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== Structure == Adenine forms several [[tautomer]]s, compounds that can be rapidly interconverted and are often considered equivalent. However, in isolated conditions, i.e. in an inert gas matrix and in the gas phase, mainly the 9H-adenine tautomer is found.<ref>{{Cite journal |journal =Phys. Chem. Chem. Phys. |year =2002 |volume =4 |issue =20 |pages =4877–4882 |title =Tautomers and electronic states of jet-cooled adenine investigated by double resonance spectroscopy |author =Plützer, Chr. |author2=Kleinermanns, K. |bibcode =2002PCCP....4.4877P |doi =10.1039/b204595h }}</ref><ref>{{Cite journal |title = Experimental matrix isolation and theoretical ab initio HF/6-31G(d, p) studies of infrared spectra of purine, adenine and 2-chloroadenine |journal = Spectrochimica Acta Part A: Molecular Spectroscopy |volume = 50 |pages = 1081–1094 |year = 1994 |issn = 0584-8539 |doi = 10.1016/0584-8539(94)80030-8 |author1=M. J. Nowak |author2=H. Rostkowska |author3=L. Lapinski |author4=J. S. Kwiatkowski |author5=J. Leszczynski |issue = 6 |bibcode = 1994AcSpA..50.1081N }}</ref>
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