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==Plant- and animal-based adhesives== {| class="wikitable sortable plainrowheaders" |- ! scope="col" width="20" | Type ! scope="col" width="20" | Subtypes ! scope="col" width="50" | Source(s) !Manufacture ! scope="col" width="250" | Chemistry ! scope="col" width="200" | Volatiles ! scope="col" align="center" width="100" | Safety ! scope="col" width="80" | Properties !Shelf life !Working time !Setting !Strength !Solvents ! scope="col" width="30" | Uses ! scope="col" width="30" | Date |- !Roasted hydrocarbons ! align="center" |[[Tar]], [[Pitch (resin)|pitch]], and [[Bitumen|asphalt/ bitumen]] | align="center" | Made from plants (especially wood) or fossil hydrocarbons |natural or artificial [[destructive distillation]] | Hydrocarbon goo of no specific chemical formula | Emits [[Volatile organic compound]]s, especially when heated | align="center" | health effects understudied (see [[Bitumen|Asphalt#Health and safety]]) | align="center" | dark, viscous, more flexible when heated |Indefinite, may stiffen |Indefinite |Reversibly becomes more flexible and fluid when heated | |water-repellant, | align="center" | [[Sealant]], [[hafting]] | align="center" | prehistoric |- ! rowspan="3" | Mixed-protein glues<ref>{{cite book |last1=Bye |first1=Carolyn N. |chapter=Casein and Mixed Protein Adhesives |title=Handbook of Adhesives |date=1990 |pages=135β152 |doi=10.1007/978-1-4613-0671-9_7|isbn=978-1-4612-8019-4 }}</ref> ! align=center | [[Casein glue]] | align=center | Milk, limestone and brine |[[Milk curd]] is mixed with alkalis | | | align="center" | non-toxic (preservatives excepted) | |Once wet, 6β7 hours. | |~4 hours for softwood, 8 for hardwood; must be under pressure for >0.5-2 hrs |tensile strength exceeds most woods, 2,200-3,00 pounds per square inch |water-resistant, depending on alkalis used | align="center" | [[Woodworking]], paper glue, fireproof laminates |Medieval or earlier |- ![[Soybean glue]] |As for casein glue, but using soy protein |[[Soy protein]] is mixed with alkalis | | | | | | | | | | | |- ![[Albumin]] glues (blood glues and egg albumin adhesive, EAA) |blood ([[serum albumin]]) or [[egg]]s | | | | | | | | | | | |prehistoric |- ![[Gelatin|Gelatin glues]] ! align="center" | [[hide glue]], including [[rabbit-skin glue]]; bone glue, and fish glue including [[isinglass]] | align="center" | Animal [[connective tissue]] and bones |hides are acid-treated, neutralized, and repeatedly soaked; the soaking-water is dried into chips |hydrolyzed [[collagen]] | | align="center" | | | |Until it cools |[[Thermoplastic]]. Somewhat brittle when set | |Water-soluble | align="center" | Cabinetmaking, bookbinding, lutherie, [[glue-size]] | |- ![[Keratin glue]]s !Hoof glue and [[horn glue]] |[[Hoof|hooves]] of [[ungulate]]s, animal [[Horn (anatomy)|horns]] |Hooves or horns are fragmented, boiled into goo, and acidified |partially- [[Hydrolysis|hydrolyzed]] [[keratin]] | | | | |Until it cools |[[Thermoplastic]]. Hardens as it cools, but does not become brittle | | |Gluing and stiffening textiles, cabinetmaking, glass sealant | |- ![[Fibrin glue]] ! |human [[fibrinogen]] and human [[thrombin]] | | when two parts are mixed, they form [[fibrin]] | | | | |10β60 seconds |converts to [[fibrin]] | | |Medicine | |- !Waxes ![[Beeswax]] |made by insects | | | | | | | | | | | | |- ![[Starch]] glues ![[potato starch]], [[rice glue]], [[wheatpaste]] |starches (plant energy-storage chemicals) |Starch may be purified before being mixed with water; leaving [[gluten]] in makes a more permanent bond | | | | | | | | | | | |- ![[Dextrin|Dextrin glues]] ![[British gum]], [[Coccoina]] |usually derived from potato starch | | | | | | | | | | | |mid-19th century |- ![[Polysaccharide]] glues ![[mucilage]], [[agar]], [[algin]] | | | | | | | | | | | | | |- !Tree gums/[[resin]]s !Balsam (fir) resins, such as [[Canada balsam]], [[Dammar gum]], [[Gum arabic|Gum Arabic]] (also called acacia gum), [[Mastic (plant resin)|Mastic]] | | | | | | | | | | | | | |- !Latex [[rubber cement]] (cow gum) ! |[[latex]], a coagulating plant fluid, also made synthetically |latex is dissolved in an organic solvent | |organic solvent evaporates as it sets |solvent may be hazardous; latex is an [[Latex allergy|allergen]] | | | | | | | | |- ![[Methyl cellulose]] ! |[[cellulose]], a plant structural material, and methyl chloride |heating cellulose with an alkali and reacting it with [[methyl chloride]] | | | | | | | | | | | |}
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