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==Production== Ammonium perchlorate (AP) is produced by reaction between [[ammonia]] and [[perchloric acid]]. This process is the main outlet for the industrial production of [[perchloric acid]]. The salt also can be produced by [[salt metathesis reaction]] of ammonium salts with [[sodium perchlorate]]. This process exploits the relatively low solubility of NH<sub>4</sub>ClO<sub>4</sub>, which is about 10% of that for sodium perchlorate.<ref name=Ullmann>Helmut Vogt, Jan Balej, John E. Bennett, Peter Wintzer, Saeed Akbar Sheikh, Patrizio Gallone "Chlorine Oxides and Chlorine Oxygen Acids" in Ullmann's Encyclopedia of Industrial Chemistry 2002, Wiley-VCH. {{doi|10.1002/14356007.a06_483}}</ref> AP crystallises as colorless [[rhombohedron|rhombohedra]].
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