Editing Strobilurin (section)

==Natural strobilurins==
===Strobilurin A===
:[[Image:Strobilurin A.svg|200px]]
Strobilurin A (also known as mucidin) is produced by ''[[Oudemansiella mucida]]'', ''[[Strobilurus tenacellus]]'', ''[[Bolinea lutea]]'', and others.<ref name=Lorenzen>{{cite journal |last1 =Lorenzen |first1= K.  |last2 =Anke | first2 =T. | year =1998  |title=Basidiomycetes as a Source for New Bioactive Natural Products |url=https://books.google.com/books?id=aI_3BDcYKXgC&pg=PA329  | pages=329–364 |editor-last1=Mori |editor-first1=Kenji |journal=Current Organic Chemistry |volume=2 |issue=4 |doi= 10.2174/1385272802666220128213627 |s2cid= 246934805 |issn=1385-2728 }}</ref><ref name=Anke>{{cite book |doi=10.1007/978-3-662-10378-4_5 |chapter=Non-β-Lactam Antibiotics |title=Industrial Applications |year=2002 |last1=Anke |first1=T. |last2=Erkel |first2=G. |pages=101–104 |isbn=978-3-642-07481-3 }}</ref><ref name="Zakharychev-Kovalenko-1998">{{cite journal | last1=Zakharychev | first1=Vladimir V | last2=Kovalenko | first2=Leonid V | title=Natural compounds of the strobilurin series and their synthetic analogues as cell respiration inhibitors | journal=[[Russian Chemical Reviews]] | volume=67 | issue=6 | date=1998-06-30 | issn=0036-021X | doi=10.1070/rc1998v067n06abeh000426 | pages=535–544 | bibcode=1998RuCRv..67..535Z | s2cid=95676421}}</ref> When first isolated it was incorrectly assigned as the E E E [[geometric isomer]] but was later identified by [[total synthesis]] as being the E Z E isomer, as shown.<ref name=Schaefer>{{cite book |doi=10.1007/978-3-642-54461-3_8 |chapter=Agrochemicals: 8.2 Strobilurins |title=Natural Products in the Chemical Industry |year=2014 |last1=Schaefer |first1=Bernd |pages=688–704 |isbn=978-3-642-54460-6 }}</ref>{{rp|694}}
====9-Methoxystrobilurin A====
9-Methoxystrobilurin A is produced by ''Favolaschia'' spp.<ref name=Anke/>
===Strobilurin B===
:[[Image:Strobilurin B.svg|200px]]
Strobilurin B is produced by ''S. tenacellus''.<ref name=Anke/>
===Strobilurin C===
:[[Image:Strobilurin C.svg|220px]]
Strobilurin C is produced by ''[[Xerula longipes|X. longipes]]'' and ''[[Xerula melanotricha|X. melanotricha]]''.<ref name=Anke/><ref name="Zakharychev-Kovalenko-1998" />
===Strobilurin D and G===
:[[Image:Strobilurin D.svg|240px]]
Strobilurin D is produced by ''[[Cyphellopsis anomala]]''.<ref name="Zakharychev-Kovalenko-1998" /> Its structure was originally incorrectly assigned and is now considered to be identical to that of strobilurin G, produced by ''B. lutea''.<ref name=Anke/><ref name="Zakharychev-Kovalenko-1998" /> A related material, hydroxystrobilurin D, with an additional [[hydroxyl]] group attached to the methyl of the main chain is produced by ''[[Mycena sanguinolenta]]''.<ref name=Anke/>
===Strobilurin E===
:[[Image:Strobilurin E.svg|240px]]
Strobilurin E is produced by ''[[Crepidotus fulvotomentosus]]''<ref name="Zakharychev-Kovalenko-1998" /> and ''[[Favolaschia]]'' spp.<ref name=Anke/>
===Strobilurin F2===
:[[Image:Strobilurin F2.svg|240px]]
Strobilurin F2 is produced by ''B. lutea''.<ref name=Lorenzen/>
===Strobilurin H===
:[[Image:Strobilurin H.svg|200px]]
Strobilurin H is produced by ''B. lutea''.<ref name=Anke/> The natural product with a [[phenol]]ic hydroxy group in place of the aromatic methoxy group of strobilurin H is called strobilurin F1 and is found in ''C. anomala''<ref name="Zakharychev-Kovalenko-1998" /> and ''[[Agaricus]] spp.<ref name=Lorenzen/>
===Strobilurin X===
:[[Image:Strobilurin X.svg|200px]]
Strobilurin X is produced by ''O. mucida''.<ref name=Anke/><ref name="Zakharychev-Kovalenko-1998" />
===Oudemansins===
The oudemansins are closely related to the strobilurins and are also quinone outside inhibitors.<ref name=Anke/>
:[[File: Oudemansins general.svg|200px]]
[[Oudemansin A]] with R<sub>1</sub> = R<sub>2</sub> = H was first described in 1979, after being isolated from mycelial fermentations of the [[basidiomycota|basidiomycete]] fungus ''Oudemansiella mucida''.<ref>{{cite journal |doi=10.7164/antibiotics.32.1112 |pmid=528381 |title=Antibiotics from basidiomycetes. IX. Oudemansin, an antifungal antibiotic from Oudemansiella mucida (Schrader ex Fr.) hoehnel (Agaricales) |journal=The Journal of Antibiotics |volume=32 |issue=11 |pages=1112–1117 |year=1979 |last1=Anke |first1=Timm |last2=Hecht |first2=Hans Jürgen |last3=Chramm |first3=Georgs |last4=Steglich |first4=Wolfgang |doi-access=free }}</ref>
Later it was found in cultures of the basidiomycete fungi ''[[Mycena polygramma]]'' and ''Xerula melanotricha''. The latter fungus also produces oudemansin B, with R<sub>1</sub> = MeO and R<sub>2</sub> = Cl. Oudemansin X, with R<sub>1</sub> = H and R<sub>2</sub> = MeO was isolated from ''[[Oudemansiella radicata]]''.<ref name=Lorenzen/>