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Monomer

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A monomer (Template:IPAc-en Template:Respell; mono-, "one" + -mer, "part") is a molecule that can react together with other monomer molecules to form a larger polymer chain or two- or three-dimensional network in a process called polymerization.<ref>Young, R. J. (1987) Introduction to Polymers, Chapman & Hall Template:ISBN</ref><ref>International Union of Pure and Applied Chemistry, et al. (2000) IUPAC Gold Book, Polymerization</ref><ref name="clayden_organic">Template:Clayden</ref>Template:Quote box

Classification

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Chemistry classifies monomers by type, and two broad classes based on the type of polymer they form.

By type:

By type of polymer they form:

Differing stoichiometry<ref>Template:Cite book</ref> causes each class to create its respective form of polymer.

File:Condensation polymerization diacid diamine.svg
This nylon is formed by condensation polymerization of two monomers, yielding water

The polymerization of one kind of monomer gives a homopolymer. Many polymers are copolymers, meaning that they are derived from two different monomers. In the case of condensation polymerizations, the ratio of comonomers is usually 1:1. For example, the formation of many nylons requires equal amounts of a dicarboxylic acid and diamine. In the case of addition polymerizations, the comonomer content is often only a few percent. For example, small amounts of 1-octene monomer are copolymerized with ethylene to give specialized polyethylene.

Synthetic monomers

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Biopolymers

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The term "monomeric protein" may also be used to describe one of the proteins making up a multiprotein complex.<ref>Bruce Alberts, Alexander Johnson, Julian Lewis, Otin Raff, Keith Roberts, and Peter Walter, Molecular Biology of the Cell, 2008, Garland Science, Template:ISBN.</ref>

Natural monomers

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Some of the main biopolymers are listed below:

Amino acids

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For proteins, the monomers are amino acids. Polymerization occurs at ribosomes. Usually about 20 types of amino acid monomers are used to produce proteins. Hence proteins are not homopolymers.

Nucleotides

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For polynucleic acids (DNA/RNA), the monomers are nucleotides, each of which is made of a pentose sugar, a nitrogenous base and a phosphate group. Nucleotide monomers are found in the cell nucleus. Four types of nucleotide monomers are precursors to DNA and four different nucleotide monomers are precursors to RNA.

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For carbohydrates, the monomers are monosaccharides. The most abundant natural monomer is glucose, which is linked by glycosidic bonds into the polymers cellulose, starch, and glycogen.<ref>Template:Cite journal</ref>

Isoprene

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Isoprene is a natural monomer that polymerizes to form a natural rubber, most often cis-1,4-polyisoprene, but also trans-1,4-polymer. Synthetic rubbers are often based on butadiene, which is structurally related to isoprene.

See also

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Notes

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