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== History == Tritium was first detected in 1934 by [[Ernest Rutherford]], [[Mark Oliphant]] and [[Paul Harteck]] after bombarding [[deuterium]] with deuterons (deuterium nuclei). Deuterium is another isotope of hydrogen, which occurs naturally with an abundance of 0.015%.<ref> {{cite journal |last1=Oliphant |first1=M.L. |author1-link=Mark Oliphant |last2=Harteck |first2=P. |author2-link=Paul Harteck |last3=Rutherford |first3=L. |author3-link=Ernest Rutherford |year=1934 |title=Transmutation effects observed with heavy hydrogen |journal=Nature |volume=133 |issue=3359 |page=413 |doi=10.1038/133413a0 |bibcode=1934Natur.133..413O |s2cid=4078529 |url=http://www.chemteam.info/Chem-History/Rutherford-1934a/Rutherford-1934a.html |doi-access=free }}</ref><ref> {{cite journal |last1=Oliphant |first1=M.L.E. |author1-link=Mark Oliphant |last2=Harteck |first2=P. |author2-link=Paul Harteck |last3=Rutherford |first3=L. |author3-link=Ernest Rutherford |year=1934 |title=Transmutation Effects Observed with Heavy Hydrogen |journal=Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences |volume=144 |issue=853 |page=692 |bibcode=1934RSPSA.144..692O |doi=10.1098/rspa.1934.0077 |doi-access=free }} </ref> Their experiment could not isolate tritium, which was first accomplished in 1939 by [[Luis Walter Alvarez|Luis Alvarez]] and [[Robert Cornog]], who also realized tritium's radioactivity.<ref> {{cite journal |last1=Alvarez |first1=Luis |author1-link=Luis Walter Alvarez |last2=Cornog |first2=Robert |author2-link=Robert Cornog |year=1939 |title=Helium and Hydrogen of Mass 3 |journal=Physical Review |volume=56 |issue=6 |page=613 |bibcode=1939PhRv...56..613A |doi=10.1103/PhysRev.56.613 }} </ref><ref> {{cite book |last1=Alvarez |first1=Luis W. |last2=Trower |first2=W. Peter |year=1987 |title=Discovering Alvarez: Selected works of Luis W. Alvarez, with commentary by his students and colleagues |pages=[https://archive.org/details/discoveringalvar0000alva/page/26 26]β30 |publisher=University of Chicago Press |isbn=978-0-226-81304-2 |url=https://archive.org/details/discoveringalvar0000alva |url-access=registration }} </ref> [[Willard Libby]] recognized in 1954 that tritium could be used for [[radiometric dating]] of water and [[wine]].<ref> {{cite journal |last1=Kaufman |first1=Sheldon |last2=Libby |first2=W. |year=1954 |title=The natural distribution of tritium |journal=Physical Review |volume=93 |issue=6 |page=1337 |doi=10.1103/PhysRev.93.1337 |bibcode=1954PhRv...93.1337K }} </ref>
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