Editing Molecular electronics (section)

==Molecular scale electronics==
{{main|Molecular scale electronics}}
{{Nanoelectronics}}

Molecular scale [[electronics]], also called single-molecule electronics, is a branch of [[nanotechnology]] that uses single molecules, or nanoscale collections of single molecules, as [[electronic component]]s. Because single molecules constitute the smallest stable structures possible, this miniaturization is the ultimate goal for shrinking [[electrical circuit]]s.

Conventional electronic devices are traditionally made from bulk materials. Bulk methods have inherent limits, and are growing increasingly demanding and costly. Thus, the idea was born that the components could instead be built up atom by atom in a chemistry lab (bottom up) as opposed to carving them out of bulk material (top down). In single-molecule electronics, the bulk material is replaced by single molecules. The molecules used have properties that resemble traditional electronic components such as a [[wire]], [[transistor]], or [[rectifier]].<ref name="Aviram1974">{{Cite journal|last1=Aviram|first1=Arieh|last2=Ratner|first2=Mark A.|date=15 November 1974|title=Molecular rectifiers|journal=Chemical Physics Letters|language=en|volume=29|issue=2|pages=277–283|doi=10.1016/0009-2614(74)85031-1|bibcode=1974CPL....29..277A}}</ref>

Single-molecule electronics is an emerging field, and entire electronic circuits consisting exclusively of molecular sized compounds are still very far from being realized. However, the continuous demand for more computing power, together with the inherent limits of the present day lithographic methods make the transition seem unavoidable. Currently, the focus is on discovering molecules with interesting properties and on finding ways to obtain reliable and reproducible contacts between the molecular components and the bulk material of the electrodes.

Molecular electronics operates at distances less than 100 nanometers. Miniaturization down to single molecules brings the scale down to a regime where [[quantum mechanics]] effects are important. In contrast to the case in conventional electronic components, where [[electron]]s can be filled in or drawn out more or less like a continuous flow of [[electric charge]], the transfer of a single electron alters the system significantly. The significant amount of energy due to charging has to be taken into account when making calculations about the electronic properties of the setup and is highly sensitive to distances to conducting surfaces nearby.

[[Image:Rotaxane cartoon.jpg|thumb|left|Graphical representation of a [[rotaxane]], useful as a molecular switch]]

One of the biggest problems with measuring on single molecules is to establish reproducible electrical contact with only one molecule and doing so without shortcutting the electrodes. Because the current [[photolithographic]] technology is unable to produce electrode gaps small enough to contact both ends of the molecules tested (in the order of nanometers), alternative strategies are used. These include molecular-sized gaps called break junctions, in which a thin electrode is stretched until it breaks. One of the ways to overcome the gap size issue is by trapping molecular functionalized nanoparticles (internanoparticle spacing is matchable to the size of molecules), and later target the molecule by place exchange reaction.<ref>{{cite journal |last1=Jafri |first1=S H M |last2=Blom |first2=T |last3=Leifer |first3=K |last4=Strømme |first4=M |last5=Löfås |first5=H |last6=Grigoriev |first6=A |last7=Ahuja |first7=R |last8=Welch |first8=K |title=Assessment of a nanoparticle bridge platform for molecular electronics measurements |journal=Nanotechnology |date=29 October 2010 |volume=21 |issue=43 |pages=435204 |doi=10.1088/0957-4484/21/43/435204 |pmid=20890018 |bibcode=2010Nanot..21Q5204J |s2cid=29398313 }}</ref>

Another method is to use the tip of a [[scanning tunneling microscope]] (STM) to contact molecules adhered at the other end to a metal substrate.<ref>{{cite journal |last=Gimzewski |first=J.K. |author2=Joachim, C. |title=Nanoscale science of single molecules using local probes |journal=Science |volume=283 |pages=1683–1688 |date=1999 |doi=10.1126/science.283.5408.1683 |pmid=10073926 |issue=5408|bibcode= 1999Sci...283.1683G}}</ref> Another popular way to anchor molecules to the electrodes is to make use of [[sulfur]]'s high [[chemical affinity]] to [[gold]]; though useful, the anchoring is non-specific and thus anchors the molecules randomly to all gold surfaces, and the [[contact resistance]] is highly dependent on the precise atomic geometry around the site of anchoring and thereby inherently compromises the reproducibility of the connection. To circumvent the latter issue, experiments have shown that [[fullerenes]] could be a good candidate for use instead of sulfur because of the large conjugated π-system that can electrically contact many more atoms at once than a single atom of sulfur.<ref>[http://isis.ku.dk/kurser/index.aspx?kursusid=25537&xslt=simple6&param1=140150&param8=false Sørensen, J.K.] {{Webarchive|url=https://web.archive.org/web/20160329183231/https://isis.ku.dk/kurser/index.aspx?kursusid=25537&xslt=simple6&param1=140150&param8=false |date=2016-03-29 }}. (2006). "Synthesis of new components, functionalized with (60)fullerene, for molecular electronics". 4th Annual meeting - CONT 2006, University of Copenhagen.</ref>

The shift from metal electrodes to [[semiconductor]] electrodes allows for more tailored properties and thus for more interesting applications. There are some concepts for contacting organic molecules using semiconductor-only electrodes, for example by using [[indium arsenide]] [[nanowire]]s with an embedded segment of the wider bandgap material [[indium phosphide]] used as an electronic barrier to be bridged by molecules.<ref>{{cite journal |last=Schukfeh |first=Muhammed Ihab |author2=Storm, Kristian |author3=Mahmoud, Ahmad |author4=Søndergaard, Roar R. |author5=Szwajca, Anna| author6=Hansen, Allan |author7=Hinze, Peter |author8=Weimann, Thomas |author9=Fahlvik Svensson, Sofia |author10=Bora, Achyut |author11=Dick, Kimberly A. |author12=Thelander, Claes |author13=Krebs, Frederik C. |author14=Lugli, Paolo |author15=Samuelson, Lars |author16=Tornow, Marc |title=Conductance Enhancement of InAs/InP Heterostructure Nanowires by Surface Functionalization with Oligo(phenylene vinylene)s |journal=ACS Nano |volume=7 |pages=4111–4118 |date=2013 |doi=10.1021/nn400380g |pmid=23631558 |issue=5}}</ref>

One of the biggest hindrances for single-molecule electronics to be commercially exploited is the lack of means to connect a molecular sized circuit to bulk electrodes in a way that gives reproducible results. Also problematic is that some measurements on single molecules are done at [[Cryogenics|cryogenic temperatures]], near absolute zero, which is very energy consuming.