additives have been used for crosslinking; among them are chromium, aluminium, antimony, zirconium, and the more commonly used boron. Boron, in the form of B(OH)4, reacts with the hydroxyl groups on the polymer in a two-step process to link two polymer strands together to form bis-diol complexes.

1:1 1,2 diol complex and a 1:1 1,3 diol complex, place the negatively charged borate ion onto the polymer chain as a pendant group. Boric acid itself does not apparently complex to the polymer so that all bound boron is negatively charged. The primary form of crosslinking may be due to ionic association between the anionic borate complex and adsorbed cations on the second polymer chain . The development of cross-linked gels was a major advance in fracturing fluid technology. Viscosity is enhanced by tying together the low molecular weight strands, effectively yielding higher molecular weight strands and a rigid structure. Cross-linking agents are added to linear polysaccharide slurries to provide higher proppant transport performance, relative to linear gels.

Lower concentrations of guar gelling agents are needed when linear guar chains are cross-linked. It has been determined that reduced guar concentrations provide better and more complete breaks in a fracture. The breakdown of cross-linked guar gel after the fracturing process restores formation permeability and allows increased production flow of petroleum products.

* [[Mining]]
* [[Hydroseeding]] – formation of seed-bearing "guar tack"{{citation needed|date=March 2019}}
* Medical institutions, especially [[nursing homes]] - used to thicken liquids and foods for patients with [[dysphagia]]
* [[Fire retardant]] industry – as a thickener in [[Phos-Chek]]
* [[Nanoparticles]] industry – to produce silver or gold nanoparticles, or develop innovative medicine delivery mechanisms for drugs in pharmaceutical industry
* [[Slime (toy)]], based on guar gum crosslinked with sodium tetraborate